HIGH REFRACTIVE INDEX OPTICAL RESIN COMPOSITION
    2.
    发明申请
    HIGH REFRACTIVE INDEX OPTICAL RESIN COMPOSITION 审中-公开
    高折射率光学树脂组合物

    公开(公告)号:WO2003011926A1

    公开(公告)日:2003-02-13

    申请号:PCT/US2001/023394

    申请日:2001-07-25

    Abstract: Polymerizable compositions are described comprising: (a) a mixture of thio(meth)acrylate functional monomers comprising: (a)(i) a first thio(meth)acrylate functional monomer, e.g., bis(thiomethacrylate)-1,2-ethylene; and (a)(ii) a second thio(meth)acrylate functional monomer, which is chain extended; (b) an aromatic monomer having at least two vinyl groups, e.g., divinyl benzene; (c) a polythiol monomer having at least two thiol groups, e.g., pentaerythritol tetrakis(3-mercaptopropionate); and (d) a comonomer selected from: (d)(i) an anhydride monomer having at least one ethylenically unsaturated group, e.g., methacrylic anhydride; (d)(ii) a monomer having at least three (meth)acryloyl groups, e.g., pentaerythritol tetrakis(acrylate); and (d)(iii) mixtures of monomers (d)(i) and (d)(ii). A polymerizate of the polymerizable composition has a refractive index of at least 1.57 and an Abbe number of at least 33.

    Abstract translation: 描述了可聚合组合物,其包括:(a)硫代(甲基)丙烯酸酯官能单体的混合物,其包含:(a)(i)第一硫代(甲基)丙烯酸酯官能单体,例如双(硫代甲基丙烯酸酯) 和(a)(ii)链延伸的第二硫代(甲基)丙烯酸酯官能单体; (b)具有至少两个乙烯基的芳族单体,例如二乙烯基苯; (c)具有至少两个硫醇基的多硫醇单体,例如季戊四醇四(3-巯基丙酸酯); 和(d)共聚单体,其选自:(d)(i)具有至少一个烯属不饱和基团的酸酐单体,例如甲基丙烯酸酐; (d)(ii)具有至少三个(甲基)丙烯酰基的单体,例如季戊四醇四(丙烯酸酯); 和(d)(iii)单体(d)(i)和(d)(ii)的混合物。 聚合性组合物的聚合物的折射率为至少1.57,阿贝数为33以上。

    HIGH IMPACT POLY(URETHANE UREA) POLYSULFIDES
    4.
    发明申请
    HIGH IMPACT POLY(URETHANE UREA) POLYSULFIDES 审中-公开
    高冲击聚脲(URETHANE UREA)POLYSULFIDES

    公开(公告)号:WO2003044070A1

    公开(公告)日:2003-05-30

    申请号:PCT/US2002/036470

    申请日:2002-11-14

    Abstract: The present invention relates to a sulfur-containing polyureaurethane and a method of preparing said polyureaurethane. In an embodiment, the sulfur-containing polyureaurethane when at least partially cured can have a refractive index of at least 1.57,an Abbe number of at least 35 and a density of less than 1.3 grams/cm3. Further, the sulfur-containing polyureaurethane can be prepared by reacting a polyureaurethane prepolymer comprising a polycyanate and at least one hydrogen-containing material, at least one episulfide-containing material; and an amine-containing curing agent.

    Abstract translation: 本发明涉及一种含硫聚脲氨基甲酸酯及其制备方法。 在一个实施方案中,当至少部分固化时,含硫聚氨酯可以具有至少1.57的折射率,至少35的阿贝数和小于1.3克/厘米3的密度。 此外,含硫聚脲氨酯可以通过使包含聚氰酸酯和至少一种含氢材料的聚脲氨酯预聚物,至少一种含硫化物的材料反应来制备; 和含胺固化剂。

    HIGH REFRACTIVE INDEX OPTICAL RESIN COMPOSITION
    5.
    发明申请
    HIGH REFRACTIVE INDEX OPTICAL RESIN COMPOSITION 审中-公开
    高折射率光学树脂组合物

    公开(公告)号:WO2003011925A1

    公开(公告)日:2003-02-13

    申请号:PCT/US2001/023396

    申请日:2001-07-25

    CPC classification number: G02B1/041 C08F220/38 C08F222/24 C08L33/14 C08L33/12

    Abstract: Polymerizable compositions are described comprising: (a) a mixture of thio(meth)acrylate functional monomers comprising, (a) (i) a first thio(meth)acrylate functional monomer, e.g., bis(thiomethacrylate)-1,2-ethylene, and (a) (ii) a second thio(meth)acrylate functional monomer, which is chain extended; and (b) a radically polymerizable comonomer having at least two (meth)acryloyl groups selected from, for example, (b) (i) ethoxylated bisphenol A dimethacrylate, (b) (ii) poly(ethylene glycol) dimethacrylate, (b) (iii) trimethylolpropane trimethacrylate, and (b)(iv) mixtures of monomers (b) (i), (b) (ii) and (b) (iii). Polymerizates of the polymerizable composition have a refractive index of at least 1.57 and an Abbe number of at least 33.

    Abstract translation: 描述了可聚合组合物,其包括:(a)硫代(甲基)丙烯酸酯官能单体的混合物,其包含(a)(i)第一硫代(甲基)丙烯酸酯官能单体,例如双(硫代甲基丙烯酸酯)-1,2-亚乙基, 和(a)(ii)链延伸的第二硫代(甲基)丙烯酸酯官能单体; (b)(b)(i)乙氧基化双酚A二甲基丙烯酸酯,(b)(ii)聚(乙二醇)二甲基丙烯酸酯,(b)和(b)(b)(b)可聚合的共聚单体,其具有至少两个(甲基)丙烯酰基, (iii)三羟甲基丙烷三甲基丙烯酸酯,和(b)(iv)单体(b)(i),(b)(ii)和(b)(iii)的混合物。 可聚合组合物的聚合物的折射率至少为1.57,阿贝数至少为33。

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