公开(公告)号：WO2015191811A1

公开(公告)日：2015-12-17

申请号：PCT/US2015/035259

申请日：2015-06-11

Applicant: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.

Inventor： RICHARDSON, David, Ernest

IPC: B01J20/26 ,  C08J3/075 ,  C08L29/04

CPC classification number: A61L2/18 ,  A01N59/00 ,  A61L2/232 ,  A61L2/235 ,  A61L2202/11 ,  C11D17/049 ,  A01N25/34

Abstract: A disinfectant appliance has a plurality of chlorite absorbent particles, a plurality of redox resin particles, and at least one absorbent material combined such that the absorbent material allows and can promote: infusion of water into the disinfectant appliance; release of the chlorite from the chlorite absorbent particles into the water to form a chlorite comprising solution; contacting of the chlorite comprising solution with the redox resin particles; and the expulsion of CIO 2 comprising solution from the disinfectant appliance onto a surface to be disinfected. The disinfectant appliance can include a storage section and can include a handle. The disinfectant appliance can be in the form of a wipe or sponge that can be contacted with a surface suspected of being infected.

Abstract translation: 消毒器具具有多个亚氯酸盐吸收剂颗粒，多个氧化还原树脂颗粒和至少一种吸收材料组合，使得吸收材料允许并且可促进：将水注入消毒器具; 将亚氯酸盐从亚氯酸盐吸收剂颗粒释放到水中以形成含有亚氯酸盐的溶液; 含亚氯酸盐溶液与氧化还原树脂颗粒的接触; 并将包含溶液的CIO2从消毒器具排出到待消毒的表面上。 消毒器具可以包括存储部分，并且可以包括把手。 消毒器具可以是可以与怀疑被感染的表面接触的擦拭物或海绵的形式。

公开(公告)号：WO2014138000A1

公开(公告)日：2014-09-12

申请号：PCT/US2014/020178

申请日：2014-03-04

Applicant: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.

Inventor： RICHARDSON, David, Ernest

IPC: A61L2/16 ,  A61L2/18

CPC classification number: C01B11/024 ,  A01N59/00 ,  A61L2/18 ,  A61L9/014 ,  A61L2209/133

Abstract: A chlorite salt-absorbent particle is prepared by absorbing a water soluble chlorite salt or a concentrated chlorite salt solution in an absorbent particle. The absorbent can be a silica gel particle or other particulate absorbent that can release the chlorite salt as an aqueous solution over time by simply contacting the chlorite salt-absorbent particle with water. The chlorine salt is extracted from the chlorite salt-absorbent particle over a period of minutes while being flushed with water. A chlorine dioxide generator in the form of a cartridge includes the chlorite salt-absorbent particles and an acid resin or a redox resin. Water can be introduced into an inlet of the cartridge and passes sequentially through the chlorite salt-absorbent particles and the acid resin or the redox resin with the discharge of a chlorine dioxide solution from the outlet of the cartridge.

Abstract translation: 通过吸收吸收颗粒中的水溶性亚氯酸盐或浓缩的亚氯酸盐溶液来制备亚氯酸盐吸收性颗粒。 吸收剂可以是硅胶颗粒或其它颗粒吸收剂，其可以通过简单地将亚氯酸盐吸收性颗粒与水接触来随着时间的推移作为水溶液释放亚氯酸盐。 在用水冲洗的同时，经过数分钟的时间，从亚氯酸盐吸收性粒子中提取氯盐。 筒形二氧化氯发生器包括亚氯酸盐吸收性颗粒和酸性树脂或氧化还原树脂。 可以将水引入盒的入口并顺次通过亚氯酸盐吸收性颗粒和酸性树脂或氧化还原树脂，同时从盒的出口排出二氧化氯溶液。

公开(公告)号：WO2014028485A1

公开(公告)日：2014-02-20

申请号：PCT/US2013/054724

申请日：2013-08-13

Applicant: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.

Inventor： RICHARDSON, David, Ernest

IPC: C08F8/18 ,  C08F14/00 ,  C08L27/00 ,  C08F12/08 ,  B01J41/14

CPC classification number: B01J41/14 ,  B01J41/05 ,  B01J47/12 ,  C02F1/42 ,  C02F1/76 ,  C08F8/18 ,  C08F212/08

Abstract: A method of preparing a trihalide resin, where a trihalide ion solution is contacted with a styrene divinylbenzene polymer resin having polymer bonded -ER 3 + X - groups where E is N, P, or As, R is a hydrocarbon group and X is C1, Br, or I. The trihalide ion can be C1 3 - , Br 3 - or I 3 - . A trichloride resin and a method of preparing the trichloride resin, where a styrene divinylbenzene polymer resin having polymer bonded -ER 3 + C1 - groups is contacted with chlorine. The trichloride resin can be used as a solid equivalent of chlorine gas. Formation of the styrene divinylbenzene resin comprising -ER 3 + C1 - units can be used to scavenge chlorine from a gas or liquid to form the styrene divinylbenzene resin comprising - ER 3 + C1 3 - units.

Abstract translation: 一种制备三卤化物树脂的方法，其中三卤离子溶液与具有聚合物键合-ER3 + X-基团的苯乙烯二乙烯基苯聚合物树脂接触，其中E为N，P或As，R为烃基，X为C1，Br ，或I.三卤化物离子可以是C13 - ，Br3 - 或I3 - 。 三氯化物树脂和制备三氯化物树脂的方法，其中具有聚合物键合-ER 3 + C 1 - 基团的苯乙烯二乙烯基苯聚合物树脂与氯接触。 三氯化物树脂可以用作氯气的固体当量。 包含-ER3 + C1-单元的苯乙烯二乙烯基苯树脂的形成可用于从气体或液体中清除氯，以形成包含-E3 + C13-单元的苯乙烯二乙烯基苯树脂。

公开(公告)号：WO2007065103A3

公开(公告)日：2007-06-07

申请号：PCT/US2006/061335

申请日：2006-11-29

Applicant: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC. ,  RICHARDSON, David, Ernest ,  DENEVAN, Daniel ,  RAMDON, Dwight

Inventor： RICHARDSON, David, Ernest ,  DENEVAN, Daniel ,  RAMDON, Dwight

IPC: C01B11/02

Abstract: An on-demand portable chlorine dioxide generator has a reagent bound medium in a first enclosed volume; a complementary reagent solution in a second enclosed volume, and a structure for selecting between a first position where the complementary reagent solution is forced through the reagent bound medium and a second position where said complementary reagent solution remains isolated from the reagent bound ion exchange medium, where a ClO 2 solution is generated only during periods when the structure for forcing is actuated. The ClO 2 solution can be discharged for use as a portable sprayer that can be used to treat surfaces infected by anthrax or other biological contaminants. When the bound reagent is chlorite, the complementary reagent is an acid or an oxidant. When the bound reagent is an acid or an oxidant, the complementary reagent solution is a chlorite solution.