公开(公告)号：WO2019235983A1

公开(公告)日：2019-12-12

申请号：PCT/SE2018/050593

申请日：2018-06-07

Applicant: SHT SMART HIGH-TECH AB

Inventor： LIU, Johan ,  WANG, Nan

IPC: C01B32/182 ,  B32B9/00 ,  B82Y30/00 ,  B82Y40/00

Abstract: Method of manufacturing a vertically aligned laminated graphene based thermally conductive film. The method comprising: attaching first and second graphene film (200, 202) using a layer of nanoparticles (204) and an adhesive (210); forming (110) a layered film (212) comprising a predetermined number of graphene film layers by repeating the steps of arranging (104) a layer of nanoparticles, arranging (106) an adhesive and attaching (108) a graphene film; and laminating (112) the layered film by applying pressure and heat to cure the adhesive, thereby forming a laminate film (216); cutting (114) the laminate film at an angle in relation to a surface plane of the film to form the vertically aligned laminated graphene based thermally conductive film (218).

公开(公告)号：WO2017217914A1

公开(公告)日：2017-12-21

申请号：PCT/SE2017/050608

申请日：2017-06-08

Applicant: SHT SMART HIGH-TECH AB

Inventor： LIU, Johan

IPC: H01L21/768 ,  B81C1/00 ,  C01B32/16 ,  H01L23/498 ,  H01L51/00 ,  B82Y40/00

CPC classification number: H01L21/486 ,  B81C1/00095 ,  B82Y40/00 ,  C01B32/158 ,  C01B32/16 ,  C01B2202/08 ,  H01L21/76898 ,  H01L23/147 ,  H01L23/481 ,  H01L23/49827 ,  H01L23/49877 ,  H01L2221/1094

Abstract: There is provided a method for manufacturing carbon based via interconnects comprising: providing a first substrate; forming a plurality of catalyst pads on the substrate; growing carbon nanotube (CNT) bundles on the catalyst pads; forming a metal coating on the carbon nanotube bundles comprising a Ti-layer followed by an Au-layer; providing a second substrate; forming via connection through openings in the second substrate, the via connection through openings having the same configuration as the array of catalyst pads; inserting the carbon nanotube bundles into the via connection openings of the second substrate; removing the first substrate such that the carbon nanotube bundles remain in the via connection openings of the second substrate; and infiltrating a metal in the carbon nanotube bundlesby means of copper electroplating

Abstract translation: 提供了一种用于制造碳基通孔互连的方法，包括：提供第一衬底; 在衬底上形成多个催化剂垫; 在催化剂垫上生长碳纳米管（CNT）束; 在包括Ti层和随后的Au层的碳纳米管束上形成金属涂层; 提供第二衬底; 通过所述第二基板中的开口经由连接形成，所述通孔连接通过具有与所述催化剂垫阵列相同构造的开口; 将碳纳米管束插入第二衬底的通孔连接开口中; 移除所述第一衬底，使得所述碳纳米管束保留在所述第二衬底的所述通孔连接开口中; 并通过电镀铜渗入碳纳米管束中的金属

公开(公告)号：WO2017164802A1

公开(公告)日：2017-09-28

申请号：PCT/SE2017/050276

申请日：2017-03-22

Applicant: SHT SMART HIGH-TECH AB

Inventor： LIU, Johan

IPC: B22F9/14 ,  B82Y30/00 ,  B82Y40/00

Abstract: There is provided an apparatus for manufacturing nanoparticles comprising: a container comprising a liquid; an anode and a cathode arranged facing each other in the container, wherein the anode is movable in relation to the cathode; a power supply connected to the anode and the cathode; a current transducer control system comprising a current sensor for detecting a discharge current from an electrostatic discharge between the anode and the cathode, resulting in formation of metal nanoparticles through melting and evaporation of the anode. A motor controls the movement of the anode to control the distance between the anode and the cathode; and a control unit controls the motor to move the anode towards the cathode until a discharge current is detected by the current transducer control system, and when a discharge current is detected,to stop movement of the anode towards the cathode, and to determine a new movement speed and movement direction of the anode based on a consumption rate of the anode such that the discharge is interrupted.

Abstract translation: 提供了一种用于制造纳米颗粒的设备，其包括：包含液体的容器; 在所述容器中彼此面对设置的阳极和阴极，其中所述阳极可相对于所述阴极移动; 连接到阳极和阴极的电源; 电流传感器控制系统，其包括用于检测来自阳极和阴极之间的静电放电的放电电流的电流传感器，导致通过阳极的熔化和蒸发形成金属纳米颗粒。 电机控制阳极的运动以控制阳极和阴极之间的距离; 并且控制单元控制马达以使阳极朝着阴极移动，直到电流换能器控制系统检测到放电电流为止，并且当检测到放电电流时停止阳极朝向阴极的移动并且确定新的 基于阳极的消耗率的阳极的运动速度和运动方向，从而使得放电被中断。

公开(公告)号：WO2016013963A1

公开(公告)日：2016-01-28

申请号：PCT/SE2014/050904

申请日：2014-07-24

Applicant: SHT SMART HIGH TECH AB

Inventor： LIU, Johan

IPC: C01B31/04 ,  C01B33/12

CPC classification number: A61K47/02 ,  B01J21/08 ,  B01J21/18 ,  B01J35/0006 ,  B01J35/026 ,  B01J37/0221 ,  C01B32/23 ,  C01B33/12 ,  C01B33/18 ,  C01P2002/82 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2004/80 ,  C01P2004/84 ,  C09C1/46

Abstract: A process for synthesis of silica coated graphene hybrid material comprising the steps of treating graphene oxide with ammonium ions to provide ammonium- activated graphene oxide; treating the ammonium-activated graphene oxide with a solution comprising silica precursors; and silane coupling agents that comprise functional groups, to provide self-assembly of silica nanoparticles on the surface of the ammonium-activated graphene oxide and covalent bonding between the nanoparticles and the surface to provide silica coated graphene oxide; and grafting of the functional groups on the surface of the silica coated graphene oxide to provide functionalized silica coated graphene oxide; and reducing the functionalized silica coated graphene oxide to provide functionalized silica coated graphene. Silica coated graphene hybrid material obtainable by this process.

Abstract translation: 一种用于合成二氧化硅涂覆的石墨烯混合材料的方法，包括用铵离子处理氧化石墨烯以提供活化氧化铝的氧化石墨烯的步骤; 用包含二氧化硅前体的溶液处理铵活化的石墨烯氧化物; 和硅烷偶联剂，其包含官能团，以在铵活化石墨烯氧化物的表面上提供二氧化硅纳米颗粒的自组装和纳米颗粒与表面之间的共价键，以提供二氧化硅涂覆的石墨烯氧化物; 以及在二氧化硅涂覆的氧化石墨烯的表面上接枝官能团以提供官能化的二氧化硅涂覆的石墨烯氧化物; 并还原官能化的二氧化硅涂覆的氧化石墨烯以提供官能化的二氧化硅涂覆的石墨烯。 通过该方法可获得的二氧化硅涂覆的石墨烯混合材料。

公开(公告)号：WO2019235986A1

公开(公告)日：2019-12-12

申请号：PCT/SE2019/050080

申请日：2019-01-31

Applicant: SHT SMART HIGH-TECH AB

Inventor： LIU, Johan ,  WANG, Nan

IPC: C01B32/182 ,  B32B9/00 ,  B82Y30/00 ,  B82Y40/00

Abstract: Heat sink and method of manufacturing a graphene based heat sink (300), the method comprising: providing (100) a first and second graphene film; arranging (104) a layer of nanoparticles (204) on a surface (206, 208) of the first and second graphene film to improve an adhesion strength between the graphene films; attaching (108) the second graphene film to the first graphene film by means of an adhesive and the layer of nanoparticles; forming (110) a laminated graphene film (212) comprising a number of graphene film layers by repeating the steps, wherein the laminated graphene film (212) is formed to have an anisotropic thermal conductivity; assembling (112) a plurality of laminated graphene films by applying pressure and heat to cure the adhesive to form a graphene block (214); and removing (114) selected portions of the graphene block to form a heat sink comprising fins (304) extending from a base plate (302) of the heat sink.

公开(公告)号：WO2019194708A1

公开(公告)日：2019-10-10

申请号：PCT/SE2018/000009

申请日：2018-04-03

Applicant: SHT SMART HIGH-TECH AB

Inventor： LIU, Johan ,  WANG, Nan

IPC: C01B32/182 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/198 ,  C01B32/20 ,  H01L23/373 ,  H01L29/16

Abstract: The invention relates to a heat spreading structure (100) comprising: a first substrate layer (102); a second substrate layer (104); and a thermally conductive graphite film (106) sandwiched between the first and second substrate layers, wherein the graphite film comprises a plurality of graphene layers having a turbostratic alignment between adjacent graphene layers. The invention also relates to a method for manufacturing a graphite film for a heat spreading structure.

公开(公告)号：WO2019009790A1

公开(公告)日：2019-01-10

申请号：PCT/SE2018/050710

申请日：2018-06-28

Applicant: SHT SMART HIGH-TECH AB

Inventor： LIU, Johan

IPC: C22C49/14 ,  C01B32/182 ,  C22C47/08 ,  H01L23/373 ,  D01D5/00

Abstract: There is provided a method for manufacturing a thermal interface material, the method comprising:forming (100) a porous mat comprising graphene fibers; heating (102) the mat to form a graphite fiber matwhere the graphene based fibers exhibits a turbostratic crystal structure; metal plating (104) of the graphite fiber mat; and metal infiltration (106) of the metal plated graphite fiber mat.

公开(公告)号：WO2018226130A1

公开(公告)日：2018-12-13

申请号：PCT/SE2017/050607

申请日：2017-06-08

Applicant: SHT SMART HIGH-TECH AB

Inventor： LIU, Johan ,  SU, Peng

IPC: C01B32/194 ,  B29C65/48 ,  B65H18/00 ,  C09J5/00 ,  D01F9/12 ,  H01L23/373

Abstract: According a first aspect of the invention, there is provided an arrangement (100) for manufacturing a roll (102) of graphene. The arrangement comprises a supply reel (104) configured to hold a strip of graphene film (106); a winding reel (108) configured to wind a strip of graphene film into a roll of graphene film; a motor controlling the winding reel; and a dispenser (110) configured to dispense a fluid adhesive (112) on a graphene film running from the supply reel to the winding reel. There is also provided a method form manufacturing a graphene film using sing the described arrangement, where the method comprises cutting the manufactures graphene roll into sheets of graphene film.