公开(公告)号：WO2018160941A1

公开(公告)日：2018-09-07

申请号：PCT/US2018/020622

申请日：2018-03-02

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  TDA RESEARCH, INC.

发明人： BAI, Chuansheng ,  CUNNINGHAM, Majosefina ,  MCCALL, Patrick P. ,  THOMANN, Hans ,  ELLIOTT, Jeannine Elizabeth ,  NGUYEN, Vinh

IPC分类号： B01J20/00 ,  B01J20/02 ,  B01J20/04 ,  B01J20/32 ,  B01J23/00 ,  B01J23/04

CPC分类号： B01J20/041 ,  B01D53/02 ,  B01D53/0462 ,  B01D2253/1124 ,  B01D2253/25 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2259/40086 ,  B01J20/08 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/3433 ,  B01J20/3466 ,  Y02C10/08

摘要： The disclosure generally relates to CCS sorbents, particularly for CO 2 /H 2 O displacement desorption process. The sorbents include an aluminum oxide support that includes two alkali metal salts impregnated on the support. The two alkali metals include a potassium metal salts and a second alkali metal salt which is not potassium. The second metal salt disrupts poisoning effects that degrade sorbent lifetime. The sorbents demonstrate improved CO 2 loadings and better H 2 O/CO 2 ratios, as well as improved stability. Compositions and methods of making are disclosed.

公开(公告)号：WO2021262323A2

公开(公告)日：2021-12-30

申请号：PCT/US2021/030707

申请日：2021-05-04

申请人： TDA RESEARCH, INC.

发明人： NGUYEN, Vinh ,  DIETZ, Steven, Dean ,  SRINIVAS, Girish

IPC分类号： B01J23/42 ,  B01J35/00 ,  B01J35/10 ,  B01J23/00 ,  C01B32/00 ,  C25B1/04 ,  C25B11/031 ,  C25B11/054 ,  C25B11/065 ,  C25B11/081 ,  C25B15/00

摘要： A porous carbon-platinum electrocatalyst made from a carbon matrix-platinum composite, which has a carbon support and platinum is deposited into the pores of the carbon support. The platinum is at least 2 weight% of the carbon matrix-platinum composite. The carbon support has a nitrogen BET surface area of about 550 to 1800 m2/g; a packing density of at least 0.8 g/cc as determined at a compressive force of 500 kgf/cm2 on dry carbon powder; and an electrical conductivity of at least 10 S/cm at a compressive force of 500 kgf/cm2 on dry carbon powder. Also, an electrolyzer, comprising: the porous carbon-platinum electrocatalyst, wherein the electrolyzer has a Tafel slope of at most 40 mV / decade.

公开(公告)号：WO2018160956A1

公开(公告)日：2018-09-07

申请号：PCT/US2018/020651

申请日：2018-03-02

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  TDA RESEARCH, INC.

发明人： BAI, Chuansheng ,  CUNNINGHAM, Majosefina ,  MCCALL, Patrick P. ,  THOMANN, Hans ,  ELLIOTT, Jeannine Elizabeth ,  NGUYEN, Vinh

IPC分类号： B01J20/04 ,  B01J20/08 ,  B01J20/30 ,  B01J20/32 ,  B01D53/02 ,  B01D53/62

CPC分类号： B01J20/041 ,  B01D53/02 ,  B01D53/0462 ,  B01D2253/1124 ,  B01D2253/25 ,  B01D2257/504 ,  B01D2259/40083 ,  B01D2259/4009 ,  B01J20/08 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/3433 ,  B01J20/3466

摘要： The disclosure generally relates to CCS sorbents, particularly for CO 2 /H 2 O displacement desorption process. The sorbent includes an aluminum oxide support and an alkali metal salt impregnated on the support. The support can be prepared by creating and extruding a dough to create an extrudate, which is then drying and calcined to form the support. Calcination temperatures can be between about 120°C and 500°C, preferably about 200°C to about 400°C. The sorbents demonstrate improved CO 2 loadings and better H 2 O/CO 2 ratios, as well as improved stability. Compositions and methods of making are disclosed.

公开(公告)号：WO2018160952A1

公开(公告)日：2018-09-07

申请号：PCT/US2018/020639

申请日：2018-03-02

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  TDA RESEARCH, INC.

发明人： BAI, Chuansheng ,  CUNNINGHAM, Majosefina ,  MCCALL, Patrick P. ,  THOMANN, Hans ,  ELLIOTT, Jeannine Elizabeth ,  NGUYEN, Vinh

IPC分类号： B01J20/04 ,  B01J20/08 ,  B01J20/10 ,  B01J20/22 ,  B01J20/30 ,  B01J20/32 ,  B01D53/02 ,  B01D53/62

CPC分类号： B01J20/041 ,  B01D53/02 ,  B01D2253/104 ,  B01D2253/106 ,  B01D2253/1124 ,  B01D2253/20 ,  B01D2253/25 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2259/40086 ,  B01J20/08 ,  B01J20/103 ,  B01J20/22 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3234 ,  B01J20/3433 ,  B01J20/3466

摘要： The disclosure generally relates to CCS sorbents, particularly for CO 2 /H 2 O displacement desorption process. The sorbent includes an aluminum oxide support and an alkali metal salt impregnated on the support, and a silicon modification of the sorbent to reduce water uptake by the sorbent and make it more hydrophobic. The silicon modification can be an organosilyl moiety added after the initial sorbent is complete, or a silica source added to the aluminum oxide structure, typically via impregnation. The sorbents demonstrate better H 2 O/CO 2 ratios. Compositions and methods of making are disclosed.

公开(公告)号：WO2018160934A1

公开(公告)日：2018-09-07

申请号：PCT/US2018/020606

申请日：2018-03-02

申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  TDA RESEARCH, INC.

发明人： BAI, Chuansheng ,  CUNNINGHAM, Majosefina ,  MCCALL, Patrick, P. ,  THOMANN, Hans ,  ELLIOTT, Jeannine, Elizabeth ,  NGUYEN, Vinh

IPC分类号： B01J20/02 ,  B01J20/04 ,  B01J20/32 ,  B01J23/00 ,  B01J23/04

CPC分类号： B01J20/08 ,  B01D53/02 ,  B01D2253/1124 ,  B01D2257/504 ,  B01D2258/0283 ,  B01J20/041 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  Y02C10/08

摘要： The disclosure generally relates to CCS sorbents, particularly for CO 2 /H 2 O displacement desorption process. The sorbents include an aluminum oxide support that includes alkali metal salts within the support, in the form of pseudo alkali aluminate. The sorbents also include alkali metal salt impregnated on the support. The sorbents demonstrate improved CO 2 loadings and better H 2 O/CO 2 ratios, as well as improved stability. Compositions and methods of making are disclosed.