公开(公告)号：WO2013169826A1

公开(公告)日：2013-11-14

申请号：PCT/US2013/040012

申请日：2013-05-07

Applicant: SEEO, INC

Inventor： SINGH, Mohit ,  EITOUNI, Hany ,  PRATT, Russell ,  MULLIN, Scott ,  WANG, Xiao-Liang

IPC: H01M4/137 ,  H01M4/525 ,  H01M10/052

CPC classification number: H01M4/624 ,  B05D1/34 ,  H01M4/366 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/622 ,  H01M4/623 ,  H01M10/0525

Abstract: Particles of cathodic materials are coated with polymer to prevent direct contact between the particles and the surrounding electrolyte. The polymers are held in place either by a) growing the polymers from initiators covalently bound to the particle, b) attachment of the already-formed polymers by covalently linking to functional groups attached to the particle, or c) electrostatic interactions resulting from incorporation of cationic or anionic groups in the polymer chain. Carbon or ceramic coatings may first be formed on the surfaces of the particles before the particles are coated with polymer. The polymer coating is both electronically and ionically conductive.

Abstract translation: 用聚合物涂覆阴极材料的颗粒以防止颗粒和周围电解质之间的直接接触。 聚合物通过以下方式保持在适当位置：a）从共价结合到颗粒的引发剂生长聚合物，b）通过共价连接到与颗粒连接的官能团上连接已经形成的聚合物，或c）通过引入 聚合物链中的阳离子或阴离子基团。 在颗粒被聚合物涂覆之前，可以首先在颗粒的表面上形成碳或陶瓷涂层。 聚合物涂层是电子和离子导电的。

公开(公告)号：WO2017058676A1

公开(公告)日：2017-04-06

申请号：PCT/US2016/053587

申请日：2016-09-23

Applicant: SEEO, INC.

Inventor： PRATT, Russell ,  YANG, Jin ,  PISTORINO, Jonathan ,  EITOUNI, Hany Basam ,  SINGH, Mohit ,  VIJAY, Vishal

IPC: H01B1/12 ,  B32B7/00 ,  B32B7/04 ,  H01B1/06

CPC classification number: H01M10/0565 ,  H01M4/382 ,  H01M4/386 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0525 ,  H01M2300/0082

Abstract: Polymer electrolytes incorporating PS-PEO block copolymers, PXE additives, and lithium salts provide improved physical properties relative to PS-PEO block copolymers and lithium salt alone, and thus provide improved battery performance.

Abstract translation: 包含PS-PEO嵌段共聚物，PXE添加剂和锂盐的聚合物电解质相对于PS-PEO嵌段共聚物和单独的锂盐提供了改善的物理性能，因此提供了改进的电池性能。

公开(公告)号：WO2017155836A1

公开(公告)日：2017-09-14

申请号：PCT/US2017/020824

申请日：2017-03-03

Applicant: SEEO, INC.

Inventor： EITOUNI, Hany Basam ,  PISTORINO, Jonathan ,  PRATT, Russell ,  SIVANANDAN, Kulandaivelu

IPC: H01B1/24 ,  H01G9/025 ,  H01M10/052 ,  H01M10/0565 ,  H01M4/13

Abstract: A novel solid block copolymer electrolyte material is described. The material has first structural polymer blocks that make up a structural domain that has a modulus greater than 1 x 10 7 Pa at 25°C. There are also second ionically-conductive polymer blocks and a salt that make up an ionically-conductive domain adjacent to the structural domain. Along with the second ionically-conductive polymers, there is also a crosslinked network of third polymers, which interpenetrates the ionically-conductive domain. The third polymers are miscible with the second polymers. It has been shown that the addition of such an interpenetrating, crosslinked polymer network to the ionically-conductive domain improves the mechanical properties of the block copolymer electrolyte with no sacrifice in ionic conductivity.

Abstract translation: 描述了一种新型固体嵌段共聚物电解质材料。 该材料具有构成结构域的第一结构聚合物嵌段，该结构域在25℃下的模量大于1×10 -7 Pa。 还有第二种离子导电聚合物嵌段和一种盐，其构成邻近结构域的离子导电结构域。 与第二种离子导电聚合物一起，还存在第三种聚合物的交联网络，其互穿了离子导电区域。 第三种聚合物可与第二种聚合物混溶。 已经表明，向离子导电域添加这种互相渗透的交联聚合物网络，改善了嵌段共聚物电解质的机械性能，而不牺牲离子导电性。

公开(公告)号：WO2017117306A1

公开(公告)日：2017-07-06

申请号：PCT/US2016/069041

申请日：2016-12-28

Applicant: SEEO, INC.

Inventor： PISTORINO, Jonathan ,  EITOUNI, Hany Basam ,  PRATT, Russell ,  SINGH, Mohit

IPC: H01M10/056 ,  H01M8/1046 ,  H01M8/1048 ,  H01M10/0562 ,  H01M10/0565

CPC classification number: H01M10/056 ,  H01M10/052 ,  H01M10/0525 ,  H01M2300/0068 ,  H01M2300/0071 ,  H01M2300/0082 ,  H01M2300/0091

Abstract: Composites of lithium-ion-conducting ceramic and polymeric materials make superior separators and electrolytes for use in lithium batteries. The ceramic material provides a high conductivity pathway for lithium-ions, enhancing the properties of the less conductive polymeric material. The polymeric material provides flexibility, binding, and space-filling properties, mitigating the tendency of rigid ceramic materials to break or delaminate. The interface between the polymer and ceramic can be made to have a low ionic resistance through the use of additives and coatings.

Abstract translation: 导电锂离子导电陶瓷和聚合物材料的复合材料使锂离子电池具有卓越的隔膜和电解质。 陶瓷材料为锂离子提供了高导电性路径，增强了导电性较小的聚合物材料的性能。 聚合物材料提供了柔韧性，粘合性和空间填充性，减轻了刚性陶瓷材料破裂或分层的趋势。 通过使用添加剂和涂料，可以使聚合物和陶瓷之间的界面具有较低的离子电阻。

公开(公告)号：WO2015160381A1

公开(公告)日：2015-10-22

申请号：PCT/US2014/062415

申请日：2014-10-27

Applicant: SEEO, INC. ,  ROBERT BOSCH GMBH

Inventor： EITOUNI, Hany ,  FANOUS, Jean ,  MULLIN, Scott ,  PRATT, Russell ,  SIVANANDAN, Kulandaivelu ,  WANG, Xiao-Liang

IPC: H01M4/137

CPC classification number: H01M4/137 ,  H01M4/382 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/0566

Abstract: In a solid-state lithium-metal/sulfur-based battery cell, barriers to sulfur and polysulfide diffusion are included in or used as an ionically conductive electrolyte in the cathode or separator layers. During operation of the battery, the barrier materials are positioned to either 1) rapidly react with any free sulfur or lithium polysulfide species that are generated, forming stable carbon-sulfur bond(s) and preventing further migration of the sulfur or polysulfide species or 2) prevent the formation and diffusion of elemental sulfur or free lithium polysulfide species. Regardless of the identity of the sulfur/polysulfide species, the sulfur-containing species is prevented from diffusing to the anode and causing capacity fade and higher internal resistance to ion flow.

Abstract translation: 在固态锂金属/硫基电池单体中，硫和多硫化物扩散的障碍包括在阴极或隔板层中或用作离子导电电解质。 在电池运行期间，阻隔材料被定位为：1）与任何游离的硫或多硫化物物质快速反应，形成稳定的碳 - 硫键，并防止硫或多硫化物物质的进一步迁移或2 ）防止元素硫或游离锂多硫化物物质的形成和扩散。 不管硫/多硫化物物质的特性如何，防止含硫物质扩散到阳极并导致容量褪色和较高的内部对离子流的阻力。

公开(公告)号：WO2016164505A1

公开(公告)日：2016-10-13

申请号：PCT/US2016/026280

申请日：2016-04-07

Applicant: SEEO, INC.

Inventor： PRATT, Russell ,  WANG, Xiao-Liang ,  LAM, Steven ,  EITOUNI, Hany

IPC: H01M6/16 ,  C08J5/20 ,  C08J5/22 ,  H01M4/13 ,  H01M8/1016 ,  H01M8/1018

CPC classification number: H01M10/0565 ,  C08G65/007 ,  C08G65/331 ,  C08G65/337 ,  H01M10/052 ,  H01M10/054 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0034

Abstract: This invention relates generally to electrolytes for use in electrochemical cells that employ alkali metals, and, more specifically, to fluorinated electrolytes for use in lithium-containing batteries. Perfluoropolyether electrolytes terminated with polar substituents such as cyclic carbonates show enhanced ionic conductivities when formulated with lithium bis(trifluoromethane)sulfonimide, making them useful for use as lithium cell electrolytes.

Abstract translation: 本发明一般涉及用于使用碱金属的电化学电池中的电解质，更具体地说，涉及用于含锂电池的氟化电解质。 用极性取代基如环状碳酸酯封端的全氟聚醚电解质，当与双（三氟甲烷）磺酰亚胺配合时，其离子电导率提高，使其可用作锂电池电解质。

公开(公告)号：WO2016161465A1

公开(公告)日：2016-10-06

申请号：PCT/US2016/025950

申请日：2016-04-05

Applicant: SEEO, INC.

Inventor： PRATT, Russell ,  WANG, Xiao-Liang ,  LAM, Steven ,  EITOUNI, Hany

IPC: H01M6/16 ,  C08J5/20 ,  C08J5/22 ,  H01M4/13 ,  H01M8/1016 ,  H01M8/1018

CPC classification number: H01M10/0569 ,  H01M10/052 ,  H01M10/054 ,  H01M2300/0028

Abstract: This invention relates generally to electrolytes for use in electrochemical cells that employ alkali metals, and, more specifically, to fluorinated electrolytes for use in lithium-containing batteries. Perfluoropolyether electrolytes terminated with polar substituents such as dimethylurethanes show enhanced ionic conductivities when formulated with lithium bis(trifluoromethane)sulfonimide, making them useful for use as lithium cell electrolytes.

Abstract translation: 本发明一般涉及用于使用碱金属的电化学电池中的电解质，更具体地说，涉及用于含锂电池的氟化电解质。 用极性取代基如二甲基氨基甲酸酯封端的全氟聚醚电解质，当与双（三氟甲烷）磺酰亚胺配制时显示增强的离子电导率，使其可用作锂电池电解质。