公开(公告)号：WO2022081641A1

公开(公告)日：2022-04-21

申请号：PCT/US2021/054687

申请日：2021-10-13

Applicant: PHILLIPS 66 COMPANY

Inventor： MAY, Camille, Malonzo ,  MENDEZ-ARROYO, Jose, Edgar ,  YAO, Jianhua

IPC: B01J20/22 ,  B01J20/28 ,  C01B32/50

Abstract: A solid metal organic framework composition comprising a solid metal organic framework supported heteropolyacid wherein the heteropolyacid loading is greater than 25% by weight; and the pore volume is less than 2.0 mL/g; prepared by a method comprising: mixing a solution of metal organic framework precursors and a heteropolyacid to form a starting solution; and reacting the starting solution in a reactor to form a solid metal organic framework supported heteropolyacid.

公开(公告)号：WO2022081647A1

公开(公告)日：2022-04-21

申请号：PCT/US2021/054694

申请日：2021-10-13

Applicant: PHILLIPS 66 COMPANY

Inventor： MAY, Camille, Malonzo ,  MENDEZ-ARROYO, Jose Edgar ,  YAO, Jianhua

IPC: C07C2/08 ,  C07C2/24 ,  C10G50/00

Abstract: A process comprising a heterogeneous reaction between a solid metal organic framework supported sulfonic acid and a hydrocarbon feed to form a modified hydrocarbon stream. The modified hydrocarbon stream comprises essentially of C6+ hydrocarbons.

公开(公告)号：WO2022081633A1

公开(公告)日：2022-04-21

申请号：PCT/US2021/054672

申请日：2021-10-13

Applicant: PHILLIPS 66 COMPANY

Inventor： MAY, Camille, Malonzo ,  MENDEZ-ARROYO, Jose Edgar ,  YAO, Jianhua

IPC: B01D53/04 ,  B01J20/22 ,  B01J20/28

Abstract: A process comprising a heterogeneous reaction between a solid metal organic framework supported catalyst and a hydrocarbon feed to form a modified hydrocarbon stream. The modified hydrocarbon stream comprises essentially of C6+ hydrocarbons.

公开(公告)号：WO2022081654A1

公开(公告)日：2022-04-21

申请号：PCT/US2021/054703

申请日：2021-10-13

Applicant: PHILLIPS 66 COMPANY

Inventor： MAY, Camille, Malonzo ,  MENDEZ-ARROYO, Jose Edgar ,  YAO, Jianhua

IPC: B01D53/04 ,  B01J20/22 ,  B01J20/28

Abstract: A process comprising a heterogeneous reaction between a solid oxyanion-modified metal organic framework and a hydrocarbon feed to form a modified hydrocarbon stream. The modified hydrocarbon stream comprises essentially of C6+ hydrocarbons.

公开(公告)号：WO2022081639A1

公开(公告)日：2022-04-21

申请号：PCT/US2021/054684

申请日：2021-10-13

Applicant: PHILLIPS 66 COMPANY

Inventor： MAY, Camille, Malonzo ,  MENDEZ-ARROYO, Jose, Edgar ,  YAO, Jianhua

IPC: B01D53/04 ,  B01J20/22 ,  B01J20/28

Abstract: A process comprising a heterogenous reaction between a solid metal organic framework supported heteropolyacid catalyst and a hydrocarbon feed to form a modified hydrocarbon stream. The modified hydrocarbon stream comprises essentially of C6+ hydrocarbons.