SELF-SUSTAINABLE SOLID OXIDE FUEL CELL SYSTEM AND METHOD FOR POWERING A GAS WELL

    公开(公告)号:WO2018236685A1

    公开(公告)日:2018-12-27

    申请号:PCT/US2018/037802

    申请日:2018-06-15

    Abstract: Embodiments of a self-sustainable solid oxide fuel cell (SOFC) system for powering a gas well comprise a first SOFC comprising a first cathode, a first anode, and a first solid electrolyte; a second SOFC comprising a second cathode, a second anode, and a second solid electrolyte; SO 2 removal equipment; a combustion circuit comprising a combustor and a circulating heat carrier in thermal connection with the combustor, the first SOFC, and the second SOFC; and one or more external electric circuits. The first anode comprises a first oxidation region configured to produce SO 2 and electrons. The second anode comprises a second oxidation region configured to electrochemically oxidize CH 4 to produce syngas and electrons and electrochemically oxidize H 2 to produce H 2 O and electrons. The external electric circuits are configured to generate power from the electrons produced in both the first SOFC and the second SOFC.

    METHOD AND SYSTEM TO MODIFY THE PERFORMANCE OF A REDOX FLOW BATTERY

    公开(公告)号:WO2020086349A1

    公开(公告)日:2020-04-30

    申请号:PCT/US2019/056471

    申请日:2019-10-16

    Abstract: A redox flow battery and a method of operating a redox flow battery. The redox flow battery includes an ionically conductive separator, a working side flowing electrolyte, a working electrode, a counter electrode, and an auxiliary electrode. The auxiliary electrode is in ionic contact with the working electrode, where an electrically insulating peripheral gap separates the auxiliary electrode from the working electrode. An auxiliary power source is configured to establish an auxiliary circuit voltage differential between a terminal in each of the counter electrode and the auxiliary electrode to control an auxiliary electrode voltage such that the auxiliary electrode voltage is within an electrochemical window of the working side flowing electrolyte, as well as to establish a voltage differential between the working electrode terminal and the auxiliary electrode terminal.

    SOLAR SYSTEMS COMPRISING SELF SUSTAINABLE CONDENSATION, WATER COLLECTION, AND CLEANING SUBASSEMBLIES
    3.
    发明申请
    SOLAR SYSTEMS COMPRISING SELF SUSTAINABLE CONDENSATION, WATER COLLECTION, AND CLEANING SUBASSEMBLIES 审中-公开
    包含自我可持续冷凝,水收集和清洁分层的太阳能系统

    公开(公告)号:WO2016114814A1

    公开(公告)日:2016-07-21

    申请号:PCT/US2015/035750

    申请日:2015-06-15

    Abstract: A solar system (100) is provided comprising a light receiving surface (10), a condensation subassembly (20), a water collection subassembly (30), and a cleaning subassembly (40). The expansion chamber (24) of the condensation subassembly is thermally coupled to the light receiving surface and thermally insulated from the ambient such that expansion of compressed air in the expansion chamber, as controlled by the compressed air expansion valve (22), encourages humidity condensation on the light receiving surface by reducing the temperature of the light receiving surface. The water collection subassembly comprises a water collection vessel and water direction hardware (34) positioned to direct condensed water on the light receiving surface to the water collection vessel. The cleaning subassembly comprises a water dispensing unit (42) positioned to dispense water from the water collection vessel over the light receiving surface of the solar system (100).

    Abstract translation: 提供了一种太阳能系统(100),其包括光接收表面(10),冷凝子组件(20),收水子组件(30)和清洁子组件(40)。 冷凝子组件的膨胀室(24)热耦合到光接收表面并与环境热绝缘,使得由压缩空气膨胀阀(22)控制的膨胀室中的压缩空气的膨胀促进湿度冷凝 通过降低光接收表面的温度在光接收表面上。 集水组件包括收集容器和水方向硬件(34),其定位成将光接收表面上的冷凝水引导到采集容器。 清洁子组件包括水分配单元(42),其定位成在太阳能系统(100)的光接收表面上从水收集容器分配水。

    ELECTROCHEMICAL OXIDATION OF CARBONACEOUS DEPOSITS IN LIQUID-HYDROCARBON FUELED SOLID OXIDE FUEL CELLS
    4.
    发明申请
    ELECTROCHEMICAL OXIDATION OF CARBONACEOUS DEPOSITS IN LIQUID-HYDROCARBON FUELED SOLID OXIDE FUEL CELLS 审中-公开
    液化石油气固体氧化物燃料电池中碳沉积物的电化学氧化

    公开(公告)号:WO2016133615A1

    公开(公告)日:2016-08-25

    申请号:PCT/US2016/013394

    申请日:2016-01-14

    Abstract: Embodiments of a method of removing carbonaceous deposits in a liquid-hydrocarbon fueled solid oxide fuel cell and related system are provided. The method includes providing a solid oxide fuel cell system having an anode, a cathode, a solid oxide electrolyte oriented between the anode and cathode, an amplifier cathode disposed proximate the solid oxide electrolyte and the cathode, a fuel cell electric circuit electrically connecting the anode and the cathode, and an amplifier electric circuit electrically connecting the anode and the amplifier cathode. Further, operating the amplifier electric circuit in an electrolytic mode to electrically power the amplifier cathode, wherein the amplifier cathode generates and supplies O2- or CO32- to the anode. The method further includes removing the carbonaceous deposits on the anode by converting the carbonaceous deposits to carbon dioxide gas via reaction with the O2- or CO32- and expelling the carbon dioxide gas.

    Abstract translation: 提供了一种在液烃烃燃料固体氧化物燃料电池及相关系统中除去碳质沉积物的方法的实施方案。 该方法包括提供固体氧化物燃料电池系统,其具有阳极,阴极,定向在阳极和阴极之间的固体氧化物电解质,靠近固体氧化物电解质和阴极设置的放大器阴极,将阳极电连接的燃料电池电路 和阴极以及电连接阳极和放大器阴极的放大器电路。 此外,以电解模式操作放大器电路以对放大器阴极电力供电,其中放大器阴极产生并向阳极供应O2-或CO 32。 该方法还包括通过与O 2 - 或CO 32 - 反应并将二氧化碳气体排出而将碳质沉积物转化为二氧化碳气体来除去阳极上的碳质沉积物。

    METHODS FOR RECOVERING ORGANIC HETEROATOM COMPOUNDS FROM HYDROCARBON FEEDSTOCKS
    5.
    发明申请
    METHODS FOR RECOVERING ORGANIC HETEROATOM COMPOUNDS FROM HYDROCARBON FEEDSTOCKS 审中-公开
    从油料回收器回收有机杂化物的方法

    公开(公告)号:WO2015094633A1

    公开(公告)日:2015-06-25

    申请号:PCT/US2014/068048

    申请日:2014-12-02

    Abstract: Methods for recovering organic heteroatom compounds from a hydrocarbon feedstock include feeding into a contactor a hydrocarbon feedstock and an aqueous solvent to form an extraction mixture of the aqueous solvent with the hydrocarbon feedstock. The hydrocarbon feedstock includes a hydrocarbon and an organic heteroatom compound. The aqueous solvent includes an ionic liquid formed from pressurized carbon dioxide and water. A pressure and temperature of the extraction mixture may be established that together tune the aqueous solvent to selectively form a solvent complex with the at least one organic heteroatom compound. Then, the solvent complex is extracted to a recovery vessel from the extraction mixture in the contactor. By adjustment of a recovery temperature of the recovery vessel, a recovery pressure of the recovery vessel, or both, the solvent complex decomposes into carbon dioxide and the organic heteroatom compound. The organic heteroatom compound is then recovered from the recovery vessel.

    Abstract translation: 从烃原料中回收有机杂原子化合物的方法包括将烃原料和含水溶剂进料到接触器中以形成含水溶剂与烃原料的萃取混合物。 烃原料包括烃和有机杂原子化合物。 含水溶剂包括由加压二氧化碳和水形成的离子液体。 可以建立萃取混合物的压力和温度,其一起调节水性溶剂以选择性地与至少一种有机杂原子化合物形成溶剂配合物。 然后,将溶剂配合物从接触器中的萃取混合物中提取回收容器。 通过调节回收容器的回收温度,回收容器的回收压力或二者,溶剂配合物分解成二氧化碳和有机杂原子化合物。 然后从回收容器中回收有机杂原子化合物。

    IN-SITU GRAVITATIONAL SEPARATION OF ELECTROLYTE SOLUTIONS IN FLOW REDOX BATTERY SYSTEMS
    7.
    发明申请
    IN-SITU GRAVITATIONAL SEPARATION OF ELECTROLYTE SOLUTIONS IN FLOW REDOX BATTERY SYSTEMS 审中-公开
    流动氧化还原电池系统中电解质溶液的原位重力分离

    公开(公告)号:WO2017160712A1

    公开(公告)日:2017-09-21

    申请号:PCT/US2017/022092

    申请日:2017-03-13

    Abstract: A flow redox battery system including an electrochemical cell, an anolyte tank, a catholyte tank, a first anolyte carrier slurry, a second anolyte carrier slurry, a first catholyte carrier slurry, a second catholyte carrier slurry, and a power generation circuit. An ion-exchange membrane is electrochemically engaged with an anode and a cathode. The power generation circuit is electrically coupled to the anode and the cathode. The anolyte tank is fluidly coupled to the anode and the catholyte tank is fluidly coupled to the cathode. The first anolyte carrier slurry includes a density less than a density of the second anolyte carrier slurry and an electronegativity different than an electronegativity of the second anolyte carrier slurry. Further, the first catholyte carrier slurry includes a density less than a density of the second catholyte carrier slurry and an electronegativity different than an electronegativity of the second catholyte carrier slurry.

    Abstract translation: 流动氧化还原电池系统包括电化学电池,阳极电解液槽,阴极电解液槽,第一阳极电解液载体浆料,第二阳极电解液载体浆料,第一阴极电解液载体浆料,第二阴极电解液载体浆料, 和发电电路。 离子交换膜与阳极和阴极电化学接合。 发电电路电耦合到阳极和阴极。 阳极液罐流体连接至阳极,阴极液罐流体连接至阴极。 第一阳极电解液载体浆料包括小于第二阳极电解液载体浆料的密度的密度和不同于第二阳极电解液载体浆料的电负性的电负性。 此外,第一阴极电解液载体浆料包括小于第二阴极电解液载体浆料密度的密度和不同于第二阴极电解液载体浆料电负性的电负性。

    SYSTEM AND METHOD FOR POWER GENERATION WITH A CLOSED-LOOP PHOTOCATALYTIC SOLAR DEVICE
    8.
    发明申请
    SYSTEM AND METHOD FOR POWER GENERATION WITH A CLOSED-LOOP PHOTOCATALYTIC SOLAR DEVICE 审中-公开
    具有闭环光电太阳能装置的发电系统和方法

    公开(公告)号:WO2017155842A1

    公开(公告)日:2017-09-14

    申请号:PCT/US2017/020851

    申请日:2017-03-06

    Abstract: A photocatalytic power generation system including a solar housing, a photoanode, an electrolyte membrane, a cathode, an oxygen diffusion membrane, and an external power generation circuit. The photoanode and the cathode are each positioned within the solar housing and electrically coupled to the external power generation circuit. The electrolyte membrane is positioned between and electrochemically engaged with the photoanode and the cathode forming a photocatalytic cell. The solar housing comprises a closed-loop water chamber having an anode side flow channel, a cathode side flow channel, a recombined water channel, and an oxygen diffusion membrane. Further, the oxygen diffusion membrane is positioned and configured to inhibit recombined water generated at the cathode from flowing from the cathode side to the anode side along the oxygen transport channel and permit recombined water generated at the cathode from flowing from the cathode side to the anode side along the recombined water channel.

    Abstract translation: 包括太阳能外壳,光电阳极,电解质膜,阴极,氧气扩散膜和外部发电电路的光催化发电系统。 光电阳极和阴极各自位于太阳能外壳内并电耦合到外部发电电路。 电解质膜位于光电阳极之间并与光电阳极电化学接合,阴极形成光催化电池。 太阳能外壳包括具有阳极侧流动通道,阴极侧流动通道,复合水通道和氧气扩散膜的闭环水室。 此外,氧扩散膜被定位和配置为抑制在阴极处产生的复合水沿着氧传输通道从阴极侧流向阳极侧,并且允许在阴极处产生的复合水从阴极侧流向阳极 沿着重新组合的水道。

    SULFUR MANAGEMENT AND UTILIZATION IN MOLTEN METAL ANODE SOLID OXIDE FUEL CELLS
    9.
    发明申请
    SULFUR MANAGEMENT AND UTILIZATION IN MOLTEN METAL ANODE SOLID OXIDE FUEL CELLS 审中-公开
    金属阳极固体氧化物燃料电池的硫化物管理与利用

    公开(公告)号:WO2015167794A2

    公开(公告)日:2015-11-05

    申请号:PCT/US2015/025668

    申请日:2015-04-14

    Abstract: Embodiments of a molten metal anode solid oxide fuel cell (MMA-SOFC) system comprise a first and second MMA-SOFC, a fuel contactor integral or in fluid communication with the first MMA-SOFC, a molten metal conduit that delivers molten metal from a first molten metal anode to a second molten metal anode, and one or more external electric circuits, wherein the first molten metal anode oxidizes molten metal to produce metal oxides and electrons. The fuel contactor reduces the metal oxides and produce metals and metal sulfides in the molten metal upon reaction with sulfur-containing fuel. The second molten metal anode oxidizes the metal sulfides in the metal sulfides-containing molten metal to produce metals and electrons, and the external electric circuits generate power from the electrons produced in the first and second MMA-SOFCs.

    Abstract translation: 熔融金属阳极固体氧化物燃料电池(MMA-SOFC)系统的实施方案包括第一和第二MMA-SOFC,与第一MMA-SOFC一体或与流体相通的燃料接触器,从熔融金属阳极固体氧化物燃料电池 第一熔融金属阳极到第二熔融金属阳极,以及一个或多个外部电路,其中第一熔融金属阳极氧化熔融金属以产生金属氧化物和电子。 当与含硫燃料反应时,燃料接触器减少金属氧化物并在熔融金属中产生金属和金属硫化物。 第二熔融金属阳极氧化金属硫化物熔融金属中的金属硫化物以产生金属和电子,并且外部电路从在第一和第二MMA-SOFC中产生的电子产生电力。

    NOVEL MODULAR ELECTROCHEMICAL CELL AND STACK DESIGN

    公开(公告)号:WO2018160317A1

    公开(公告)日:2018-09-07

    申请号:PCT/US2018/016407

    申请日:2018-02-01

    Abstract: An electrochemical cell, electrochemical cell assembly and a method of assembling an electrochemical cell assembly. The cell includes a pair of current collectors that when joined together form a three-dimensional electrode assembly with an ion-exchange membrane disposed between the anode and cathode of the electrode assembly. The current collectors are sized and shaped such that a three-dimensional reactant chamber volume of one of the current collectors accepts nested placement of at least a portion of the three-dimensional reactant chamber volume of the other current collector. This design allows for easy and direct addition, removal or replacement of cells in a stack of such cells in a modular fashion. In addition, ease of mounting and unmounting of the cells on reactant manifolds promotes ease of assembly of two-dimensional or three-dimensional stack structures.

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