ALTERNATIVE METHANOL TO OLEFIN (MTO) PROCESS

    公开(公告)号:WO2022063993A1

    公开(公告)日:2022-03-31

    申请号:PCT/EP2021/076372

    申请日:2021-09-24

    发明人: BEATO, Pablo

    摘要: A process and plant for producing an olefin stream, comprising passing a feedstock stream comprising oxygenates over a catalyst thereby forming an olefin stream; using a first reactor set including a single reactor or several reactors for the partial or full conversion of the oxygenates; and in series arrangement with the first reactor set, using a second reactor set including a single reactor or several reactors, for the further conversion of the oxygenates, and a phase separation stage in between the first reactor set and the second reactor set, for thereby forming the olefin stream.

    由轻烃生产芳烃和/或液体燃料的方法

    公开(公告)号:WO2021203816A1

    公开(公告)日:2021-10-14

    申请号:PCT/CN2021/074679

    申请日:2021-02-01

    IPC分类号: C07C2/42 C07C15/02 C10G50/00

    摘要: 本发明提供了一种由轻烃脱氢芳构化生产芳烃和/或液体燃料的方法,该方法包括以下步骤:1)在脱氢反应条件下,将轻烃物流进行脱氢反应,得到含烯烃的物流;2)在芳构化反应条件下,将含烯烃的物流与芳构化催化剂接触,进行低聚/芳构化反应,得到含有芳烃和/或液体燃料的物流。本发明通过将脱氢与低聚/芳构化进行分离,使用不同的条件分步骤执行,并使用含有负载有活性金属组分的沸石分子筛作为芳构化催化剂,在优选的低温芳构化条件下,使得本发明的方法能够获得较高的烷烃转化率、较高的碳利用率和较高的单循环芳烃生产容量;且催化剂失活缓慢,单程寿命长,易再生,并具有良好的多循环稳定性。

    一种液固径向移动床反应装置和一种固体酸烷基化方法

    公开(公告)号:WO2020088440A1

    公开(公告)日:2020-05-07

    申请号:PCT/CN2019/113950

    申请日:2019-10-29

    IPC分类号: B01J8/00 C10G29/00 C10G50/00

    摘要: 一种液固径向移动床反应装置和使用所述液固径向移动床反应装置进行固体酸烷基化方法,所述液固径向移动床反应装置包括:依次连接的径向移动床反应器、待生剂接收器、催化剂再生器和再生剂接收器,其中,再生剂接收器的催化剂出料口与径向移动床反应器的催化剂入口连通;所述的径向移动床反应器中由内向外,或者由外向内设置有反应物料分布区、催化剂床层和反应后物料收集区,所述的反应物料分布区与反应物料的进料管线相通;所述的反应后物料收集区与反应后物料引出管相通;所述的反应物料的进料管线上设置有构件化混合器。以及利用该装置进行固体酸烷基化的方法。该反应装置实现了烷基化反应与失活催化剂再生的连续平稳运行,提高了目标产物的选择性和装置操作的弹性,降低了设备投资。

    INTEGRATED PROCESS FOR MAKING HIGH-OCTANE GASOLINE AND HIGH-CETANE DIESEL

    公开(公告)号:WO2018118347A1

    公开(公告)日:2018-06-28

    申请号:PCT/US2017/063385

    申请日:2017-11-28

    摘要: An integrated process for converting low-value paraffinic materials to high octane gasoline and high-cetane diesel light is disclosed. The process involves: (1) oxidation of an iso-paraffin to alkyl hydroperoxide and alcohol; (2) converting the alkyl hydroperoxide and alcohol to dialkyl peroxide; (3) converting low-octane, paraffinic gasoline molecules using the dialkyl peroxides as radical initiators, thereby forming high-cetane diesel, while the dialkyl peroxide is converted to an alcohol; (4) converting the alcohol to an olefin; and (5) alkylating the olefin with iso-butane to form high-octane alkylate. The net reaction is thus conversion of iso-paraffin to high-octane gasoline alkylate, and conversion of low-octane paraffinic gasoline to high-cetane diesel.