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148 条记录 (耗时 0.02 秒)

    INTEGRATED PROCESS FOR THE PRODUCTION OF VINYL ACETATE FROM ACETIC ACID VIA ETHYLENE
    3.
    发明申请
    INTEGRATED PROCESS FOR THE PRODUCTION OF VINYL ACETATE FROM ACETIC ACID VIA ETHYLENE 审中-公开
    通过乙烯从乙酸生产乙酸乙烯酯的综合方法

    公开(公告)号：WO2010056299A1

    公开(公告)日：2010-05-20

    申请号：PCT/US2009/006016

    申请日：2009-11-06

    申请人： CELANESE INTERNATIONAL CORPORATION ,  JOHNSTON, Victor, J. ,  CHEN, Laiyuan ,  ZINK, James, H. ,  CHAPMAN, Josefina, T. ,  KIMMICH, Barbara, F. ,  REPMAN, Deborah, R.

    发明人： JOHNSTON, Victor, J. ,  CHEN, Laiyuan ,  ZINK, James, H. ,  CHAPMAN, Josefina, T. ,  KIMMICH, Barbara, F. ,  REPMAN, Deborah, R.

    IPC分类号： C07C67/05

    CPC分类号： C07C67/00 ,  C07C29/149 ,  C07C67/055 ,  Y02P20/125 ,  C07C31/08 ,  C07C69/14 ,  C07C69/01 ,  C07C69/15

    摘要： This invention provides an integrated two stage economical process for the production of vinyl acetate monomer (VAM) from acetic acid in the vapor phase. First, acetic acid is selectively hydrogenated over a hydrogenating catalyst composition to form ethylene either in a single reactor zone or in a dual reactor zone wherein the intermediate hydrogenated products are either dehydrated and/or cracked to form ethylene. In a subsequent second stage so formed ethylene is reacted with molecular oxygen and acetic acid over a suitable catalyst to form VAM. In an embodiment of this invention reaction of acetic acid and hydrogen over a hydrogenation catalyst and subsequent reaction over a dehydration catalyst selectively produces ethylene, which is further mixed with acetic acid and molecular oxygen and reacted over a supported palladium/gold/potassium catalyst.

    摘要翻译： 本发明提供了一种用于在蒸气相中从乙酸生产乙酸乙烯酯单体（VAM）的综合两阶段经济方法。 首先，在氢化催化剂组合物上选择性氢化乙酸，以在单个反应器区域或双重反应器区域中形成乙烯，其中中间氢化产物被脱水和/或裂化形成乙烯。 在随后的第二阶段中，如此形成的乙烯通过合适的催化剂与分子氧和乙酸反应以形成VAM。 在本发明的一个实施方案中，乙酸和氢气在氢化催化剂上的反应和随后的脱水催化剂反应选择性地产生乙烯，其进一步与乙酸和分子氧混合并在负载的钯/金/钾催化剂上反应。

    ACYLOXYLATION CATALYST AND PROCESS FOR ITS PRODUCTION
    5.
    发明申请
    ACYLOXYLATION CATALYST AND PROCESS FOR ITS PRODUCTION 审中-公开
    乙酰化催化剂及其生产工艺

    公开(公告)号：WO2008075588A1

    公开(公告)日：2008-06-26

    申请号：PCT/JP2007/073904

    申请日：2007-12-05

    申请人： SHOWA DENKO K.K. ,  YAMAMOTO, Yoshimi ,  WATANABE, Yumiko ,  SATO, Seiji

    发明人： YAMAMOTO, Yoshimi ,  WATANABE, Yumiko ,  SATO, Seiji

    IPC分类号： B01J23/66 ,  B01J23/68 ,  B01J23/89 ,  B01J37/02 ,  B01J37/06 ,  B01J37/03

    CPC分类号： B01J23/66 ,  B01J23/52 ,  B01J23/683 ,  B01J23/8946 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/03 ,  B01J37/06 ,  B01J37/16 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

    摘要： An acyloxylation catalyst is obtained by loading (a) a first component containing at least one element of Groups 8, 9, 10 and 11 of the Periodic Table, (b) a second component containing an element which is at least one element of Groups 8, 9, 10 and 11 of the Periodic Table and which is different from the element of the first component, and (c) a third component containing an element which is a component that produces a precipitation-starting pH below the precipitation-starting pH of the first component and second component and which is different from the elements of the first component and second component, onto (d) a support. A catalyst is obtained that can be used to efficiently carry out acyloxylation for economical production of acyloxylated compounds.

    摘要翻译： 通过加载（a）含有元素周期表第8,9,10和11族的至少一种元素的第一组分，（b）含有至少一种元素组8的元素的第二组分，获得酰氧基化催化剂 ，9,10和11，并且与第一组分的元素不同，和（c）含有元素的第三组分，该组分是产生沉淀起始pH低于沉淀起始pH的组分，其沉淀起始pH低于 第一部件和第二部件，并且与第一部件和第二部件的元件不同，到（d）支撑件。 获得可用于有效进行酰氧基化以经济生产酰氧化化合物的催化剂。

    PREPARATION OF PALLADIUM-GOLD CATALYSTS
    6.
    发明申请
    PREPARATION OF PALLADIUM-GOLD CATALYSTS 审中-公开
    铂金催化剂的制备

    公开(公告)号：WO2007094903A2

    公开(公告)日：2007-08-23

    申请号：PCT/US2007/000600

    申请日：2007-01-10

    申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P.

    发明人： AUGUSTINE, Steven, M.

    CPC分类号： B01J27/055 ,  B01J21/063 ,  B01J37/0207 ,  B01J37/14 ,  B01J37/18 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15 ,  C07C69/155

    摘要： A new method for preparing supported palladium-gold catalysts is disclosed. The method comprises sulfating a titanium dioxide support, calcining the sulfated support, impregnating the calcined support with a palladium salt, a gold salt, and an alkali metal or ammonium compound, calcining the impregnated support, and reducing the calcined support. The resultant supported palladium-gold catalysts have increased activity and stability in the acetoxylation.

    摘要翻译： 公开了一种制备负载型钯 - 金催化剂的新方法。 该方法包括硫酸化二氧化钛载体，煅烧硫酸化载体，用钯盐，金盐和碱金属或铵化合物浸渍煅烧的载体，煅烧浸渍的载体和还原煅烧载体。 所得负载的钯 - 金催化剂具有增加的乙酰氧基化活性和稳定性。

    CO-PRODUCTION OF VINYL ACETATE AND ETHYL ACETATE
    7.
    发明申请
    CO-PRODUCTION OF VINYL ACETATE AND ETHYL ACETATE 审中-公开
    乙酸乙烯酯和乙酸乙烯酯的共生产

    公开(公告)号：WO2006055183A1

    公开(公告)日：2006-05-26

    申请号：PCT/US2005/038289

    申请日：2005-10-21

    申请人： CELANESE INTERNATIONAL CORPORATION

    发明人： WARNER, Jay, R. ,  TORRES, Alfonso, J.

    IPC分类号： C07C67/055 ,  C07C69/15 ,  C07C67/283 ,  C07C69/14 ,  B01J19/00

    CPC分类号： C07C67/055 ,  B01J23/44 ,  B01J25/02 ,  C07C67/283 ,  C07C69/01 ,  C07C69/14 ,  C07C69/15

    摘要： A method of co-producing vinyl acetate and ethyl acetate includes: (a) reacting ethylene, acetic acid and oxygen to form vinyl acetate and at least a minor amount of ethyl acetate; (b) providing a crude product stream containing the vinyl acetate and ethyl acetate of step (a) and acetic acid to a distillation tower; (c) separating the crude product stream into: (i) a vinyl acetate product stream enriched in vinyl acetate with respect to the crude product stream; (ü) an acid recycle stream enriched in acetic acid with respect to the crude product stream; (iii) a mixed sidestream containing vinyl acetate and ethyl acetate, the mixed sidestream being enriched in ethyl acetate with respect to the vinyl acetate product stream; and (d) hydrogenating vinyl acetate in the mixed sidestream to provide an ethyl acetate product stream.

    摘要翻译： 共同生产乙酸乙烯酯和乙酸乙酯的方法包括：（a）使乙烯，乙酸和氧反应形成乙酸乙烯酯和至少少量的乙酸乙酯; （b）向蒸馏塔提供含有步骤（a）的乙酸乙烯酯和乙酸乙酯和乙酸的粗产物流; （c）将粗产物流分离为：（i）相对于粗产物流，富含乙酸乙烯酯的乙酸乙烯酯产物流; （ü）相对于粗产物流富含乙酸的酸循环物流; （iii）含乙酸乙烯酯和乙酸乙酯的混合侧流，混合侧流相对于乙酸乙烯酯产物流富含乙酸乙酯; 和（d）在混合侧流中加氢乙酸乙烯酯以提供乙酸乙酯产物流。

    INTEGRATED PROCESS FOR ACETIC ACID AND METHANOL
    8.
    发明申请
    INTEGRATED PROCESS FOR ACETIC ACID AND METHANOL 审中-公开
    乙酸和甲醇的一体化方法

    公开(公告)号：WO2005070855A1

    公开(公告)日：2005-08-04

    申请号：PCT/CY2004/000002

    申请日：2004-01-22

    申请人： ACETEX (CYPRUS) LIMITED ,  THIEBAUT, Daniel, Marcel

    发明人： THIEBAUT, Daniel, Marcel

    IPC分类号： C07C29/151

    CPC分类号： C07C29/1518 ,  C07C51/12 ,  C07C67/05 ,  Y02P20/125 ,  C07C53/08 ,  C07C69/01 ,  C07C69/15 ,  C07C31/04

    摘要： An integrated process for making methanol, acetic acid, and a product from an associated process is disclosed. Syngas (120) is produced by combined steam reforming (109) and autothermal reforming (118) of natural gas (102) where a portion (112) of the natural gas bypasses the steam reformer (109) and is blended with the steam reformer effluent for supply to the autothermal reformer (ATR) (118) with C02 recycle (110). A portion of the syngas is fed to C02 removal (122) to obtain the recycle C02 and cold box (130) to obtain a hydrogen stream (131) and a CO stream (135). The remaining syngas, hydrogen stream (131) and C02 from an associated process are fed to methanol synthesis (140), which produces methanol and a purge stream (124) supplied to the C02 removal unit. The methanol is supplied to an acetic acid unit (13)6 with the CO (135) to make acetic acid, which in turn is supplied to a VAM synthesis unit (148). Oxygen for both the ATR and VAM synthesis can be supplied by a common air separation unit (116), and utilities such as steam generation can further integrate the process.

    摘要翻译： 公开了一种用于制备甲醇，乙酸和来自相关方法的产物的综合方法。 合成气（120）通过天然气（102）的组合蒸汽重整（109）和自热重整（118）生产，其中天然气的一部分（112）绕过蒸汽重整器（109）并与蒸汽重整器流出物 供应到具有CO 2再循环（110）的自热重整器（ATR）（118）。 将一部分合成气进料至CO 2去除（122）以获得循环CO 2和冷箱（130）以获得氢气流（131）和CO流（135）。 将来自相关方法的剩余合成气，氢气流（131）和CO 2进料到甲醇合成（140），其产生甲醇和提供给CO 2去除单元的清洗流（124）。 将甲醇与CO（135）一起供应到乙酸单元（13）6以制备乙酸，其又被供给到VAM合成单元（148）。 用于ATR和VAM合成的氧气可以由公共空气分离单元（116）提供，并且诸如蒸汽发生的功能可以进一步整合该过程。

    ZIRCONIA CONTAINING SUPPORT MATERIAL FOR CATALYSTS
    9.
    发明申请
    ZIRCONIA CONTAINING SUPPORT MATERIAL FOR CATALYSTS 审中-公开
    包含催化剂支持材料的ZIRCONIA

    公开(公告)号：WO2005061107A1

    公开(公告)日：2005-07-07

    申请号：PCT/US2004/039039

    申请日：2004-11-19

    申请人： CELANESE INTERNATIONAL CORPORATION ,  WANG, Tao ,  WADE, Leslie, E. ,  WONG, Victor ,  LOWE, David, M. ,  HAGEMEYER, Alfred ,  HAN, Jun ,  SOKOLOVSKII, Valery

    发明人： WANG, Tao ,  WADE, Leslie, E. ,  WONG, Victor ,  LOWE, David, M. ,  HAGEMEYER, Alfred ,  HAN, Jun ,  SOKOLOVSKII, Valery

    IPC分类号： B01J23/52

    CPC分类号： B01J23/52 ,  B01J21/066 ,  B01J23/007 ,  B01J29/06 ,  B01J35/008 ,  B01J35/0086 ,  B01J35/0093 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0018 ,  B01J37/16 ,  B01J37/18 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

    摘要： The present invention addresses at aeast four different aspects relating to catalyat structure, method of making those catalysts and methods of using those catalysts for making allcenyl alkanoates. Separately or together in combination, the various aspects of the invention are directed at improving the production of alkenyl alkanoates and VA in particular, including reduction of by-products and improved production efficiency. A first aspect of the presente invention pertains to a unique palladium/gold catalyst or pre-catalyst (optionally calcined) that includes rhodium or another metal. A second aspect pertains to a palladium/gold catalyst or precatalyst at is based on a layered support material where one layer of the support materiel is substantially free of catalytic components. A third aspect pertains to a palladium/gold catalyst or precatalysts on a zirconia containing support material. A fourth aspect pertains to a palladium gold catalyst or pre-catalyst that is produced from substantially chloride free catalytic components.

    摘要翻译： 本发明涉及催化结构，制备这些催化剂的方法和使用这些催化剂制备烯基链烷酸酯的方法的四个不同方面。 本发明的单独或一起组合地涉及改进烯基链烷酸酯和VA的生产，特别是包括副产物的还原和提高的生产效率。 本发明的第一方面涉及包含铑或另一种金属的独特的钯/金催化剂或预催化剂（任选煅烧的）。 第二方面涉及钯/金催化剂或预催化剂，其基于层状载体材料，其中一层载体材料基本上不含催化组分。 第三方面涉及在含氧化锆载体材料上的钯/金催化剂或预催化剂。 第四方面涉及由基本上不含氯的催化组分制备的钯金催化剂或预催化剂。

    THE PROCESS FOR TREATING THE BOTTOM RESIDUE OF VINYL ACETATE
    10.
    发明申请
    THE PROCESS FOR TREATING THE BOTTOM RESIDUE OF VINYL ACETATE 审中-公开

    公开(公告)号：WO2005039729A1

    公开(公告)日：2005-05-06

    申请号：PCT/CN2003/000915

    申请日：2003-10-29

    IPC分类号： B01D17/02

    CPC分类号： C07C67/48 ,  C08L31/04 ,  C07C69/01 ,  C07C69/15

    摘要： Abstract: The invention relates to the reproduction of the industrial waste and it is an environmental treatment process for the bottom residue of vinyl acetate. Said process comprises the process of washing and dewatering the bottom residue, can attain the no public nuisance treatment of the industrial residue and can obtain the solid poly(vinyl acetate) at a low cost when recovering the acetate. The poly(vinyl acetate) of the invention can be used for preparing quick-drying oil paint, primer paint, antirust paint, adhesive, printing ink, building material and road material etc. and its production cost is low. The cost of the process equipment of the invention is low and the operation is simple and convenient. The invention has found a new significantly environmental and economic treatment process for the bottom residue discharged from the production process of vinyl acetate.