公开(公告)号：WO2010118128A1

公开(公告)日：2010-10-14

申请号：PCT/US2010/030230

申请日：2010-04-07

Applicant: NOVOMER, INC. ,  ALLEN, Scott, D. ,  VALENTE, Ronald, R. ,  LEE, Han ,  CHERIAN, Anna, E. ,  BUNNING, Donald, L. ,  CLINTON, Nye, A. ,  FRUCHEY, Olan, Stanley ,  DOMBEK, Bernard, Duane

Inventor： ALLEN, Scott, D. ,  VALENTE, Ronald, R. ,  LEE, Han ,  CHERIAN, Anna, E. ,  BUNNING, Donald, L. ,  CLINTON, Nye, A. ,  FRUCHEY, Olan, Stanley ,  DOMBEK, Bernard, Duane

IPC: C08G63/82

CPC classification number: C07C51/377 ,  C07C51/09 ,  C07C67/30 ,  C07C67/317 ,  C07C231/14 ,  C07D305/12 ,  C07D307/60 ,  C08G63/08 ,  Y02P20/584

Abstract: The present application provides a method for producing an beta-lactone product. The method includes the steps of: reacting an epoxide, a solvent with a carbonylation catalyst and carbon monoxide to produce a reaction stream comprising a beta-lactone then separating a portion of the beta-lactone in the reaction stream from the solvent and carbonylation catalyst to produce: i) a beta-lactone stream with the beta-lactone, and ii) a catalyst recycling stream including the carbonylation catalyst and the high boiling solvent; and adding the catalyst recycling stream to the feed stream.

Abstract translation: 本申请提供了生产β-内酯产物的方法。 该方法包括以下步骤：使环氧化物，溶剂与羰基化催化剂和一氧化碳反应，以产生包含β-内酯的反应物流，然后将反应物流中的一部分β-内酯与溶剂和羰基化催化剂分离成 产生：i）具有β-内酯的β-内酯流，和ii）包含羰基化催化剂和高沸点溶剂的催化剂再循环流; 并将催化剂再循环流加入进料流中。

公开(公告)号：WO2018085251A1

公开(公告)日：2018-05-11

申请号：PCT/US2017/059243

申请日：2017-10-31

Applicant: NOVOMER, INC.

Inventor： SOOKRAJ, Sadesh, H. ,  TSEITLIN, Alexander ,  LEE, Han ,  POKROVSKI, Konstantin, A.

IPC: C08F122/02 ,  C08G63/08

Abstract: Provided herein are absorbent polymers produced from beta-propiolactone, and methods of producing such polymers. These absorbent polymer may be cross-linked. The beta-propiolactone may be derived from ethylene oxide and carbon monoxide. The absorbent polymer may be bio-based and/or bio-degradable. The absorbent polymers may be used for diapers, adult incontinence products, and feminine hygiene products, as well as for agricultural applications.

Abstract translation: 本文提供由β-丙内酯制备的吸收性聚合物，以及制备此类聚合物的方法。 这些吸收性聚合物可以交联。 β-丙内酯可以衍生自环氧乙烷和一氧化碳。 吸收性聚合物可以是生物基的和/或生物可降解的。 吸收性聚合物可用于尿布，成人失禁用品和女性卫生用品，以及农业用途。

公开(公告)号：WO2015085295A2

公开(公告)日：2015-06-11

申请号：PCT/US2014/069066

申请日：2014-12-08

Applicant: NOVOMER, INC.

Inventor： LAPOINTE, Robert E. ,  ALLEN, Scott D. ,  LEE, Han ,  WIDZINSKI, Thomas ,  FARMER, Jay J.

IPC: B65G1/137

CPC classification number: B01D67/0093 ,  B01D61/027 ,  B01D71/56 ,  B01D71/60 ,  B01D71/64 ,  B01D71/70 ,  B01D71/76 ,  B01D71/82 ,  B01D2323/30 ,  B01D2323/36 ,  B01D2325/30 ,  C07D305/12

Abstract: The present invention provides nanofiltration membranes with reduced chemical reactivity that can be utilized in manufacturing processes where reactive feedstocks and/or products are utilized or produced. Methods of making and using the membranes are also provided.

Abstract translation: 本发明提供具有降低的化学反应性的纳滤膜，其可以用于制造过程中，其中使用或生产反应性原料和/或产物。 还提供了制备和使用膜的方法。

公开(公告)号：WO2013122905A1

公开(公告)日：2013-08-22

申请号：PCT/US2013/025683

申请日：2013-02-12

Applicant: NOVOMER, INC.

Inventor： LEE, Han ,  SLOWIK, Michael, A.

IPC: C07C67/38 ,  C07D307/60 ,  C07D303/12

CPC classification number: C07D307/60 ,  B01J31/2295 ,  B01J2231/48 ,  B01J2531/31 ,  B01J2531/845 ,  C07D303/12 ,  C07D305/12

Abstract: A method of making acid anhydrides from epoxide and carbon monoxide feedstocks is presented. In various aspects, the method includes steps of reacting the contents of a feed stream comprising an epoxide, a solvent, a carbonylation catalyst and carbon monoxide to produce a first carbonylation product stream comprising a beta-lactone, then reacting the contents of the first carbonylation product stream with additional carbon monoxide to produce a second carbonylation product stream comprising an acid anhydride, and separating at least a portion of the acid anhydride from the second carbonylation product stream to produce: i) an acid anhydride product stream comprising the separated portion of acid anhydride; and ii) a recycling stream comprising the carbonylation catalyst, and finally adding the recycling stream to the feed stream.

Abstract translation: 提出了从环氧化物和一氧化碳原料制备酸酐的方法。 在各个方面，该方法包括使包含环氧化物，溶剂，羰基化催化剂和一氧化碳的进料流的内容物反应以产生包含β-内酯的第一羰基化产物流，然后使第一羰基化反应的内容物 产物流与另外的一氧化碳反应以产生包含酸酐的第二羰基化产物流，并将第二羰基化产物流中的至少一部分酸酐分离以产生：i）包含酸的分离部分的酸酐产物流 酐; 和ii）包含羰基化催化剂的再循环流，最后将再循环流加入进料流中。

公开(公告)号：WO2012158573A1

公开(公告)日：2012-11-22

申请号：PCT/US2012/037675

申请日：2012-05-12

Applicant: NOVOMER, INC. ,  LEE, Han ,  ALLEN, Scott, D. ,  FARMER, Jay ,  COATES, Geoff

Inventor： LEE, Han ,  ALLEN, Scott, D. ,  FARMER, Jay ,  COATES, Geoff

IPC: C07C51/10

CPC classification number: C08G63/823 ,  B01J31/183 ,  B01J31/2217 ,  B01J31/2243 ,  B01J2231/34 ,  B01J2531/0216 ,  B01J2531/025 ,  B01J2531/0252 ,  B01J2531/16 ,  B01J2531/22 ,  B01J2531/26 ,  B01J2531/31 ,  B01J2531/32 ,  B01J2531/33 ,  B01J2531/46 ,  B01J2531/62 ,  B01J2531/72 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  B01J2540/42 ,  B01J2540/54 ,  C07C51/54 ,  C07D305/08 ,  C07D307/20 ,  C07D487/22 ,  C07F5/069 ,  C07F15/065 ,  C07C55/10

Abstract: In one aspect, the present invention provides catalysts for the carbonylation of heterocycles. The inventive catalysts feature metal-ligand complexes having cationic functional groups tethered to the ligand, wherein the tethered cationic groups are associated with anionic metal carbonyl species. The invention also provides methods of using the inventive catalysts to affect the ring opening carbonylation of epoxides.

Abstract translation: 一方面，本发明提供了用于羰基化杂环的催化剂。 本发明的催化剂具有金属配体配合物，其具有与配体结合的阳离子官能团，其中所述连接的阳离子基团与阴离子金属羰基物质相关联。 本发明还提供使用本发明的催化剂来影响环氧化物的开环羰基化的方法。

公开(公告)号：WO2019051184A1

公开(公告)日：2019-03-14

申请号：PCT/US2018/049890

申请日：2018-09-07

Applicant: NOVOMER, INC.

Inventor： LEE, Han ,  WILSON, Bob ,  LIU, Yin ,  POKROVSKI, Konstantin ,  MCLENNAN, Ian ,  SOOKRAJ, Sadesh H.

IPC: C07C233/02 ,  C07C235/02 ,  C07C255/08 ,  C07D305/12

Abstract: Provided herein are acrylamide and acrylonitrile compounds and other compounds that may be produced from hydroxy amides and/or lactones. Provided herein are methods and systems to produce such compounds.

公开(公告)号：WO2018085254A1

公开(公告)日：2018-05-11

申请号：PCT/US2017/059249

申请日：2017-10-31

Applicant: NOVOMER, INC.

Inventor： LEE, Han ,  RUHL, John, B. ,  LAPOINTE, Robert, E. ,  SHERRY, Kyle ,  TSEITLIN, Alexander ,  SOOKRAJ, Sadesh, H.

IPC: C07C51/09 ,  C07C51/42 ,  C08G63/08 ,  C08G63/78

Abstract: Provided herein are absorbent polymers produced from beta-propiolactone, and methods and systems of producing such polymers. The beta-propiolactone may be derived from ethylene oxide and carbon monoxide. The absorbent polymer may be bio-based and/or bio-degradable. The absorbent polymers may be used for diapers, adult incontinence products, and feminine hygiene products, as well as for agricultural applications.

Abstract translation: 本文提供由β-丙内酯生产的吸收性聚合物，以及生产这种聚合物的方法和系统。 β-丙内酯可以衍生自环氧乙烷和一氧化碳。 吸收性聚合物可以是生物基的和/或生物可降解的。 吸收性聚合物可用于尿布，成人失禁用品和女性卫生用品，以及农业用途。

公开(公告)号：WO2019183284A1

公开(公告)日：2019-09-26

申请号：PCT/US2019/023262

申请日：2019-03-20

Applicant: NOVOMER, INC.

Inventor： LEE, Han ,  TSEITLIN, Alexander ,  SOOKRAJ, Sadesh H.

IPC: C08F236/10 ,  C08K3/36

Abstract: Provided are methods of producing sulfur- and phosphorus-containing polymers from beta-lactones. The sulfur- and phosphorus-containing polymers include bio-based sulfur- and phosphorus-containing polymers that may be obtained from renewable sources.

公开(公告)号：WO2018170006A1

公开(公告)日：2018-09-20

申请号：PCT/US2018/022248

申请日：2018-03-13

Applicant: NOVOMER INC.

Inventor： LEE, Han ,  SOOKRAJ, Sadesh H. ,  TSEITLIN, Alexander

IPC: C08G69/04 ,  C08G69/08

Abstract: Provided are methods of producing polyamides from beta-lactones. The polyamides include bio-based polyamides that may be obtained, either in part or completely, from renewable sources.

公开(公告)号：WO2016015019A1

公开(公告)日：2016-01-28

申请号：PCT/US2015/042124

申请日：2015-07-24

Applicant: NOVOMER, INC.

Inventor： LEE, Han

IPC: B01J31/22 ,  B01J31/18

CPC classification number: B01J31/2243 ,  B01J31/1815 ,  B01J2531/0205 ,  B01J2531/025 ,  B01J2531/0252 ,  B01J2531/31 ,  B01J2531/845

Abstract: The present disclosure provides novel methods of making aluminum complexes with utility for promoting epoxide carbonylation reactions. Methods include reacting neutral metal carbonyl compounds with alkylaluminum complexes.

Abstract translation: 本公开提供了制备铝络合物的新方法，其用于促进环氧化物羰基化反应。 方法包括使中性羰基化合物与烷基铝络合物反应。