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1.发明申请STEREOREGULAR DIBLOCK POLYBUTADIENES HAVING A 1,4-CIS/SYNDIOTACTIC 1,2 STRUCTURE FROM STEREOSPECIFIC POLYMERIZATION 审中-公开具有1,4- CIS / SYNDIOTACTIC 1,2结构的立体双嵌段聚丁二烯由立体异构聚合
公开(公告)号：WO2015068095A1
公开(公告)日：2015-05-14
申请号：PCT/IB2014/065768
申请日：2014-11-03
Applicant: VERSALIS S.P.A.
Inventor： MASI, Francesco , SOMMAZZI, Anna , RICCI, Giovanni , LEONE, Giuseppe , COPPOLA, Salvatore
IPC: C08F295/00 , C08F4/655
CPC classification number: C08F295/00 , C08F4/7006 , C08F4/7008 , C08F4/7042 , C08F4/7044
Abstract: Stereoregular diblock polybutadiene composed of a polybutadiene block having a 1,4-cis structure and a polybutadiene block having a syndiotactic 1,2 structure. Said stereoregular diblock polybutadiene can be advantageously used in both the footwear industry (for example, in the production of soles for shoes) and in the production of tires for motor vehicles and/or trucks.
Abstract translation: 由具有1,4-顺式结构的聚丁二烯嵌段和具有间同立构1,2结构的聚丁二烯嵌段组成的立体规整性二嵌段聚丁二烯。 所述有规立构双嵌段聚丁二烯可有利地用于鞋类工业（例如用于制鞋的鞋底）和用于机动车辆和/或卡车的轮胎的生产中。
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公开(公告)号：WO01092342A2
公开(公告)日：2001-12-06
申请号：PCT/US2001/017627
申请日：2001-05-31
IPC: C07C251/08 , B01J31/00 , C07C251/20 , C07C251/24 , C07F5/06 , C07F7/00 , C07F9/50 , C07F9/572 , C07F9/58 , C07F15/04 , C07F19/00 , C08F4/00 , C08F4/06 , C08F4/16 , C08F4/44 , C08F4/60 , C08F4/605 , C08F4/619 , C08F4/642 , C08F4/70 , C08F4/76 , C08F4/80 , C08F10/00 , C08F10/02 , C08F110/02 , C08F118/02 , C08F210/00 , C08F210/02
CPC classification number: C08F10/00 , B01J31/1805 , B01J31/2282 , B01J2231/122 , B01J2531/847 , C07F9/46 , C07F9/5004 , C07F9/5009 , C07F15/0066 , C07F15/04 , C07F15/045 , C08F4/619 , C08F110/02 , C08F210/02 , C08F2500/04 , C08F2500/10 , C08F2500/20 , C08F220/10 , C08F2500/03 , C08F220/12 , C08F4/6028 , C08F4/64065 , C08F4/7031 , C08F4/7029 , C08F4/7019 , C08F4/7022 , C08F4/7014 , C08F4/7008 , C08F4/7006 , C08F4/40
Abstract: Transition metal complexes of selected monoanionic phosphine ligands, which also contain a selected Group 15 or 16 (IUPAC) element and which are coordinated to a Group 3 to 11 (IUPAC) transition metal or a lanthanide metal, are po-lymerization catalysts for the (co)polymerization of olefins such as ethylene and alpha -olefins, and the copolymerization of such olefins with polar group-containing olefins. These and other nickel complexes of neutral and monoanionic bidentate ligands copolymerize ethylene and polar comonomers, especially acrylates, at relatively high ethylene pressures and surprisingly high temperatures, and give good incorporation of the polar comonomers and good polymer productivity. These copolymers are often unique structures, which are described.
Abstract translation: 还含有选择的第15或16族（IUPAC）元素并且与第3至11族（IUPAC）过渡金属或镧系元素金属配位的选择的单阴离子膦配体的过渡金属络合物是用于（ 共聚）烯烃如乙烯和α-烯烃，以及这些烯烃与极性基团烯烃的共聚合。 中性和单阴离子双齿配体的这些和其它镍配合物在相对高的乙烯压力和惊人的高温下共聚乙烯和极性共聚单体，特别是丙烯酸酯，并且使极性共聚单体具有良好的掺入性和良好的聚合物生产率。 这些共聚物通常是独特的结构，其被描述。
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3.发明申请COMPLEX POLYMERIZATION CATALYSTS FOR THE HOMOPOLYMERIZATION OF ETHYLENE AND FOR THE COPOLYMERIZATION OF ETHYLENE 审中-公开用于乙烯的共聚合和乙烯共聚合的复合聚合催化剂
公开(公告)号：WO01074831A1
公开(公告)日：2001-10-11
申请号：PCT/EP2001/003023
申请日：2001-03-19
IPC: C07F15/04 , C08F4/80 , C08F110/02
CPC classification number: C08F110/02 , C07F15/045 , C08F4/704 , C08F4/7042 , C08F10/00 , C08F2500/23 , C08F2500/09 , C08F4/7006 , C08F4/7009 , C08F4/7008
Abstract: Complex catalysts based on a metal of group VIII complexed with suitable ligands, particularly active in the homopolymerization of ethylene and in its copolymerization with another unsaturated monomer of the vinylic and acrylic type.
Abstract translation: 基于VIII族金属络合的复合催化剂，与合适的配位体相结合，特别是在乙烯均聚中具有活性，并与乙烯基和丙烯酸类的另一不饱和单体共聚。
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公开(公告)号：WO1997002298A1
公开(公告)日：1997-01-23
申请号：PCT/US1996011131
申请日：1996-06-28
Applicant: E.I. DU PONT DE NEMOURS AND COMPANY , JOHNSON, Lynda, Kaye , FELDMAN, Jerald , KREUTZER, Kristina, Ann , MCLAIN, Stephan, James , BENNETT, Alison, Margaret, Anne , COUGHLIN, Edward, Bryan , DONALD, Dennis, Scott , NELSON, Lissa, Taka, Jennings , PARTHASARATHY, Anju , SHEN, Xing , TAM, Wilson , WANG, Yueli
Inventor： E.I. DU PONT DE NEMOURS AND COMPANY
IPC: C08F10/02
CPC classification number: C08F32/08 , C07F15/04 , C08F10/00 , C08F10/02 , C08F12/08 , C08F110/02 , C08F210/02 , C08F2500/10 , C08F232/00 , C08F2500/25 , C08F212/08 , C08F4/7006 , C08F4/7009 , C08F4/7008 , C08F4/7018
Abstract: Disclosed herein is a process for the polymerization of ethylene, norbornenes and styrenes, by contacting in solution a selected nickel compound and a selected compound which is or can be coordinated to the nickel with the olefin(s). The polymers produced are useful for films and molding resins.
Abstract translation: 本文公开了一种通过使溶液中的选定的镍化合物和选择的化合物与乙烯与烯烃接触而使乙烯，降冰片烯和苯乙烯聚合的方法。 所生产的聚合物可用于膜和模塑树脂。
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公开(公告)号：WO0192342A3
公开(公告)日：2003-01-16
申请号：PCT/US0117627
申请日：2001-05-31
Applicant: DU PONT , WANG LIN , HAUPTMAN ELISABETH , JOHNSON LYNDA K , MCCORD ELIZABETH F , WANG YING , ITTEL STEVEN D
Inventor： WANG LIN , HAUPTMAN ELISABETH , JOHNSON LYNDA K , MCCORD ELIZABETH F , WANG YING , ITTEL STEVEN D
IPC: C07C251/08 , B01J31/00 , C07C251/20 , C07C251/24 , C07F5/06 , C07F7/00 , C07F9/50 , C07F9/572 , C07F9/58 , C07F15/04 , C07F19/00 , C08F4/00 , C08F4/06 , C08F4/16 , C08F4/44 , C08F4/60 , C08F4/605 , C08F4/619 , C08F4/642 , C08F4/70 , C08F4/76 , C08F4/80 , C08F10/00 , C08F10/02 , C08F110/02 , C08F118/02 , C08F210/00 , C08F210/02
CPC classification number: C08F10/00 , B01J31/1805 , B01J31/2282 , B01J2231/122 , B01J2531/847 , C07F9/46 , C07F9/5004 , C07F9/5009 , C07F15/0066 , C07F15/04 , C07F15/045 , C08F4/619 , C08F110/02 , C08F210/02 , C08F2500/04 , C08F2500/10 , C08F2500/20 , C08F220/10 , C08F2500/03 , C08F220/12 , C08F4/6028 , C08F4/64065 , C08F4/7031 , C08F4/7029 , C08F4/7019 , C08F4/7022 , C08F4/7014 , C08F4/7008 , C08F4/7006 , C08F4/40
Abstract: Transition metal complexes of selected monoanionic phosphine ligands, which also contain a selected Group 15 or 16 (IUPAC) element and which are coordinated to a Group 3 to 11 (IUPAC) transition metal or a lanthanide metal, are po-lymerization catalysts for the (co)polymerization of olefins such as ethylene and alpha -olefins, and the copolymerization of such olefins with polar group-containing olefins. These and other nickel complexes of neutral and monoanionic bidentate ligands copolymerize ethylene and polar comonomers, especially acrylates, at relatively high ethylene pressures and surprisingly high temperatures, and give good incorporation of the polar comonomers and good polymer productivity. These copolymers are often unique structures, which are described.
Abstract translation: 还含有选择的第15或16族（IUPAC）元素并且与第3至11族（IUPAC）过渡金属或镧系元素金属配位的选择的单阴离子膦配体的过渡金属络合物是用于（ 共聚）烯烃如乙烯和α-烯烃，以及这些烯烃与极性基团烯烃的共聚合。 中性和单阴离子双齿配体的这些和其它镍配合物在相对高的乙烯压力和惊人的高温下共聚乙烯和极性共聚单体，特别是丙烯酸酯，并且使极性共聚单体具有良好的掺入性和良好的聚合物生产率。 这些共聚物通常是独特的结构，其被描述。
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Patent Agency Ranking
公开(公告)号：WO02059165A2
公开(公告)日：2002-08-01
申请号：PCT/US0203088
申请日：2002-01-25
Applicant: DU PONT , BROOKHART MAURICE S , KUNITSKY KEITH , MALINOSKI JON M , WANG LIN , WANG YIN , LIU WEIJUN , JOHNSON LYNDA KAYE , KREUTZER KRISTINA A , ITTEL STEVEN DALE
Inventor： BROOKHART MAURICE S , KUNITSKY KEITH , MALINOSKI JON M , WANG LIN , WANG YIN , LIU WEIJUN , JOHNSON LYNDA KAYE , KREUTZER KRISTINA A , ITTEL STEVEN DALE
IPC: C07D307/33 , C07C251/06 , C07D209/40 , C07F9/50 , C07F15/00 , C07F15/04 , C08F4/60 , C08F10/00 , C08F110/02 , C08F110/14 , C08F210/02
CPC classification number: C07F15/0066 , C07F15/045 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F110/14 , C08F210/02 , C08F2500/10 , C08F2500/04 , C08F2500/03 , C08F220/10 , C08F4/7008 , C08F4/64017 , C08F4/7006 , C08F4/7013 , C08F4/7014
Abstract: Certain complexes containing ligands having a phosphino group, amino group or an imino group, and a second functional group such as amide, ester or ketone, when complexed to transition metals, catalyze the (co)polymerization of olefinic compounds such as ethylene, &agr;-olefins and/or acrylates. A newly recognized class of ligands for making copolymer containing polar monomers using late transition metal complexes is described.
Abstract translation: 当与过渡金属络合时，含有具有膦基，氨基或亚氨基的配位体和第二官能团如酰胺，酯或酮的某些络合物催化烯烃化合物如乙烯的（共）聚合， 烯烃和/或丙烯酸酯。 描述了使用后期过渡金属络合物制备含极性单体的共聚物的新认可的一类配体。
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公开(公告)号：WO01092354A2
公开(公告)日：2001-12-06
申请号：PCT/US2001/017626
申请日：2001-05-31
IPC: C07C251/08 , B01J31/00 , C07C251/20 , C07C251/24 , C07F5/06 , C07F7/00 , C07F9/50 , C07F9/572 , C07F9/58 , C07F15/04 , C07F19/00 , C08F4/00 , C08F4/06 , C08F4/16 , C08F4/44 , C08F4/60 , C08F4/605 , C08F4/619 , C08F4/642 , C08F4/70 , C08F4/76 , C08F4/80 , C08F10/00 , C08F10/02 , C08F110/02 , C08F118/02 , C08F210/00 , C08F210/02
CPC classification number: C08F10/00 , B01J31/1805 , B01J31/2282 , B01J2231/122 , B01J2531/847 , C07F9/46 , C07F9/5004 , C07F9/5009 , C07F15/0066 , C07F15/04 , C07F15/045 , C08F4/619 , C08F110/02 , C08F210/02 , C08F2500/04 , C08F2500/10 , C08F2500/20 , C08F220/10 , C08F2500/03 , C08F220/12 , C08F4/6028 , C08F4/64065 , C08F4/7031 , C08F4/7029 , C08F4/7019 , C08F4/7022 , C08F4/7014 , C08F4/7008 , C08F4/7006 , C08F4/40
Abstract: In the copolymerization of ethylene and acrylate esters, the use of selected acrylate esters suppresses the formation of acrylate ester homopolymer, and/or allows the rapid analysis by H-NMR of the amount of homopolymer by product present in the copolymer, both aids in manufacturing high quality copolymers. Useful such acrylates include hexyl acrylate, 3,5,5-trimethylhexyl acrylate, 2-phenoxyethyl acrylate and 2-phenylethyl acrylate. The polymers are useful for films and molding resins.
Abstract translation: 在乙烯和丙烯酸酯的共聚中，使用选择的丙烯酸酯抑制丙烯酸酯均聚物的形成，和/或通过1 H-NMR快速分析共聚物中存在的产物的均聚物量 有助于制造高品质的共聚物。 有用的这种丙烯酸酯包括丙烯酸己酯，丙烯酸3,5,5-三甲基己酯，丙烯酸2-苯氧基乙酯和丙烯酸2-苯基乙酯。 聚合物可用于膜和模制树脂。
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公开(公告)号：WO0192354A3
公开(公告)日：2003-01-16
申请号：PCT/US0117626
申请日：2001-05-31
Applicant: DU PONT , JOHNSON LYNDA K , WANG LIN , MCCORD ELIZABETH F
Inventor： JOHNSON LYNDA K , WANG LIN , MCCORD ELIZABETH F
IPC: C07C251/08 , B01J31/00 , C07C251/20 , C07C251/24 , C07F5/06 , C07F7/00 , C07F9/50 , C07F9/572 , C07F9/58 , C07F15/04 , C07F19/00 , C08F4/00 , C08F4/06 , C08F4/16 , C08F4/44 , C08F4/60 , C08F4/605 , C08F4/619 , C08F4/642 , C08F4/70 , C08F4/76 , C08F4/80 , C08F10/00 , C08F10/02 , C08F110/02 , C08F118/02 , C08F210/00 , C08F210/02
CPC classification number: C08F10/00 , B01J31/1805 , B01J31/2282 , B01J2231/122 , B01J2531/847 , C07F9/46 , C07F9/5004 , C07F9/5009 , C07F15/0066 , C07F15/04 , C07F15/045 , C08F4/619 , C08F110/02 , C08F210/02 , C08F2500/04 , C08F2500/10 , C08F2500/20 , C08F220/10 , C08F2500/03 , C08F220/12 , C08F4/6028 , C08F4/64065 , C08F4/7031 , C08F4/7029 , C08F4/7019 , C08F4/7022 , C08F4/7014 , C08F4/7008 , C08F4/7006 , C08F4/40
Abstract: In the copolymerization of ethylene and acrylate esters, the use of selected acrylate esters suppresses the formation of acrylate ester homopolymer, and/or allows the rapid analysis by H-NMR of the amount of homopolymer by product present in the copolymer, both aids in manufacturing high quality copolymers. Useful such acrylates include hexyl acrylate, 3,5,5-trimethylhexyl acrylate, 2-phenoxyethyl acrylate and 2-phenylethyl acrylate. The polymers are useful for films and molding resins.
Abstract translation: 在乙烯和丙烯酸酯的共聚中，使用选择的丙烯酸酯抑制丙烯酸酯均聚物的形成，和/或通过1 H-NMR快速分析共聚物中存在的产物的均聚物量 有助于制造高品质的共聚物。 有用的这种丙烯酸酯包括丙烯酸己酯，丙烯酸3,5,5-三甲基己酯，丙烯酸2-苯氧基乙酯和丙烯酸2-苯基乙酯。 聚合物可用于膜和模制树脂。
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公开(公告)号：WO0192347A3
公开(公告)日：2003-01-16
申请号：PCT/US0117628
申请日：2001-05-31
Applicant: DU PONT , JOHNSON LYNDA K , BENNETT ALISON M A , DOBBS KERWIN D , IONKIN ALEX S , ITTEL STEVEN D , WANG YING , RADZEWICH CATHERINE E , WANG LIN
Inventor： JOHNSON LYNDA K , BENNETT ALISON M A , DOBBS KERWIN D , IONKIN ALEX S , ITTEL STEVEN D , WANG YING , RADZEWICH CATHERINE E , WANG LIN
IPC: C07C251/08 , B01J31/00 , C07C251/20 , C07C251/24 , C07F5/06 , C07F7/00 , C07F9/50 , C07F9/572 , C07F9/58 , C07F15/04 , C07F19/00 , C08F4/00 , C08F4/06 , C08F4/16 , C08F4/44 , C08F4/60 , C08F4/605 , C08F4/619 , C08F4/642 , C08F4/70 , C08F4/76 , C08F4/80 , C08F10/00 , C08F10/02 , C08F110/02 , C08F118/02 , C08F210/00 , C08F210/02
CPC classification number: C08F10/00 , B01J31/1805 , B01J31/2282 , B01J2231/122 , B01J2531/847 , C07F9/46 , C07F9/5004 , C07F9/5009 , C07F15/0066 , C07F15/04 , C07F15/045 , C08F4/619 , C08F110/02 , C08F210/02 , C08F2500/04 , C08F2500/10 , C08F2500/20 , C08F220/10 , C08F2500/03 , C08F220/12 , C08F4/6028 , C08F4/64065 , C08F4/7031 , C08F4/7029 , C08F4/7019 , C08F4/7022 , C08F4/7014 , C08F4/7008 , C08F4/7006 , C08F4/40
Abstract: Polymers are produced using transition metal complexes that have sites capable of binding a Lewis acid in close proximity to the metal center.
Abstract translation: 使用具有能够紧密接近金属中心的路易斯酸结合位点的过渡金属络合物制备聚合物。
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公开(公告)号：WO01092347A2
公开(公告)日：2001-12-06
申请号：PCT/US2001/017628
申请日：2001-05-31
IPC: C07C251/08 , B01J31/00 , C07C251/20 , C07C251/24 , C07F5/06 , C07F7/00 , C07F9/50 , C07F9/572 , C07F9/58 , C07F15/04 , C07F19/00 , C08F4/00 , C08F4/06 , C08F4/16 , C08F4/44 , C08F4/60 , C08F4/605 , C08F4/619 , C08F4/642 , C08F4/70 , C08F4/76 , C08F4/80 , C08F10/00 , C08F10/02 , C08F110/02 , C08F118/02 , C08F210/00 , C08F210/02
CPC classification number: C08F10/00 , B01J31/1805 , B01J31/2282 , B01J2231/122 , B01J2531/847 , C07F9/46 , C07F9/5004 , C07F9/5009 , C07F15/0066 , C07F15/04 , C07F15/045 , C08F4/619 , C08F110/02 , C08F210/02 , C08F2500/04 , C08F2500/10 , C08F2500/20 , C08F220/10 , C08F2500/03 , C08F220/12 , C08F4/6028 , C08F4/64065 , C08F4/7031 , C08F4/7029 , C08F4/7019 , C08F4/7022 , C08F4/7014 , C08F4/7008 , C08F4/7006 , C08F4/40
Abstract: Polymers are produced using transition metal complexes that have sites capable of binding a Lewis acid in close proximity to the metal center.
Abstract translation: 使用具有能够紧密接近金属中心的路易斯酸结合位点的过渡金属络合物制备聚合物。
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