公开(公告)号：WO2017102694A1

公开(公告)日：2017-06-22

申请号：PCT/EP2016/080744

申请日：2016-12-13

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  SHELL OIL COMPANY

Inventor： BASTINGS, Roel, Guillaume, Hubertus, Leonardus ,  BLACK, Jesse, Raymond ,  EVANS, Wayne, Errol ,  VAN KLEECK, David, Allen ,  WARD, Gregory, John

IPC: B01J8/04 ,  C07D301/32

CPC classification number: B01J8/0492 ,  B01J8/0419 ,  B01J8/0457 ,  B01J8/0496 ,  B01J2208/00176 ,  B01J2219/0004 ,  C07D301/32

Abstract: The invention provides a reaction system for the production of ethylene carbonate and/or ethylene glycol, said reaction comprising a guard bed system positioned upstream of a catalytic EO reactor, said guard bed system comprising a feed line supplying a gaseous feed to be treated and an effluent line configured to remove the treated gaseous feed and two or more guard bed vessels arranged in series in sequential order, each guard bed vessel comprising an inlet, a bed of guard bed material and an outlet, wherein the inlet of each guard bed vessel is attached by means of valves to both the feed line and the outlet of the guard bed vessel preceding it in sequential order and wherein the outlet of each guard bed vessel is attached by means of valves to both the effluent line and to the inlet of the guard bed vessel following it in sequential order and wherein the guard bed vessel following the last guard bed vessel in sequential order is the first guard bed vessel in sequential order.

Abstract translation: 本发明提供了用于生产碳酸亚乙酯和/或乙二醇的反应体系，所述反应包括位于催化EO反应器上游的保护床系统，所述保护床系统包括供应管线供应 待处理的气态进料和构造成去除经处理的气态进料的排出管线以及依次顺序布置的两个或更多个保护床容器，每个保护床容器包括入口，保护床材料床和出口，其中 每个保护床容器的入口依次通过阀门连接到前面的保护床容器的供给管线和出口，并且其中每个保护床容器的出口借助于阀门连接到流出物 并依次连接到保护床容器的入口，并且顺序地在最后的保护床容器之后的保护床容器是顺序中的第一保护床容器 l订单。

公开(公告)号：WO2017089080A1

公开(公告)日：2017-06-01

申请号：PCT/EP2016/076321

申请日：2016-11-02

Applicant: EVONIK DEGUSSA GMBH ,  THYSSENKRUPP INDUSTRIAL SOLUTIONS AG

Inventor： KOLBE, Bärbel ,  BÄRZ, Manfred ,  BRENDEL, Marc ,  WON, Kidon ,  YANG, Hojin ,  PARK, Soohyun ,  BERNHARD, Maik

IPC: C07D301/32

CPC classification number: C07D301/32

Abstract: Propene oxide is purified by extractive distillation, feeding crude propene oxide comprising from 15 to 97 % by weight of propene oxide, from 2 to 84 % by weight of methanol, and acetaldehyde to a feed point A in the middle section of an extractive distillation column; feeding an aqueous extraction solvent to a feed point B located above feed point A; and feeding a reactive compound of structure R 1 -Y-NH 2 , where Y is oxygen or NR 2 and R 1 and R 2 are independently of one another hydrogen, an alkyl group or an aryl group, or a salt of such reactive compound, to feed point B, feed point A or between feed points A and B; withdrawing a stream S1 from the top of the extractive distillation column to provide a first propene oxide product containing less than 200 ppm water; and withdrawing a stream S2 at a withdrawal point 5 to 25 theoretical separation stages above feed point B to provide a second propene oxide product containing 500 to 10000 ppm water.

Abstract translation: 通过萃取蒸馏纯化氧化丙烯，将包含15-97重量％氧化丙烯，2-84重量％甲醇和乙醛的粗制环氧丙烷进料至进料A的 萃取精馏塔的中段; 将水性萃取溶剂供给至位于供给点A上方的供给点B; 并且加入结构为R 1 -Y-NH 2的活性化合物，其中Y是氧或NR 2和R 1， R 2和R 2彼此独立地为氢，烷基或芳基或该反应性化合物的盐与进料B点，进料点A或进料点A和B之间 B; 从萃取蒸馏塔顶部排出物流S1以提供含有小于200ppm水的第一环氧丙烷产物; 并且在进料点B上方5至25个理论分离级的取出点取出料流S2以提供含有500至10000ppm水的第二氧化丙烯产物。

公开(公告)号：WO2015017333A1

公开(公告)日：2015-02-05

申请号：PCT/US2014/048436

申请日：2014-07-28

Applicant: LYONDELL CHEMICAL TECHNOLOGY, L.P.

Inventor： LI, Xiangmin ,  CHANG, Te ,  LEYSHON, David, W. ,  DUBNER, Walter, S. ,  ROSS-MEDGAARDEN, Elizabeth, I.

IPC: C07D301/19 ,  B01D3/40

CPC classification number: C07D301/32 ,  B01D3/143 ,  B01D11/0488 ,  B01D11/0492 ,  B01D17/0214

Abstract: A propylene oxide separation system that comprises a distillation column, a decanter, and water wash system. The distillation column is configured to receive a crude propylene oxide stream, discharge an impurity stream that comprises methanol and water, and discharge a bottoms stream that comprises a majority of the propylene oxide entering in the crude propylene oxide stream. The decanter is configured to receive at least a portion of the impurity stream and a hydrocarbon solvent to provide for formation in the decanter of an organic phase and an aqueous phase. The organic phase comprises propylene oxide and hydrocarbon solvent, and is sent to the distillation column. The aqueous phase comprises a majority weight percent of the methanol and the water entering in the impurity stream. The water wash system is configured to receive and purge the aqueous phase from the propylene oxide separation system.

Abstract translation: 包括蒸馏塔，滗析器和水洗系统的环氧丙烷分离系统。 蒸馏塔被配置为接收粗的环氧丙烷流，排出包含甲醇和水的杂质流，并排出包含进入粗环氧丙烷流中的大部分环氧丙烷的塔底物流。 滗析器被配置为接收至少一部分杂质流和烃溶剂以提供在有机相和水相的滗析器中的形成。 有机相包括环氧丙烷和烃溶剂，并送入蒸馏塔。 水相包含大部分重量百分比的甲醇和进入杂质流的水。 水洗系统构造成从环氧丙烷分离系统接收和清除水相。

公开(公告)号：WO2014198243A1

公开(公告)日：2014-12-18

申请号：PCT/CZ2014/000064

申请日：2014-06-09

Applicant: SPOLEK PRO CHEMICKOU A HUTNI VYROBU, AKCIOVA SPOLECNOST

Inventor： KUBICEK, Pavel ,  NEMECEK, Bedrich ,  SLADEK, Petr

IPC: C07D301/26 ,  C07D301/32

CPC classification number: C07D301/26 ,  C07D301/32 ,  C08G65/22 ,  C08G2650/32

Abstract: A process for manufacturing epoxy monomers and/or epoxides in high yields and useful quality and chemical stability by dehydrochlorination of the corresponding chlorohydrins with an alkaline agent, producing the corresponding side product dry salt in a high purity, characterized in that the process comprises the following steps: a. Reaction of the chlorohydrins with the alkaline agent to form corresponding epoxides and the corresponding precipitated chloride salt; b. Dehydration, and optionally completing the reaction, of the reaction mixture of step (a), by use of an azeotropic agent, added to step (b) or generated in situ in step (a), resulting in the producing of a dehydrated reaction mixture; c. Separating the resulting chloride salt by filtration from the dehydrated reaction mixture (b) and d. Isolating the epoxide from the filtered liquid fraction.

Abstract translation: 一种以高产率制备环氧单体和/或环氧化物的方法，并且通过用碱性试剂对相应的氯代醇进行脱氯化氢来产生有用的质量和化学稳定性，产生高纯度的相应的副产物干盐，其特征在于该方法包括以下 步骤：a。 氯醇与碱性试剂的反应形成相应的环氧化物和相应的沉淀氯化物盐; 湾 通过使用加入到步骤（b）中的共沸剂或在步骤（a）中原位产生的步骤（a）的反应混合物的脱水和任选地完成反应），导致产生脱水的反应混合物 ; C。 通过过滤从脱水反应混合物（b）和d分离得到的氯化物盐。 从过滤的液体馏分中分离出环氧化物。

公开(公告)号：WO2014157699A1

公开(公告)日：2014-10-02

申请号：PCT/JP2014/059346

申请日：2014-03-28

Applicant: 株式会社日本触媒

Inventor： 渡邊　明正 ,  瀧波　孝広 ,  森川　規司

IPC: C07D301/10 ,  B01D53/14 ,  C07D301/32 ,  C07D303/04 ,  C07B61/00

CPC classification number: C07D301/10 ,  B01D53/1406 ,  B01D53/1475 ,  B01D53/1487 ,  B01D53/62 ,  B01D53/78 ,  B01D2251/304 ,  B01D2251/306 ,  B01D2251/604 ,  B01D2252/103 ,  B01D2256/24 ,  B01D2257/504 ,  B01D2259/65 ,  C07D301/32 ,  Y02C10/04 ,  Y02C10/06 ,  Y02P20/121 ,  Y02P20/124 ,  Y02P20/152 ,  Y02P20/51

Abstract: 銀触媒の存在下、エチレンを分子状酸素を用いた接触気相酸化により酸化して得たエチレンオキシド（ＥＯ）を含有する反応生成ガスを、ＥＯ吸収塔へ供給し、前記吸収塔へ供給された吸収液と接触させ、ＥＯを含有する前記吸収塔の塔底液をＥＯ精製系へ供給し、前記精製系においてＥＯを精製する工程と、前記吸収塔の塔頂部から排出される炭酸ガス含有ガスの少なくとも一部を炭酸ガス吸収塔へ供給し、前記炭酸ガス含有ガスを吸収液と接触させて得られる炭酸ガス濃厚吸収液を前記吸収塔の塔底液として抜き出して炭酸ガス放散塔の上部へ供給し、前記炭酸ガス濃厚吸収液から炭酸ガスを放散させて前記放散塔の塔頂部から排ガスとして排出させる工程とを含むＥＯの製造方法であって、前記精製系が下部にリボイラーを備えたＥＯ精製塔を有し、前記リボイラーを加熱するための加熱媒体を前記排ガスとの熱交換により加熱することを特徴とする、ＥＯの製造方法。

Abstract translation: 一种生产环氧乙烷（EO）的方法，所述方法包括以下步骤：在银催化剂存在下，通过催化气相氧化将含氧化的乙烯反应生成的反应产物气体， EO吸收塔，使反应产物气体与供给到吸收塔的吸收溶液接触，然后将含EO的吸收塔中的塔底部溶液供应到EO净化系统中，以纯化EO中的EO 系统; 并且将通过吸收塔的塔顶部排出的含二氧化碳气体的气体的至少一部分供给到二氧化碳气体吸收塔，使含二氧化碳气体的气体与吸收溶液接触 然后将作为接触结果产生的二氧化碳气体富集吸收产物溶液作为吸收塔中的塔底部溶液抽出，然后将富二氧化碳气体吸收产物溶液供给到 二氧化碳气体扩散塔，用于从二氧化碳气体富集吸收产物溶液中扩散二氧化碳气体，然后通过作为排出气体的扩散塔的塔顶部排出扩散的二氧化碳气体。 该方法的特征在于，净化系统配备有在其下部设置有再沸器的EO纯化塔，并且通过加热介质和排出气体之间的热交换来加热再沸器的加热介质。

公开(公告)号：WO2012104886A8

公开(公告)日：2013-09-06

申请号：PCT/IT2012000036

申请日：2012-02-03

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  CARLBERG PHILIP J ,  CRAMPTON HANNAH L ,  FORLIN ANNA ,  PEDERNERA ESTEBAN ,  MEZA CESAR E

Inventor： CARLBERG PHILIP J ,  CRAMPTON HANNAH L ,  FORLIN ANNA ,  PEDERNERA ESTEBAN ,  MEZA CESAR E

IPC: C07D301/12 ,  B01D11/04 ,  C07D301/32

CPC classification number: B01J8/20 ,  B01D11/0488 ,  B01D11/0492 ,  B01J8/0278 ,  B01J19/00 ,  B01J2219/00247 ,  C07D301/12 ,  C07D301/32 ,  Y02P20/52

Abstract: Embodiments of the present disclosure are directed to a system and a process for producing an oxirane. For the various embodiments, the system and process of the present disclosure includes: a reaction vessel having a reaction mixture of an olefin, a peroxide compound, a solvent mixture with an alcohol and a non-reactive co-solvent, a solid phase, and reaction products of the reaction mixture, where the reaction products include an oxirane; a separation vessel coupled to the reaction vessel, where an effluent of the reaction mixture and reaction products from the reaction vessel separates in the separation vessel into a liquid aqueous phase and a liquid organic phase; and an extraction vessel coupled to an outlet of the separation vessel, where the liquid aqueous phase taken from the outlet of the separation vessel mixes with an extraction solvent to extract oxirane from the aqueous phase.

Abstract translation: 本公开的实施方案涉及用于生产环氧乙烷的系统和方法。 对于各种实施方案，本公开的系统和方法包括：反应容器，其具有烯烃，过氧化物化合物，溶剂混合物与醇和非反应性助溶剂的反应混合物，固相和 反应混合物的反应产物，其中反应产物包括环氧乙烷; 耦合到反应容器的分离容器，其中反应混合物的流出物和来自反应容器的反应产物在分离容器中分离成液体水相和液体有机相; 以及耦合到分离容器的出口的提取容器，其中从分离容器的出口取出的液体水相与提取溶剂混合以从水相中提取环氧乙烷。

公开(公告)号：WO2013119402A1

公开(公告)日：2013-08-15

申请号：PCT/US2013/023362

申请日：2013-01-28

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： MUNDRA, Manish ,  GHOSH-DASTIDAR, Abhijit ,  EATON, Robert F. ,  FU, Lin ,  CAMPBELL, Robert M. ,  BELL, Bruce M.

IPC: C08K5/00 ,  C07D303/42

CPC classification number: C08K9/02 ,  C07D301/32 ,  C08K5/0016 ,  C08K5/1515 ,  C08L27/06

Abstract: The present disclosure is directed to a plasticizer composition, polymeric compositions containing the plasticizer composition, and conductors coated with the polymeric composition. The plasticizer composition includes a first plasticizer comprising epoxidized fatty acid alkyl esters and a second plasticizer comprising an epoxidized natural oil. The plasticizer composition, first plasticizer, and/or second plasticizer can undergo one or more color-reducing treatment processes, such as distillation, filtration, and/or peroxide treatment.

Abstract translation: 本公开涉及增塑剂组合物，含有增塑剂组合物的聚合物组合物和涂覆有聚合物组合物的导体。 增塑剂组合物包括包含环氧化脂肪酸烷基酯的第一增塑剂和包含环氧化天然油的第二增塑剂。 增塑剂组合物，第一增塑剂和/或第二增塑剂可以进行一种或多种减色处理方法，例如蒸馏，过滤和/或过氧化物处理。

公开(公告)号：WO2012170685A1

公开(公告)日：2012-12-13

申请号：PCT/US2012/041349

申请日：2012-06-07

Applicant: LYONDELL CHEMICAL TECHNOLOGY, L.P. ,  LI, Xiangmin ,  LEYSHON, David, W. ,  CHANG, Te

Inventor： LI, Xiangmin ,  LEYSHON, David, W. ,  CHANG, Te

IPC: C07D301/19 ,  C07D301/32 ,  C07D303/04

CPC classification number: C07D303/04 ,  B01D3/40 ,  C07D301/19 ,  C07D301/32

Abstract: The disclosure relates to a process for separating propylene oxide for a crude propylene oxide stream, for example an intermediate stream from a PO/TBA process. The crude propylene oxide stream can be passed through an extractive distillation column. The distillation column is operated at a pressure in a range of greater than 25 up to 50 psig, and/or at a temperature in a range of from 70 to 150 degrees Celsius using C 8 -C 20 paraffin as extractive solvent with an overhead distillate water wash drum. The crude propylene oxide stream include from 0.001 to 0.1 wt% methanol, based on the total composition of the crude propylene oxide stream. The systems, methods, and apparatuses can produce a propylene oxide stream having less formaldehyde and acetaldehyde than the prior art.

Abstract translation: 本公开涉及用于分离粗环氧丙烷流的环氧丙烷的方法，例如来自PO / TBA方法的中间体流。 粗环氧丙烷流可以通过萃取蒸馏塔。 使用C8-C20石蜡作为萃取溶剂，用塔顶蒸馏水洗涤将蒸馏塔在大于25psig至50psig的范围内和/或在70至150摄氏度的温度范围内操作。 鼓。 粗环氧丙烷流包含0.001至0.1重量％的甲醇，基于粗环氧丙烷流的总组成。 系统，方法和装置可以产生比现有技术更少的甲醛和乙醛的环氧丙烷流。

公开(公告)号：WO2012104886A2

公开(公告)日：2012-08-09

申请号：PCT/IT2012000036

申请日：2012-02-03

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  CARLBERG PHILIP J ,  CRAMPTON HANNAH L ,  FORLIN ANNA ,  PEDERNERA ESTEBAN ,  MEZA CESAR E

Inventor： CARLBERG PHILIP J ,  CRAMPTON HANNAH L ,  FORLIN ANNA ,  PEDERNERA ESTEBAN

IPC: C07D301/12 ,  B01D11/04 ,  C07D301/32

CPC classification number: B01J8/20 ,  B01D11/0488 ,  B01D11/0492 ,  B01J8/0278 ,  B01J19/00 ,  B01J2219/00247 ,  C07D301/12 ,  C07D301/32 ,  Y02P20/52

Abstract: Embodiments of the present disclosure are directed to a system and a process for producing an oxirane. For the various embodiments, the system and process of the present disclosure includes: a reaction vessel having a reaction mixture of an olefin, a peroxide compound, a solvent mixture with an alcohol and a non-reactive co-solvent, a solid phase, and reaction products of the reaction mixture, where the reaction products include an oxirane; a separation vessel coupled to the reaction vessel, where an effluent of the reaction mixture and reaction products from the reaction vessel separates in the separation vessel into a liquid aqueous phase and a liquid organic phase; and an extraction vessel coupled to an outlet of the separation vessel, where the liquid aqueous phase taken from the outlet of the separation vessel mixes with an extraction solvent to extract oxirane from the aqueous phase.

Abstract translation: 本公开的实施方案涉及用于生产环氧乙烷的系统和方法。 对于各种实施方案，本公开的系统和方法包括：反应容器，其具有烯烃，过氧化物化合物，溶剂混合物与醇和非反应性助溶剂的反应混合物，固相和 反应混合物的反应产物，其中反应产物包括环氧乙烷; 耦合到反应容器的分离容器，其中反应混合物的流出物和来自反应容器的反应产物在分离容器中分离成液体水相和液体有机相; 以及耦合到分离容器的出口的提取容器，其中从分离容器的出口取出的液体水相与提取溶剂混合以从水相中提取环氧乙烷。

公开(公告)号：WO2010024839A1

公开(公告)日：2010-03-04

申请号：PCT/US2009/004415

申请日：2009-07-31

Applicant: LYONDELL CHEMICAL TECHNOLOGY, L.P.

Inventor： CHANG, Te ,  SAWYER, Gary, A.

IPC: C07D301/06 ,  C07D301/08 ,  C07D301/32

CPC classification number: C07D301/06 ,  C07D301/08 ,  C07D301/32

Abstract: A process for making propylene oxide from propylene is disclosed. The process comprises reacting propylene, oxygen, and hydrogen in the presence of a catalyst and a solvent to produce a reaction mixture comprising propylene oxide. Separation of propylene, oxygen, hydrogen, and propylene oxide from the reaction mixture results in a residual mixture comprising methanol. A portion of the residual mixture is recycled to the reaction. A portion of the residual mixture is distilled to generate a distilled methanol stream, which is recycled to the reaction.

Abstract translation: 公开了一种从丙烯制备环氧丙烷的方法。 该方法包括在催化剂和溶剂的存在下使丙烯，氧和氢反应以产生包含环氧丙烷的反应混合物。 从反应混合物中分离丙烯，氧，氢和环氧丙烷导致包含甲醇的残留混合物。 将一部分残余混合物再循环至反应。 将一部分残余混合物蒸馏以产生蒸馏的甲醇流，将其再循环至反应中。