PROCESS FOR THE PREPARATION OF (CO)POLYMERS OF CONJUGATED DIENES IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING AN OXO-NITROGENATED COMPLEX OF COBALT
    2.
    发明申请
    PROCESS FOR THE PREPARATION OF (CO)POLYMERS OF CONJUGATED DIENES IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING AN OXO-NITROGENATED COMPLEX OF COBALT 审中-公开
    在含有氧化复合物的催化体系中存在共聚二烯的(CO)聚合物的方法

    公开(公告)号:WO2014097087A1

    公开(公告)日:2014-06-26

    申请号:PCT/IB2013/060905

    申请日:2013-12-13

    Applicant: VERSALIS S.P.A

    CPC classification number: C08F136/06 C08F4/704 C08F4/7044 C08F36/04 C08F36/06

    Abstract: Process for the preparation of (co) polymers of conjugated dienes which comprises polymerizing at least one conjugated diene in the presence of a catalytic system comprising at least one oxo-nitrogenated complex of cobalt having general formula (I),wherein : - R 1 and R 2 , equal to or different from each other, represent a hydrogen atom; or they are selected from linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, optionally halogenated; cycloalkyl groups optionally substituted; aryl groups optionally substituted; - Y represents an oxygen atom; or a group -N-R 3 wherein R 3 represents a hydrogen atom, or it is selected from linear or branched C 1 -C 20 preferably C 1 -C 15 , alkyl groups, optionally halogenated, cycloalkyl groups optionally substituted-; aryl groups optionally substituted; or, when Y represents a group -N-R 3 , R 2 and R 3 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C 1 -C 20 preferably C 1 -C 15 , alkyl groups, said cycle optionally containing heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; - X 1 and X 2 , equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine; or they are selected from linear or branched C 1 -C 20 preferably C 1 -C 15 , alkyl groups, -OCOR 4 groups or -OR 4 groups wherein R 4 is selected from linear or branched C 1 -C 20 preferably C 1 -C 15 , alkyl groups.

    Abstract translation: 制备共轭二烯的(共)聚合物的方法,其包括在催化体系的存在下聚合至少一种共轭二烯,所述催化体系包含至少一个通式(I)的含氧的含氮复合物的钴,其中:-R 1和R 2 相同或不同,表示氢原子; 或者它们选自直链或支链C 1 -C 20,优选C 1 -C 15烷基,任选卤代; 任选取代的环烷基; 任选取代的芳基; -Y表示氧原子; 或其中R 3表示氢原子的基团-N-R 3,或其选自直链或支链C 1 -C 20,优选C 1 -C 15烷基,任选卤代的环烷基,任选取代的; 任选取代的芳基; 或者当Y代表基团-N-R 3时,R 2和R 3可以彼此结合,形成与其结合的其它原子一起含有3至6个碳原子的饱和的,不饱和的, 或芳族的,任选地被直链或支链的C 1 -C 20,优选C 1 -C 15烷基取代,所述循环任选地含有杂原子,例如氧,硫,氮,硅,磷,硒; -X 1和X 2彼此相同或不同,表示卤素原子,例如氯,溴,碘; 或者它们选自直链或支链C 1 -C 20,优选C 1 -C 15烷基,-OCOR 4基团或-OR 4基团,其中R 4选自直链或支链C 1 -C 20,优选C 1 -C 15烷基。

    CATALYST FOR OLEFIN POLYMERIZATION AND METHOD OF POLYMERIZING OLEFIN
    5.
    发明申请
    CATALYST FOR OLEFIN POLYMERIZATION AND METHOD OF POLYMERIZING OLEFIN 审中-公开
    用于烯烃聚合的催化剂和聚烯烃的方法

    公开(公告)号:WO99065952A1

    公开(公告)日:1999-12-23

    申请号:PCT/JP1999/003206

    申请日:1999-06-16

    CPC classification number: C08F10/00 C08F10/02 C08F4/7047 C08F4/704

    Abstract: A catalyst for olefin polymerization which is highly active in olefin polymerization and with which a polyolefin having excellent properties can be produced; and a method of polymerizing an olefin using the catalyst. The catalyst comprises (A) a transition metal imine compound represented by general formula (I) and (B) at least one compound selected among (B-1) an organometallic compound, (B-2) an organoaluminumoxy compound, and (B-3) a compound which reacts with the compound (A) to form an ion pair.

    Abstract translation: 用于烯烃聚合的催化剂,其在烯烃聚合中具有高活性,并且可以制备具有优异性能的聚烯烃; 以及使用该催化剂聚合烯烃的方法。 催化剂包含(A)由通式(I)和(B)表示的过渡金属亚胺化合物,至少一种选自(B-1)有机金属化合物,(B-2)有机铝氧化合物和(B- 3)与化合物(A)反应形成离子对的化合物。

    ACTIVE, HETEROGENEOUS SUPPORTED BI- OR TRI-DENTATE OLEFIN POLYMERISATION CATALYST
    8.
    发明申请
    ACTIVE, HETEROGENEOUS SUPPORTED BI- OR TRI-DENTATE OLEFIN POLYMERISATION CATALYST 审中-公开
    主动,异构支持的双 - 或三硬脂醇烯烃聚合催化剂

    公开(公告)号:WO01032723A1

    公开(公告)日:2001-05-10

    申请号:PCT/US2000/028920

    申请日:2000-10-19

    CPC classification number: C08F10/02 C08F10/00 C08F4/7042 C08F4/704

    Abstract: A catalyst composition, and olefin polymerization process using same, formed from a mixture of a non-aluminoxane aluminum compound, an inorganic oxide and a transition metal bidentate or tridentate complex in certain prescribed proportions. The composition can be formed in a single step or in-situ in the polymerization reaction zone. The resultant catalyst has high activity and is capable of producing high molecular weight olefin products without reactor fouling.

    Abstract translation: 以非铝氧烷铝化合物,无机氧化物和过渡金属二齿或三齿络合物的混合物形成的催化剂组合物和使用该催化剂组合物的烯烃聚合方法按某些规定比例形成。 组合物可以在单一步骤中或在聚合反应区域中原地形成。 得到的催化剂具有高活性,并且能够生产没有反应器结垢的高分子量烯烃产物。

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