公开(公告)号：WO2002073315A1

公开(公告)日：2002-09-19

申请号：PCT/US2002/004402

申请日：2002-02-14

Applicant: KODAK POLYCHROME GRAPHICS COMPANY, LTD.

Inventor： PLATZER, Stephan ,  PERRON, Paul ,  ALDEN, Melinda

IPC: G03F7/021

CPC classification number: G03F7/0215 ,  C08F8/18 ,  G03F7/0046

Abstract: A novel fluorinated aromatic acetal polymer comprises at least one unit of A and at least one unit of B or C, or at least one unit of each of A, B and C and optionally further comprises at least one unit of either D or E or at least one unit of each of D and E, wherein the units A and B and/or C, and optionally D and/or E are linked together by single covalent C-C bonds and have the formulae (A), (B), (C), (D) and (E), wherein R A is H or C 1 -C 11 alkyl, or an aryl group that does not contain fluorine, and R B and R C are an aryl groups that contains fluorine. The polymer is prepared by reacting a hydrolyzed polyvinyl acetate polymer or copolymer with at least one non-fluorinated aldehyde component, and at least one fluorinated aromatic component. The polymer is useful is preparing a photosensitive composition which comprises at least one diazo resin and at least one such fluorinated aromatic acetal polymer. Such a photosensitive composition may be applied to a support to form an imageable member which may be imaged to form a lithographic printing plates.

Abstract translation: 一种新的含氟芳族缩醛聚合物包含至少一个单元A和至少一个单元B或C，或每个A，B和C中的至少一个单元，并且任选地还包含至少一个D或E单元或 D和E各自的至少一个单元，其中单元A和B和/或C以及任选的D和/或E通过单一共价CC键连接在一起并具有式（A），（B），（ C），（D）和（E），其中RA是H或C 1 -C 11烷基，或不含氟的芳基，RB和RC是含有氟的芳基。 聚合物通过使水解的聚乙酸乙烯酯聚合物或共聚物与至少一种非氟化醛组分和至少一种氟化芳族组分反应来制备。 聚合物可用于制备包含至少一种重氮树脂和至少一种这种氟化芳族缩醛聚合物的光敏组合物。 可以将这样的感光组合物施加到支撑体上以形成可成像以形成平版印刷版的可成像构件。