公开(公告)号：WO2023069236A1

公开(公告)日：2023-04-27

申请号：PCT/US2022/045003

申请日：2022-09-28

Applicant: UNIVERSITY OF SOUTHERN CALIFORNIA

Inventor： GOEPPERT, Alain ,  KOCH, Christopher J. ,  PRAKASH, G.K. Surya ,  SEN, Raktim

IPC: C10L3/08 ,  C07C29/132 ,  C10L3/06

Abstract: A liquid phase process for direct utilization of inorganic metal carbonate and related salts under hydrogenative conditions to produce value-added fuels and feedstocks such as methanol, methane, carbon monoxide, and higher hydrocarbons. Advantageously, the reaction can use heterogeneous catalysts. The hydrogenation proceeds with high selectivity and yield for the desired product at relatively low temperatures, along with co-production of metal hydroxide. The metal hydroxide can be used to capture CO2, forming metal carbonates and bicarbonates that can be reused to produce more methanol and methane, hydrocarbons and carbon monoxide, closing the loop. Such a hydrogenation process can thus also be used in a "carbon capture and recycling" manner to produce renewable methane, methanol, carbon monoxide, hydrocarbons, and other carbon feedstocks from CO2 sourced from any natural and anthropogenic emissions as well as from ambient air.

公开(公告)号：WO2016114991A1

公开(公告)日：2016-07-21

申请号：PCT/US2016/012663

申请日：2016-01-08

Applicant: UNIVERSITY OF SOUTHERN CALIFORNIA

Inventor： GOEPPERT, Alain ,  ZHANG, Hang ,  PRAKASH, G.K. Surya ,  OLAH, George, A.

IPC: B01J20/10 ,  B01J20/28 ,  B01J20/26 ,  B01J20/30 ,  B01J20/32 ,  B01J20/34 ,  B01D53/04

CPC classification number: B01J20/103 ,  B01D53/02 ,  B01D53/04 ,  B01D2253/202 ,  B01D2253/25 ,  B01D2257/504 ,  B01J20/262 ,  B01J20/28007 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3272 ,  B01J20/3425 ,  B01J20/3483 ,  B01J20/3491 ,  Y02C10/04 ,  Y02C10/08

Abstract: The invention relates to regenerative, solid sorbents for adsorbing carbon dioxide from a gas mixture, including air, with the sorbent including a modified polyamine and a solid support. The modified polyamine is the reaction product of an amine and an epoxide. The sorbent provides structural integrity, as well as high selectivity and increased capacity for efficiently capturing carbon dioxide from gas mixtures, including the air. The sorbent is regenerative, and can be used through multiple cycles of adsorption-desorption.

Abstract translation: 本发明涉及用于从包括空气的气体混合物吸附二氧化碳的再生固体吸附剂，其中吸附剂包括改性聚胺和固体载体。 改性多胺是胺和环氧化物的反应产物。 吸附剂提供结构完整性，以及高选择性和提高的有效捕集包括空气在内的气体混合物中的二氧化碳的能力。 吸附剂是再生的，可以通过吸附 - 解吸的多个循环使用。