Abstract:
Embodiments of a self-sustainable solid oxide fuel cell (SOFC) system for powering a gas well comprise a first SOFC comprising a first cathode, a first anode, and a first solid electrolyte; a second SOFC comprising a second cathode, a second anode, and a second solid electrolyte; SO 2 removal equipment; a combustion circuit comprising a combustor and a circulating heat carrier in thermal connection with the combustor, the first SOFC, and the second SOFC; and one or more external electric circuits. The first anode comprises a first oxidation region configured to produce SO 2 and electrons. The second anode comprises a second oxidation region configured to electrochemically oxidize CH 4 to produce syngas and electrons and electrochemically oxidize H 2 to produce H 2 O and electrons. The external electric circuits are configured to generate power from the electrons produced in both the first SOFC and the second SOFC.
Abstract:
A redox flow battery and a method of operating a redox flow battery. The redox flow battery includes an ionically conductive separator, a working side flowing electrolyte, a working electrode, a counter electrode, and an auxiliary electrode. The auxiliary electrode is in ionic contact with the working electrode, where an electrically insulating peripheral gap separates the auxiliary electrode from the working electrode. An auxiliary power source is configured to establish an auxiliary circuit voltage differential between a terminal in each of the counter electrode and the auxiliary electrode to control an auxiliary electrode voltage such that the auxiliary electrode voltage is within an electrochemical window of the working side flowing electrolyte, as well as to establish a voltage differential between the working electrode terminal and the auxiliary electrode terminal.
Abstract:
A solar system (100) is provided comprising a light receiving surface (10), a condensation subassembly (20), a water collection subassembly (30), and a cleaning subassembly (40). The expansion chamber (24) of the condensation subassembly is thermally coupled to the light receiving surface and thermally insulated from the ambient such that expansion of compressed air in the expansion chamber, as controlled by the compressed air expansion valve (22), encourages humidity condensation on the light receiving surface by reducing the temperature of the light receiving surface. The water collection subassembly comprises a water collection vessel and water direction hardware (34) positioned to direct condensed water on the light receiving surface to the water collection vessel. The cleaning subassembly comprises a water dispensing unit (42) positioned to dispense water from the water collection vessel over the light receiving surface of the solar system (100).
Abstract:
Embodiments of a method of removing carbonaceous deposits in a liquid-hydrocarbon fueled solid oxide fuel cell and related system are provided. The method includes providing a solid oxide fuel cell system having an anode, a cathode, a solid oxide electrolyte oriented between the anode and cathode, an amplifier cathode disposed proximate the solid oxide electrolyte and the cathode, a fuel cell electric circuit electrically connecting the anode and the cathode, and an amplifier electric circuit electrically connecting the anode and the amplifier cathode. Further, operating the amplifier electric circuit in an electrolytic mode to electrically power the amplifier cathode, wherein the amplifier cathode generates and supplies O2- or CO32- to the anode. The method further includes removing the carbonaceous deposits on the anode by converting the carbonaceous deposits to carbon dioxide gas via reaction with the O2- or CO32- and expelling the carbon dioxide gas.
Abstract:
Methods for recovering organic heteroatom compounds from a hydrocarbon feedstock include feeding into a contactor a hydrocarbon feedstock and an aqueous solvent to form an extraction mixture of the aqueous solvent with the hydrocarbon feedstock. The hydrocarbon feedstock includes a hydrocarbon and an organic heteroatom compound. The aqueous solvent includes an ionic liquid formed from pressurized carbon dioxide and water. A pressure and temperature of the extraction mixture may be established that together tune the aqueous solvent to selectively form a solvent complex with the at least one organic heteroatom compound. Then, the solvent complex is extracted to a recovery vessel from the extraction mixture in the contactor. By adjustment of a recovery temperature of the recovery vessel, a recovery pressure of the recovery vessel, or both, the solvent complex decomposes into carbon dioxide and the organic heteroatom compound. The organic heteroatom compound is then recovered from the recovery vessel.
Abstract:
A vehicular power system, a vehicle and a method of providing auxiliary power to a vehicle using an auxiliary power unit that uses a molten metal anode solid oxide fuel cell rather than an internal combustion engine. The auxiliary power unit includes a container with numerous fuel cells disposed within it such that when the metal anode is heated, the metal converts to a molten state that can be electrochemically cycled between oxidized and reduced states by oxygen and a fuel present in the molten metal, respectively. The auxiliary power unit further includes a furnace that selectively provides heat to the fuel cells in order to place the anode into its molten metal state. Seals may provide fluid isolation between the molten metal within the container and the ambient environment.
Abstract:
A flow redox battery system including an electrochemical cell, an anolyte tank, a catholyte tank, a first anolyte carrier slurry, a second anolyte carrier slurry, a first catholyte carrier slurry, a second catholyte carrier slurry, and a power generation circuit. An ion-exchange membrane is electrochemically engaged with an anode and a cathode. The power generation circuit is electrically coupled to the anode and the cathode. The anolyte tank is fluidly coupled to the anode and the catholyte tank is fluidly coupled to the cathode. The first anolyte carrier slurry includes a density less than a density of the second anolyte carrier slurry and an electronegativity different than an electronegativity of the second anolyte carrier slurry. Further, the first catholyte carrier slurry includes a density less than a density of the second catholyte carrier slurry and an electronegativity different than an electronegativity of the second catholyte carrier slurry.
Abstract:
A photocatalytic power generation system including a solar housing, a photoanode, an electrolyte membrane, a cathode, an oxygen diffusion membrane, and an external power generation circuit. The photoanode and the cathode are each positioned within the solar housing and electrically coupled to the external power generation circuit. The electrolyte membrane is positioned between and electrochemically engaged with the photoanode and the cathode forming a photocatalytic cell. The solar housing comprises a closed-loop water chamber having an anode side flow channel, a cathode side flow channel, a recombined water channel, and an oxygen diffusion membrane. Further, the oxygen diffusion membrane is positioned and configured to inhibit recombined water generated at the cathode from flowing from the cathode side to the anode side along the oxygen transport channel and permit recombined water generated at the cathode from flowing from the cathode side to the anode side along the recombined water channel.
Abstract:
Embodiments of a molten metal anode solid oxide fuel cell (MMA-SOFC) system comprise a first and second MMA-SOFC, a fuel contactor integral or in fluid communication with the first MMA-SOFC, a molten metal conduit that delivers molten metal from a first molten metal anode to a second molten metal anode, and one or more external electric circuits, wherein the first molten metal anode oxidizes molten metal to produce metal oxides and electrons. The fuel contactor reduces the metal oxides and produce metals and metal sulfides in the molten metal upon reaction with sulfur-containing fuel. The second molten metal anode oxidizes the metal sulfides in the metal sulfides-containing molten metal to produce metals and electrons, and the external electric circuits generate power from the electrons produced in the first and second MMA-SOFCs.
Abstract:
An electrochemical cell, electrochemical cell assembly and a method of assembling an electrochemical cell assembly. The cell includes a pair of current collectors that when joined together form a three-dimensional electrode assembly with an ion-exchange membrane disposed between the anode and cathode of the electrode assembly. The current collectors are sized and shaped such that a three-dimensional reactant chamber volume of one of the current collectors accepts nested placement of at least a portion of the three-dimensional reactant chamber volume of the other current collector. This design allows for easy and direct addition, removal or replacement of cells in a stack of such cells in a modular fashion. In addition, ease of mounting and unmounting of the cells on reactant manifolds promotes ease of assembly of two-dimensional or three-dimensional stack structures.