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公开(公告)号:WO2022268736A1
公开(公告)日:2022-12-29
申请号:PCT/EP2022/066758
申请日:2022-06-20
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: NIESSNER, Norbert , RUTHARD, Christian , MADHAV, Shridhar , GEVARIA, Kirit , AK, Manjula , ROHIT, Pankaj , MISHRA, Saurabh
IPC: C08L25/12 , C08L51/04 , C08L23/08 , C08L2201/08 , C08L2205/025 , C08L2205/03 , C08L2205/035 , C08L23/0853
Abstract: Weather resistant thermoplastic ASA compositions comprising (A): 20 to 80 wt.-% of a polymer mixture (A) consisting of: 35 to 65 wt.-% graft copolymer GR1 (D50 of 55 to 170 nm), composed of: 40 to 80 wt.-% cross-linked C1 to C8 alkyl acrylate graft base G11 and 20 to 60 wt.-% SAN-copolymer graft shell G12; and 65 to 35 wt.-% SAN copolymer S1 (MVR 50 to 70 ml/10 min); (B): 5 to 35 wt.-% polymer mixture (B) consisting of: 35 to 65 wt.-% graft copolymer GR2 (D50 of 410 to 1000 nm), composed of: 40 to 80 wt.-% cross-linked C1 to C8 alkyl acrylate graft base G21 and 20 to 60 wt.-% SAN-copolymer graft shell G22; and 65 to 35 wt.-% SAN copolymer S2 (MVR 11 to 25 ml/10 min); (C): 10 to 40 wt.-% of at least one SAN copolymer (C) (MVR 11 to 70 ml/10 min); (D): 1 to 15 wt.-% EVA copolymer (D) (VA > 25 wt.-%); are particularly useful e.g. in the automotive industry.
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2.
公开(公告)号:WO2021074155A1
公开(公告)日:2021-04-22
申请号:PCT/EP2020/078789
申请日:2020-10-13
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: RUTHARD, Christian , CARSTENSEN, Oliver , CHAMBOST, Eric
Abstract: The invention relates to a thermoplastic molding composition (P) comprising: (A) 81.1 to 99.7 wt.-% of at thermoplastic polymer composition (A) comprising: (A-1) graft copolymer (A-1), and (A-2) thermoplastic matrix (A-2) based on vinylaromatic copolymers; (B) at least one hindered amine light stabilizing composition (B) comprising: (B-1) 0.2 to 0.9 wt.-%, of at least one hindered amine light stabilizer having a dipiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the dipiperidine structure and (B-2) 0.1 to 0.9 wt.-%, of a hindered amine light stabilizer mixture having a monopiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the monopiperidine structure and (B-3) 0 to 2 wt.-%, of at least one hindered amine light stabilizer having a polymeric structure comprising piperidine groups with at least one alkyl group at each of the 2 and 6 positions of the piperidine groups, (C) 0 to 10 wt.-%, of colorants, dyes and/or pigments (C); and (D) 0 to 5 wt.-%, of further additives (D) different from (B) and (C); provided that the thermoplastic molding composition (P) further comprises 0.001 wt.-% to 0.1 wt.-%, based on the total weight of the molding composition (P), of oligomers and/or polymers comprising ethylene and/or propylene repeating units or provided that the thermoplastic molding composition (P) further comprises 0 wt.-%, based on the total weight of the molding composition (P), of oligomers and/or polymers comprising ethylene and/or propylene repeating units (as component E), wherein the constituents (A) to (E) sum up to 100 wt.-% of the molding composition (P).
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公开(公告)号:WO2020020834A1
公开(公告)日:2020-01-30
申请号:PCT/EP2019/069698
申请日:2019-07-22
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: SCHULZ, Tobias , FISCHER, Wolfgang , NIESSNER, Norbert , RUTHARD, Christian , KERSCHBAUMER, Hannes
IPC: C08F257/02 , C08L25/12 , C08L51/04 , C08K5/00 , C08F285/00
Abstract: Thermoplastic molding composition comprising a graft copolymer B with core-shell structure having a particle diameter d w of 280 to 450 nm, comprising a core B1 and three layers B2 to B4: B1 : 6 to 19 wt.-% of a core B1 comprising crosslinked polystyrene; B2: 41 to 54 wt.-% of a first layer B2 of a crosslinked acrylate polymer; B3: 1 to 19 wt.-% of a second layer B3 of polystyrene; and B4: 21 to 39 wt.-% of a third layer B4 consisting of SAN copolymer.
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4.
公开(公告)号:WO2015000873A1
公开(公告)日:2015-01-08
申请号:PCT/EP2014/063907
申请日:2014-07-01
Applicant: STYROLUTION GROUP GMBH
Inventor: NIESSNER, Norbert , BANASZAK, Brian J. , VERSTRAETEN, Rudy , MICHELS, Gisbert , FISCHER, Wolfgang , RUTHARD, Christian , JANSEN, Ulrich
CPC classification number: C08L25/12 , B29B7/18 , B29B7/46 , B29B7/48 , B29C47/402 , B29C47/6056 , B29C47/64 , B29C47/761 , B29C47/92 , B29C2947/92209 , B29C2947/92704 , C08L55/02
Abstract: A process for preparing a thermoplastic polymer composition or a thermoplastic polymer blend, comprising: - from 20 to 80 % by weight of at least one water-moist elastomer component A containing up to 40 %, preferably up to 30 % by weight of residual water, - from 20 to 80 % by weight of at least one thermoplastic polymer B, - from 0 to 40 % by weight of at least one further polymer C, and - from 0 to 60% by weight of additive(s) D, by mixing the elastomer component A with the thermoplastic polymer B and, if present, the further polymer C and, if present, the additive(s) D in an extruder, comprising the steps of precipitating the elastomer component A, and mechanical dewatering of the elastomer component A leads to improved salt-free products.
Abstract translation: 一种制备热塑性聚合物组合物或热塑性聚合物共混物的方法,包括: - 20至80重量%的至少一种含水多至40重量%,优选至多30重量%的残余水的水润滑性组分A , - 20至80重量%的至少一种热塑性聚合物B, - 0至40重量%的至少一种其它聚合物C和0至60重量%的添加剂D,由 将弹性体组分A与热塑性聚合物B混合,如果存在的话,将挤出机中的另外的聚合物C和添加剂D存在,包括沉淀弹性体组分A的步骤和弹性体的机械脱水 组分A导致改进的无盐产品。
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公开(公告)号:WO2021074154A1
公开(公告)日:2021-04-22
申请号:PCT/EP2020/078786
申请日:2020-10-13
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: RUTHARD, Christian
Abstract: The invention relates to a thermoplastic molding composition (P) comprising: (A) thermoplastic polymer composition (A) comprising: (A-1) 10 to 50 wt.-% of graft copolymer (A-1), (A-2) 1 to 50 wt.-%, of thermoplastic polymer matrix (A-2) based on one or more vinylaromatic copolymers, (A-3) 20 to 50 wt.-%, of polymerized alkyl methacrylate component (A-3), and (A-4) 0 to 45 wt.-% of comonomer which is copolymerized with the at least one polymerized alkyl methacrylate component (A-3), where the sum of (A-1), (A-2), (A-3) and optional comonomers (A-4) is 83.2 to 99.8 wt.-%; (B) a hindered amine light stabilizer composition (B), comprising at least two of substances (B-1) to (B-3): (B-1) 0 to 0.9 wt.-%, of at least one hindered amine light stabilizer having a dipiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the dipiperidine structure (B-2) 0 to 0.9 wt.-%, of a hindered amine light stabilizer mixture having a monopiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the monopiperidine structure, and (B-3) 0 to 2 wt.-%, of at least one hindered amine light stabilizer having a polymeric structure comprising piperidine groups with at least one alkyl group at each of the 2 and 6 positions of the piperidine groups (C) 0 to 5 wt.-%, of one or more further additives (C), different from (B); and (D) 0 to 10 wt.-%, of colorants, dyes and/or pigments (D), different from (C); wherein the constituents (A) to (D) sum up to 100 wt.-% of the molding composition (P).
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公开(公告)号:WO2021074152A1
公开(公告)日:2021-04-22
申请号:PCT/EP2020/078783
申请日:2020-10-13
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: RUTHARD, Christian
IPC: B60R1/06 , B60R19/52 , C08K5/00 , C08K5/3435 , C08L25/12
Abstract: The invention relates to a molding composition (P) comprising: (A) 83.2 to 98.5 wt.-% of a thermoplastic polymer composition (A) comprising: (A-1) at least one graft copolymer (A-1), and (A-2) at least one thermoplastic matrix polymer (A-2) based on one or more vinylaromatic copolymers; (B) 1.5 to 3 wt.-% of carbon black (B) or a mixture of carbon blacks (B); (C) a hindered amine light stabilizer composition (C), comprising at least two of substances (C-1) to (C-3): (C-1) 0 to 0.9 wt.-%, based on the total weight of the molding composition (P), of at least one hindered amine light stabilizer having a dipiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the dipiperidine structure, (C-2) 0 to 0.9 wt.-% of a hindered amine light stabilizer mixture having a monopiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the monopiperidine structure and (C-3) 0 to 2 wt.-%, of at least one hindered amine light stabilizer having a polymeric structure comprising piperidine groups with at least one alkyl group at each of the 2 and 6 positions of the piperidine groups provided that the at least one hindered amine light stabilizer composition (C) is present in the molding composition (P) in an amount of at least 0.2 wt.-%; (D) 0 to 5 wt.-%, of one or more further additives (D), different from (B) and (C); and (E) 0 to 5 wt.-%, of one or more further colorants, dyes or pigments (E), different from (B) and (D); wherein the constituents (A) to (E) sum up to 100 wt.-% of the molding composition (P).
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7.
公开(公告)号:WO2021074151A1
公开(公告)日:2021-04-22
申请号:PCT/EP2020/078778
申请日:2020-10-13
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: RUTHARD, Christian
Abstract: The invention relates to a molding composition (P) comprising: (A) 81.7 to 99.4 wt.-% of at least one thermoplastic polymer composition (A); (B) at least one hindered amine light stabilizing composition (B) comprising: (B-1) 0.1 to 0.9 wt.-% of a hindered amine light stabilizer mixture having a monopiperidine structure, (B-2) 0 to 0.4 wt.-% of at least one hindered amine light stabilizer having a dipiperidine structure with at least one alkyl group at each of the 2 and 6 positions of the dipiperidine structure and (B-3) 0.5 to 2 wt.-% of at least one hindered amine light stabilizer having a polymeric structure comprising piperidine groups (C) 0 to 10 wt.-% of one or more colorants, dyes and/or pigments (C); and (D) 0 to 5 wt.-%, based on the total weight of the molding composition (P), of one or more further additives (D); wherein constituents (A) to (D) sum up to 100 wt.-% of molding composition (P).
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8.
公开(公告)号:WO2020020831A1
公开(公告)日:2020-01-30
申请号:PCT/EP2019/069693
申请日:2019-07-22
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: SCHULZ, Tobias , FISCHER, Wolfgang , NIESSNER, Norbert , RUTHARD, Christian , KERSCHBAUMER, Hannes
IPC: C08F265/06 , C08L25/12 , C08L51/04
Abstract: Polyacrylate graft rubber copolymer B and an impact modified thermoplastic molding composition thereof, where the graft copolymer B is composed of: B1 : 50 to 70 wt.-% crosslinked acrylate polymer graft base B1 B2: 30 to 50 wt.-% graft shell B2 comprising a first layer B21 of vinylaromatic monomers, and a second layer B22 of vinylaromatic monomers B21-1 and nitrile monomers B22-2; wherein the particle diameter dw of the graft base B1 is 255 to 290 nm; the fraction of B21 is 10 to 26 wt.-%; and the amount of B22-2, is 20 to 30 wt.-%.
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公开(公告)号:WO2019243105A1
公开(公告)日:2019-12-26
申请号:PCT/EP2019/065109
申请日:2019-06-11
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: SCHULZ, Tobias , RUTHARD, Christian
Abstract: INEOS Styrolution Group GmbH 4 SL18/71689PC11June2019 Thermoplastic compositions with improved UV resistance Abstract The present invention relates to a method of improving UV resistance of a vinylaro- maticmolding mass by means of compounding a thermoplastic polymer composition which comprises at least one graft copolymer with an organopolysiloxane compound and optionally further components.
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