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    WATER-BORNE AQUEOUS EPOXY-ESTER/ACRYLATE AND POLY(URETHANE-UREA) BASED CROSSLINKED RESINS
    2.
    发明申请
    WATER-BORNE AQUEOUS EPOXY-ESTER/ACRYLATE AND POLY(URETHANE-UREA) BASED CROSSLINKED RESINS 审中-公开
    水性水性环氧酯/丙烯酸酯和聚（URETHANE-UREA）的交联树脂

    公开(公告)号：WO2003046039A1

    公开(公告)日：2003-06-05

    申请号：PCT/US2001/046120

    申请日：2001-11-28

    Applicant: SUN CHEMICAL CORPORATION

    Inventor： ARCURIO, Ralph ,  CZARNECKI, Richard ,  LUCCI, Sam ,  SIMONI-TRUNCELLITO, Jeannette

    IPC: C08G18/08

    CPC classification number: C09D11/10 ,  C08G18/0823 ,  C08G18/12 ,  C09D11/102 ,  C08G18/3228

    Abstract: A water based dual crosslinked resin and printing inks derived therefrom containing (a) a water borne epoxy/ester/acrylate copolymer having reactive keto groups and thylenic unstaruation and (b) a poly(urethane/urea) having terminal amino groups; whre the crosslinking occurs between the reactive keto and terminal amino groups. The resin also contains onium carboxylate salt groups derived from carboxylic acid groups, ammonia or volatile amine so that the crosslinking system is neither neutral nor basic.

    Abstract translation: 一种水基双交联树脂和由其衍生的印刷油墨，其含有（a）具有反应性酮基和亚稳非离子的水性环氧/酯/丙烯酸酯共聚物和（b）具有末端氨基的聚（氨基甲酸酯/脲） 在反应性酮基和末端氨基之间发生交联。 树脂还含有衍生自羧酸基团的羧酸盐盐基团，氨或挥发性胺，使得交联体系既不中性也不是碱性的。

    HIGH BIO-RENEWABLE CONTENT INKS AND RESINS
    5.
    发明申请
    HIGH BIO-RENEWABLE CONTENT INKS AND RESINS 审中-公开

    公开(公告)号：WO2021231829A1

    公开(公告)日：2021-11-18

    申请号：PCT/US2021/032393

    申请日：2021-05-14

    Applicant: SUN CHEMICAL CORPORATION

    Inventor： ROSEN, Josie M. ,  VANOUDENHOVEN, Guy ,  ARCURIO, Ralph

    IPC: C08L93/04 ,  C09D193/04 ,  C09D11/02 ,  C09D11/03 ,  C09D11/08

    Abstract: The present invention provides novel anionic modified rosin ester resins having a high BRC content, up to 100% BRC. The resins of the present invention are useful as emulsion, dispersion, or solution resins. High BRC content pigment grind vehicles, coatings, and finished inks can be prepared using the resins of the present invention. Advantageously, the finished inks of the present invention have equal to or superior properties compared to current commercially available inks sold as sustainable products, but having little to no BRC content. The present invention represents a significant step towards developing sustainable inks and coatings that are better for the environment.

    WATER-BASED COATINGS
    6.
    发明申请
    WATER-BASED COATINGS 审中-公开
    水基涂料

    公开(公告)号：WO2015112334A3

    公开(公告)日：2015-07-30

    申请号：PCT/US2015/010432

    申请日：2015-01-07

    Applicant: SUN CHEMICAL CORPORATION ,  MARSHALL, Bruce ,  SCHMIDT, Mike ,  ARCURIO, Ralph

    Inventor： MARSHALL, Bruce ,  SCHMIDT, Mike ,  ARCURIO, Ralph

    IPC: C09D11/02 ,  C09D11/10

    Abstract: The present invention is directed to a water-based printing ink or coating composition comprising an acrylic resin emulsion and an epoxy ester resin dispersion. The present invention also provides a process for preparing the printing ink or coating composition comprising forming an emulsion of an acrylic resin having the general formula I by copolymerizing monomers in water, forming an epoxy ester resin dispersion by adding the epoxy ester resin to a solvent and combining the acrylic resin emulsion and the epoxy resin ester dispersion to provide the composition. Finally the present invention provides a process for preparing an article with a coating or an ink printed thereon which comprises applying the ink or coating composition to a surface of an article and drying the composition. The compositions exhibit a high degree of alkali resistance, acid resistance and/or water softener resistance.

    Abstract translation: 本发明涉及包含丙烯酸树脂乳液和环氧酯树脂分散体的水基印刷油墨或涂料组合物。 本发明还提供了一种制备印刷油墨或涂料组合物的方法，包括通过在水中共聚单体形成具有通式I的丙烯酸树脂的乳液，通过将环氧酯树脂加入到溶剂中形成环氧酯树脂分散体，和 合并丙烯酸树脂乳液和环氧树脂酯分散液以提供组合物。 最后，本发明提供了制备其上印有涂层或油墨的制品的方法，该方法包括将油墨或涂料组合物施加到制品的表面并干燥该组合物。 该组合物表现出高度的耐碱性，耐酸性和/或耐水软化剂性。

    POLAR FUNCTIONAL NON-AQUEOUS ACRYLIC DISPERSIONS
    8.
    发明申请
    POLAR FUNCTIONAL NON-AQUEOUS ACRYLIC DISPERSIONS 审中-公开
    极性功能性非水性丙烯酸分散体

    公开(公告)号：WO2017160728A1

    公开(公告)日：2017-09-21

    申请号：PCT/US2017/022112

    申请日：2017-03-13

    Applicant: SUN CHEMICAL CORPORATION

    Inventor： PARRIS, Juanita, M. ,  OMIZU, Soichiro ,  WEISBECKER, Carl, S. ,  ROSEN, Josie, M. ,  ARCURIO, Ralph

    IPC: C09D131/02 ,  C08F18/00 ,  C08F18/04 ,  C08F218/00 ,  C08F218/04 ,  C09D131/00

    Abstract: Described herein is a polar non-aqueous dispersion comprising polar polymeric microparticles in a polar non-aqueous medium, the polar polymeric microparticles being insoluble in the medium and being produced by dispersion polymerization of vinyl monomers such as acrylate monomers in the medium in the presence of a polymeric acrylic stabilizer. Inks, coatings and overprint varnishes are formulated that employ the polar non-aqueous dispersion. Such inks, etc., exhibit superior chemical resistance properties, for example in one-part and two-part systems.

    Abstract translation: 本文描述了极性非水分散体，其在极性非水性介质中包含极性聚合物微粒，所述极性聚合物微粒不溶于介质并且通过乙烯基单体如丙烯酸酯的分散聚合制备 单体在聚合物丙烯酸类稳定剂存在下在介质中进行。 配制使用极性非水分散体的油墨，涂料和罩印清漆。 这种油墨等表现出优异的耐化学性能，例如在单组分和双组分体系中。

    URETHANE-COMPATIBLE POLYESTER ADHESION PROMOTERS
    9.
    发明申请
    URETHANE-COMPATIBLE POLYESTER ADHESION PROMOTERS 审中-公开
    URETHANE兼容聚酯粘合促进剂

    公开(公告)号：WO2015112528A1

    公开(公告)日：2015-07-30

    申请号：PCT/US2015/012133

    申请日：2015-01-21

    Applicant: SUN CHEMICAL CORPORATION ,  ARCURIO, Ralph ,  CHUDOLIJ, Alex ,  KRISHNAN, Ramasamy ,  SCHNEIDER, Mark ,  HUNT, Paul ,  SMALES, Paul

    Inventor： ARCURIO, Ralph ,  CHUDOLIJ, Alex ,  KRISHNAN, Ramasamy ,  SCHNEIDER, Mark ,  HUNT, Paul ,  SMALES, Paul

    IPC: C09D11/10

    CPC classification number: C08G63/199 ,  C08G18/4241 ,  C08G18/4263 ,  C08G63/52 ,  C08G63/54 ,  C08G63/78 ,  C09D11/104

    Abstract: The present invention concerns polyester resins of General Formula I (HO-[R 1 R 2 C(CH 2 -)] a [- OCOC x H y CO 2 -] b [-C p H z O-] c -H) or General Formula II (HO-[R 1 R 2 C(CH 2 -) 2 ] a [-OCOC x H y CO 2 -] b [- CH 2 CR 3 (CO 2 H)CH 2 O] d -H), wherein R 1 , R 2 , a, b, c, d, x, y, p, and z are as defined herein, for use in inks and coating compositions. The polyester resins of the present invention are particularly, but not exclusively, suitable to enhance the adhesion between a printing ink or coating composition and a substrate, especially a plastic substrate, to which it is applied. The polyester adhesion promoters of the invention are compatible with urethane-based inks and coating compositions.

    Abstract translation: 本发明涉及通式I的聚酯树脂（HO- [R 1 R 2 C（CH 2 - ）] a [-OCOC x H y CO 2] b [ - C 10 H 10] c H）或通式II（HO- [R 1 R 2 C（CH 2 - ）2] a [-OCOC x H y CO 2] b [-CH 2 CR 3（CO 2 H）CH 2 O] dH），其中R 1，R 2，a，b，c，d，x，y，p和z如本文所定义，用于油墨和涂料组合物 。 本发明的聚酯树脂特别但不排他地适合于增强印刷油墨或涂料组合物与其所用的基材，特别是塑料基材之间的粘合性。 本发明的聚酯粘合促进剂与氨基甲酸酯类油墨和涂料组合物相容。

    SOLVENT SOLUBLE POLY(URETHANE/UREA) RESINS
    10.
    发明申请
    SOLVENT SOLUBLE POLY(URETHANE/UREA) RESINS 审中-公开

    公开(公告)号：WO2002038643A3

    公开(公告)日：2002-05-16

    申请号：PCT/US2001/045556

    申请日：2001-11-01

    Applicant: SUN CHEMICAL CORPORATION

    Inventor： ARCURIO, Ralph ,  ROCCO, Mark ,  SLAVINSKI, David, J. ,  SCHNEIDER, Mark

    IPC: C08G18/08

    Abstract: Solvent based poly(urethane/urea) resins suitable for formulating flexographic and gravure laminating printing ink and coating compositions formed from a poly(urethane) prepolymer solution made from a blend of polymeric diols and diols reacted with diisocyanates and then with diamine in an organic solvent. The resin is prepared by adding the poly(urethane) prepolymer solution at a controlled rate to the diamine in a organic solvent which allows a resin solution to be formed, which may be used in the formulation of laminating printing ink and coating compositions without the need for adjuvants, grinding in polyvinyl butyral or blending with nitrocellulose base.

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