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公开(公告)号:WO2023033692A1
公开(公告)日:2023-03-09
申请号:PCT/SE2022/050676
申请日:2022-07-04
申请人: SWEDISH BIOFUELS AB
发明人: GOLUBKOV, Igor
IPC分类号: C10G3/00 , B01J21/02 , B01J21/10 , B01J23/06 , B01J23/10 , C07C1/20 , C07C5/03 , C07C29/145 , C07C29/60 , C07C47/06 , C10L1/02 , C07C2/06 , C07C29/141 , C07C29/38 , C07C45/50 , C07C47/02 , C10G45/02 , C10G45/32 , C10G50/00
摘要: A method is for producing motor fuel, and more particularly gasoline, kerosene, anddiesel, from ethanol is disclosed. The ethanol is suitably obtained from a feedstock ofmainly plant origin. In addition, intermediate products and by-products from theinventive motor fuel synthesis, e.g. alcohols, aldehydes, ketones, ethers, olefins,paraffins, and aromatic compounds can be obtained using the method.
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公开(公告)号:WO2022063993A1
公开(公告)日:2022-03-31
申请号:PCT/EP2021/076372
申请日:2021-09-24
申请人: HALDOR TOPSØE A/S
发明人: BEATO, Pablo
摘要: A process and plant for producing an olefin stream, comprising passing a feedstock stream comprising oxygenates over a catalyst thereby forming an olefin stream; using a first reactor set including a single reactor or several reactors for the partial or full conversion of the oxygenates; and in series arrangement with the first reactor set, using a second reactor set including a single reactor or several reactors, for the further conversion of the oxygenates, and a phase separation stage in between the first reactor set and the second reactor set, for thereby forming the olefin stream.
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公开(公告)号:WO2022015777A1
公开(公告)日:2022-01-20
申请号:PCT/US2021/041505
申请日:2021-07-14
IPC分类号: B01D3/10 , B01D3/14 , C10G21/00 , B01D1/0058 , B01D1/26 , B01D1/2856 , B01D1/2884 , B01D1/2887 , B01D1/2896 , B01D3/007 , B01D3/143 , B01D9/00 , C07B31/00 , C07B33/00 , C07B35/02 , C07B35/04 , C07B35/08 , C07B37/08 , C07B37/10 , C10B55/00 , C10G11/00 , C10G2300/40 , C10G31/06 , C10G45/00 , C10G47/00 , C10G49/00 , C10G50/00 , C10G51/00 , C10G53/00 , C10G55/00 , C10G57/00 , C10G59/00 , C10G61/00 , C10G63/00 , C10G65/00 , C10G67/00 , C10G69/00 , C10G7/00 , C10G9/00 , C10G99/00 , E20
摘要: The present invention utilizes mechanical vapor compression and/or thermal vapor compression integrating compression loops across multiple process stages. A sequential network of compressors is utilized to increase the pressure and condensing temperature of the vapors within each process stage, as intra-vapor flow, and branching between process stages, as inter-vapor flow. Because the vapors available are shared among and between compressor stages, the number of compressors can be reduced, improving economics. Balancing vapor mass flow through incremental compressor stages which traverse multiple process stages by splitting vapors between compressor stages enables the overall vapor-compression system to be tailored to individual process energy requirements and to accommodate dynamic fluctuations in process conditions.
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公开(公告)号:WO2022015776A1
公开(公告)日:2022-01-20
申请号:PCT/US2021/041504
申请日:2021-07-14
IPC分类号: C12M1/107 , B01D1/28 , B01D3/38 , B01D1/0058 , B01D1/26 , B01D1/2856 , B01D1/2884 , B01D1/2887 , B01D1/2896 , B01D3/007 , B01D3/14 , B01D3/143 , B01D9/00 , C07B31/00 , C07B33/00 , C07B35/02 , C07B35/04 , C07B35/08 , C07B37/08 , C07B37/10 , C10B55/00 , C10G11/00 , C10G2300/40 , C10G31/06 , C10G45/00 , C10G47/00 , C10G49/00 , C10G50/00 , C10G51/00 , C10G53/00 , C10G55/00 , C10G57/00 , C10G59/00 , C10G61/00 , C10G63/00 , C10G65/00 , C10G67/00 , C10G69/00 , C10G7/00 , C10G9/00 , C10G99/00 , E20
摘要: This disclosure provides systems and methods that utilize integrated mechanical vapor or thermal vapor compression to upgrade process vapors and condense them to recover the heat of condensation across multiple processes, wherein the total process energy is reduced. Existing processes that are unable to recover the heat of condensation in vapors are integrated with mechanical or thermal compressors that raise vapor pressures and temperatures sufficient to permit reuse. Integrating multiple processes permits vapor upgrading that can selectively optimize energy efficiency, environmental sustainability, process economics, or a prioritized blend of such goals. Mechanical or thermal vapor compression also alters the type of energy required in industrial processes, favoring electro-mechanical energy which can be supplied from low-carbon, renewable sources rather than combustion of carbonaceous fuels.
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公开(公告)号:WO2021203816A1
公开(公告)日:2021-10-14
申请号:PCT/CN2021/074679
申请日:2021-02-01
申请人: 国家能源投资集团有限责任公司 , 北京低碳清洁能源研究院
摘要: 本发明提供了一种由轻烃脱氢芳构化生产芳烃和/或液体燃料的方法,该方法包括以下步骤:1)在脱氢反应条件下,将轻烃物流进行脱氢反应,得到含烯烃的物流;2)在芳构化反应条件下,将含烯烃的物流与芳构化催化剂接触,进行低聚/芳构化反应,得到含有芳烃和/或液体燃料的物流。本发明通过将脱氢与低聚/芳构化进行分离,使用不同的条件分步骤执行,并使用含有负载有活性金属组分的沸石分子筛作为芳构化催化剂,在优选的低温芳构化条件下,使得本发明的方法能够获得较高的烷烃转化率、较高的碳利用率和较高的单循环芳烃生产容量;且催化剂失活缓慢,单程寿命长,易再生,并具有良好的多循环稳定性。
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公开(公告)号:WO2020088440A1
公开(公告)日:2020-05-07
申请号:PCT/CN2019/113950
申请日:2019-10-29
摘要: 一种液固径向移动床反应装置和使用所述液固径向移动床反应装置进行固体酸烷基化方法,所述液固径向移动床反应装置包括:依次连接的径向移动床反应器、待生剂接收器、催化剂再生器和再生剂接收器,其中,再生剂接收器的催化剂出料口与径向移动床反应器的催化剂入口连通;所述的径向移动床反应器中由内向外,或者由外向内设置有反应物料分布区、催化剂床层和反应后物料收集区,所述的反应物料分布区与反应物料的进料管线相通;所述的反应后物料收集区与反应后物料引出管相通;所述的反应物料的进料管线上设置有构件化混合器。以及利用该装置进行固体酸烷基化的方法。该反应装置实现了烷基化反应与失活催化剂再生的连续平稳运行,提高了目标产物的选择性和装置操作的弹性,降低了设备投资。
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公开(公告)号:WO2019204365A1
公开(公告)日:2019-10-24
申请号:PCT/US2019/027766
申请日:2019-04-16
摘要: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olens to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.
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公开(公告)号:WO2018118395A1
公开(公告)日:2018-06-28
申请号:PCT/US2017/064453
申请日:2017-12-04
CPC分类号: C07C2/12 , B01J29/40 , B01J29/70 , B01J29/7026 , B01J29/703 , B01J29/7034 , B01J29/7038 , B01J29/7046 , C07C1/20 , C07C2529/40 , C07C2529/70 , C10G3/42 , C10G50/00 , C10G2300/1092 , C10G2400/04 , C10G2400/08 , Y02P30/20 , C07C11/02
摘要: Processes and reaction systems for low pressure oligomerization of olefins to produce distillate boiling range products using zeolite catalysts are provided herein.
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公开(公告)号:WO2018118347A1
公开(公告)日:2018-06-28
申请号:PCT/US2017/063385
申请日:2017-11-28
发明人: WANG, Kun , MERCHANT, Shamel
摘要: An integrated process for converting low-value paraffinic materials to high octane gasoline and high-cetane diesel light is disclosed. The process involves: (1) oxidation of an iso-paraffin to alkyl hydroperoxide and alcohol; (2) converting the alkyl hydroperoxide and alcohol to dialkyl peroxide; (3) converting low-octane, paraffinic gasoline molecules using the dialkyl peroxides as radical initiators, thereby forming high-cetane diesel, while the dialkyl peroxide is converted to an alcohol; (4) converting the alcohol to an olefin; and (5) alkylating the olefin with iso-butane to form high-octane alkylate. The net reaction is thus conversion of iso-paraffin to high-octane gasoline alkylate, and conversion of low-octane paraffinic gasoline to high-cetane diesel.
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公开(公告)号:WO2018111542A8
公开(公告)日:2018-06-21
申请号:PCT/US2017/063573
申请日:2017-11-29
摘要: Systems and methods are provided for the conversion of methanol to gasoline. Such methods may be performed be the sequential conversion of methanol to dimethyl ether, the conversion of dimethyl ether (and unconverted methanol, if present) to an intermediate olefin-rich product, and the oligomerization of the olefin-rich product to gasoline boiling range hydrocarbons.
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