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公开(公告)号：WO2020099285A1
公开(公告)日：2020-05-22
申请号：PCT/EP2019/080783
申请日：2019-11-11
IPC分类号： B01J35/00 , B01J35/02 , B01J37/02 , B01J31/08 , B01J31/10 , B01J8/02 , C07C37/20 , C07C315/00 , C07C315/02 , B01J39/05 , B01J35/08 , C08F8/36
摘要： The invention is directed to a catalyst, to a method for manufacturing a catalyst, to a method for manufacturing a bisphenol compound, and to the use of a catalyst. The catalyst of the invention comprises particles having a core and a shell, wherein the shell comprises an ion exchange resin covering the core at least in part and wherein the core has a density that is higher than the density of the ion exchange resin.
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公开(公告)号：WO2017063849A1
公开(公告)日：2017-04-20
申请号：PCT/EP2016/072677
申请日：2016-09-23
IPC分类号： C08G65/20 , C08G63/16 , C08G63/181 , C08G63/183 , C08G63/672 , C08G63/695 , C08G65/332 , C08G77/445 , C08G77/46
CPC分类号： C08G65/20 , C08G63/672 , C08G63/6956 , C08G65/3326 , C08G77/445 , C08G77/46
摘要： The present invention relates to a polyether ester block copolymer comprising: (I) hard block moieties formed by reacting one or more aromatic dicarboxylic acid comprising 6-12 carbon atoms and/or the C1-C4 diester thereof with one or more aliphatic diol comprising 2-10 carbon atoms; (II) soft block moieties formed by reacting one or more aromatic dicarboxylic acid comprising 6-12 carbon atoms and/or the C1-C4 diester thereof with one or more polyalkylene glycol comprising 2-10 carbon atoms in the repeating polymeric unit; (III) soft block moieties formed by reacting one or more aromatic dicarboxylic acid comprising 6-12 carbon atoms and/or the C1-C4 diester thereof with one or more hydroxy-terminated polysiloxane or a copolymer thereof; wherein the weight ratio of soft block (II) to soft block (III)≥ 8.0 and
摘要翻译： 本发明涉及聚醚酯嵌段共聚物，其包含：（I）通过使一种或多种包含6-12个碳原子的芳族二羧酸和/或其C1-C4二酯反应形成的硬嵌段部分 与一种或多种包含2-10个碳原子的脂族二醇; （II）通过使一种或多种包含6-12个碳原子的芳族二羧酸和/或其C1-C4二酯与一种或多种包含2-10个碳原子的聚亚烷基二醇在重复聚合单元中反应形成的软嵌段部分; （III）通过使一种或多种包含6-12个碳原子的芳族二羧酸和/或其C1-C4二酯与一种或多种羟基封端的聚硅氧烷或其共聚物反应形成的软嵌段部分; 其中软嵌段（II）与软嵌段（III）的重量比≥8.0且＆lt; 12.0; 软嵌段（III）部分的重量≥0.5且< 相对于聚醚酯嵌段共聚物的总重量为6.0重量％; 软嵌段（II）部分的重量≥10.0且< 相对于聚醚酯嵌段共聚物的总重量为50.0重量％。 这种聚醚酯嵌段共聚物可以例如具有与耐水性有关的良好性质，例如良好的疏水性和良好的耐水解性，以及良好的热性能和良好的机械性能。
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公开(公告)号：WO2017089099A1
公开(公告)日：2017-06-01
申请号：PCT/EP2016/076775
申请日：2016-11-07
发明人： MITRA, Susanta , SEN, Suman, Kumar , PASK, Stephen, D , SHAIKH, Abbas-Alli, Ghudubhai , AL-FARHOOD, Bander
IPC分类号： C08G63/672 , C08G63/695 , C08G63/85
CPC分类号： C08G63/672 , C08G63/6956 , C08G63/85
摘要： The present invention relates to a process for the production of polyether ester block copolymers wherein the process comprises reacting a mixture of reactants comprising: • one or more aromatic dicarboxylic acid comprising 6-12 carbon atoms; • one or more aliphatic diol comprising 2-10 carbon atoms; and • one or more polyalkylene glycol having a polymeric structure comprising alkylene oxide units having 2-10 carbon atoms; wherein the reaction takes in the presence of a catalyst having a structure according to formula (I); wherein R1 and R2 each individually are a moiety comprising 2-10 carbon atoms. The production of polyether ester block copolymers using such process eliminates the formation of undesired alcohol as a by-product. The polyether ester block copolymers produced using such process show a good balance of mechanical properties. Such process allows for the production of polyether ester block copolymers having a good balance of mechanical properties in a single reaction rather than involving the addition of the reactants to the reactor in several separate feeds.
摘要翻译： 本发明涉及生产聚醚酯嵌段共聚物的方法，其中所述方法包括使反应物的混合物反应，所述反应物的混合物包含：·一种或多种包含6-12个碳原子的芳族二羧酸; ·一种或多种包含2-10个碳原子的脂族二醇; 和·一种或多种具有包含具有2-10个碳原子的氧化亚烷基单元的聚合结构的聚亚烷基二醇; 其中所述反应在具有根据式（I）的结构的催化剂存在下进行; 其中R 1和R 2各自是包含2-10个碳原子的部分。 使用这种方法生产聚醚酯嵌段共聚物消除了作为副产物的不需要的醇的形成。 使用这种方法生产的聚醚酯嵌段共聚物显示出良好的机械性能平衡。 该方法允许在单一反应中生产具有良好机械性能平衡的聚醚酯嵌段共聚物，而不涉及在几个单独的进料中向反应器中加入反应物。
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