公开(公告)号：WO2012022998A1

公开(公告)日：2012-02-23

申请号：PCT/IB2010/002067

申请日：2010-08-18

Applicant: VEOLIA WATER SOLUTIONS & TECHNOLOGIES SUPPORT ,  WERKER, Alan, Gideon ,  JOHANSSON, Peter, Stig, Tomas ,  MAGNUSSON, Per, Olof, Gösta ,  MAURER, Franciscus, Hubertus, Jacobus ,  JANNASCH, Patric

Inventor： WERKER, Alan, Gideon ,  JOHANSSON, Peter, Stig, Tomas ,  MAGNUSSON, Per, Olof, Gösta ,  MAURER, Franciscus, Hubertus, Jacobus ,  JANNASCH, Patric

IPC: C08G63/89

CPC classification number: C08G63/89 ,  C08G63/06

Abstract: The invention is directed to a method of increasing the chemical and/or thermal stability of PHA in biomass where the biomass is contained within mixed liquor, and wherein the mixed liquor is treated by a combination of removing water from the mixed liquor and pH adjustment of the mixed liquor or maintenance of the pH of the mixed liquor within a selected pH range, and wherein the method includes reducing the pH of the mixed liquor below 6, or maintaining the pH of the mixed liquor below 6 for a selected period of time, and wherein the pH adjustment of the mixed liquor to below 6 or the maintenance of the pH of the mixed liquor below 6 gives rise to an increase in chemical and/or thermal stability of the PHA in the biomass.

Abstract translation: 本发明涉及增加PHA在生物质中的化学和/或热稳定性的方法，其中生物质包含在混合液中，并且其中混合液通过从混合液中除去水和pH调节 混合液或在选定的pH范围内维持混合液的pH，并且其中所述方法包括将混合液的pH降低至6以下，或将混合液的pH保持在低于6的选定时间段内， 并且其中将混合液的pH调节至低于6或维持低于6的混合液的pH导致PHA在生物质中的化学和/或热稳定性的增加。

公开(公告)号：WO2011108916A3

公开(公告)日：2011-11-24

申请号：PCT/MY2010000333

申请日：2010-12-30

Applicant: UNIV PUTRA MALAYSIA ,  HASSAN MOHD ALI ,  MOHAMMADI MITRA ,  AB RAZAK NOR ASMA ,  CHONG MEI LING ,  ABD AZIZ SURAINI ,  ABDULLAH AMIRUL AL-ASHRAF ,  CHE MAN HASFALINA ,  ANIS SITI NOR SYAIRAH ,  PHANG LAI YEE ,  SHIRAI YOSHIHITO ,  WAN YUNUS WAN MD ZIN

Inventor： HASSAN MOHD ALI ,  MOHAMMADI MITRA ,  AB RAZAK NOR ASMA ,  CHONG MEI LING ,  ABD AZIZ SURAINI ,  ABDULLAH AMIRUL AL-ASHRAF ,  CHE MAN HASFALINA ,  ANIS SITI NOR SYAIRAH ,  PHANG LAI YEE ,  SHIRAI YOSHIHITO ,  WAN YUNUS WAN MD ZIN

IPC: C12P7/62 ,  C12N1/00 ,  C12S3/18

CPC classification number: C12P7/625 ,  C08G63/89

Abstract: The present invention relates to a method to recover an intracellular polyhydroxyalkanoates (PHA). The method includes the steps of (a) separating culture medium containing PHA-rich cells using centrifugation, (b) rinsing pellet obtained from step (a) with distilled water, (c) freeze- drying the pellet obtained in step (b), (d) adding distilled water to the freeze-dried sample, (e) separating non-PHA cellular material (NPCM) from PHA granules, (f) washing the pellet containing PHA from step (e) by distilled water and centrifuging for producing final pellet, and (g) freeze-drying the pellet produced from step (f).

Abstract translation: 本发明涉及回收细胞内聚羟基链烷酸酯（PHA）的方法。 该方法包括以下步骤：（a）使用离心分离富含PHA的细胞的培养基，（b）用蒸馏水冲洗步骤（a）获得的沉淀，（c）冷冻干燥步骤（b）中获得的沉淀， （d）向冷冻干燥的样品中加入蒸馏水，（e）从PHA颗粒中分离非PHA细胞物质（NPCM），（f）用蒸馏水洗涤步骤（e）中含有PHA的沉淀并离心以产生最终 （g）冷冻干燥步骤（f）产生的小球。

公开(公告)号：WO2008123149A1

公开(公告)日：2008-10-16

申请号：PCT/JP2008/055304

申请日：2008-03-21

Applicant: 三菱化学株式会社 ,  熊澤 勝久 ,  田浦 隆之 ,  山本 正規

Inventor： 熊澤 勝久 ,  田浦 隆之 ,  山本 正規

IPC: B65G53/04

CPC classification number: C08G64/403 ,  C08G63/89

Abstract: 　吸湿性のポリマーペレットを気力輸送する際に、ポリマーペレットの含水率を増大させることなく簡便な手段で輸送することができるポリマーペレットの輸送方法及びポリマーペレットの貯蔵方法を提供する。 　ポリマーペレットを圧力気体流と共に輸送配管を介し気力輸送するポリマーペレットの気力輸送方法であって、ポリマーペレットの気力輸送に用いる気体に含まれる水分量を低減し当該気体の露点を０°C以下に調整する気体除湿工程と、気体除湿工程において露点が０°C以下に調整された気体を圧縮する気体圧縮工程と、気体圧縮工程において圧縮された圧力気体をポリマーペレット１トン当たり５０Ｎｍ ３ ／時間～６００Ｎｍ ３ ／時間で輸送配管内に供給する圧力気体供給工程と、圧力気体供給工程において輸送配管に供給された圧力気体流と共にポリマーペレットを輸送配管を介し気力輸送する輸送工程と、を有することを特徴とするポリマーペレットの気力輸送方法。

Abstract translation: 输送聚合物颗粒的方法，其中在吸湿聚合物颗粒的气动输送中，可以通过容易的方式进行运输，而不增加聚合物颗粒的含水量; 以及储存聚合物颗粒的相关方法。 涉及将聚合物颗粒与压力气体流动通过输送管道气动输送的气动聚合物颗粒输送的方法的特征在于包括减少聚合物颗粒的气动输送中使用的气体的含水量的气体除湿步骤，以便 将气体的露点调节至0℃以下; 在气体除湿工序中将其露点调节为0℃以下的气体进行压缩的气体压缩工序; 所述压力气体供给步骤以每吨聚合物粒料50〜600Nm 3 / hr的速率在所述输送管道中供给在所述气体压缩工序中被压缩的压力气体; 以及通过聚合物粒料的输送管道进行气动输送的输送步骤，以及在压力气体供给步骤中已经供给到输送管道中的压力气体流。

公开(公告)号：WO2006088819B1

公开(公告)日：2007-04-12

申请号：PCT/US2006005083

申请日：2006-02-13

Applicant: IBAR JEAN-PIERRE

Inventor： IBAR JEAN-PIERRE

IPC: C08G64/00 ,  C08G63/02 ,  C08G69/08

CPC classification number: C08G64/403 ,  C08G63/89 ,  C08L77/06

Abstract: A process for manufacturing a polymer having a molecular weight in excess of 5,000, and preferably in excess of 40,000, comprises, producing a polymerized reaction mass in which the polymer is dispersed, the reaction mass including solvents), unreacted monomer and other unwanted contaminants; feeding the reaction mass to a means for disentangling the polymer's molecules to produce a modified polymer in the reaction mass; feeding the modified polymer in the reaction mass to a polymer-recovering means; removing the unwanted volatiles and other byproducts; and, recovering a high molecular weight substantially pure modified polymer having substantially the same molecular weight as the polymer fed to the disentangling means and a viscosity at least 10% lower than that of the polymer fed to the disentangling means.

Abstract translation: 制造分子量超过5,000，优选超过40,000的聚合物的方法包括制备其中分散有聚合物的聚合反应物质，反应物质包括溶剂），未反应的单体和其它不需要的污染物; 将反应物料送入用于解聚聚合物分子的装置以在反应物质中产生改性聚合物; 将反应物质中的改性聚合物进料到聚合物回收装置; 去除不需要的挥发物和其他副产物; 并且回收具有与供给到解缠装置的聚合物基本上相同的分子量的高分子量基本上纯的改性聚合物，并且粘度比供给到解缠装置的聚合物的粘度低至少10％。

公开(公告)号：WO2003006526A1

公开(公告)日：2003-01-23

申请号：PCT/JP2002/006836

申请日：2002-07-05

Applicant: KUREHA CHEMICAL INDUSTRY COMPANY, LIMITED ,  YAMANE, Kazuyuki ,  KAWAKAMI, Yukichika ,  SATO, Hiroyuki ,  HOSHI, Tomohiro

Inventor： YAMANE, Kazuyuki ,  KAWAKAMI, Yukichika ,  SATO, Hiroyuki ,  HOSHI, Tomohiro

IPC: C08G63/78

CPC classification number: B01J19/24 ,  B01J19/02 ,  B01J19/2415 ,  B01J2219/0236 ,  B01J2219/1943 ,  B01J2219/1946 ,  C08G63/08 ,  C08G63/78 ,  C08G63/785 ,  C08G63/89

Abstract: The invention provides a polyester production process by bulk polymerization in a reactor, wherein the volume of the resulting polyester is shrunk for a release from the inner surface of the reactor, so that the polyester can be recovered in the form of a bulky mass. The invention also provides a reactor for bulk polymerization for polyester, which comprises an inner surface that enabling the resulting polyester to be released therefrom upon its volume shrinkage.

Abstract translation: 本发明提供了在反应器中本体聚合的聚酯制造方法，其中所得聚酯的体积收缩以从反应器的内表面释放，使得聚酯可以以体积质量的形式回收。 本发明还提供了一种用于聚酯的本体聚合反应器，其包括使得所得聚酯在其体积收缩时能够从其中释放的内表面。

公开(公告)号：WO01034826A1

公开(公告)日：2001-05-17

申请号：PCT/EP2000/010442

申请日：2000-10-20

IPC: C08G63/89 ,  C12P7/62

CPC classification number: C12P7/625 ,  C08G63/89

Abstract: The invention relates to a method for the production of a homo- or copolymer of a poly- beta -hydroxyalkanoic acid (PHA) from biomass, characterized in that the biomass is extracted by 1-methyl-2-pyrrolidone (NMP), optionally using a water binding agent, from a viscous suspension which forms at a temperature >/= of 40 DEG C. PHA-containing solution is separated out and PHA is subsequently precipitated out.

Abstract translation: 本发明涉及一种用于获得从生物质聚-β--hydroxyalkansäure（PHA），其特征在于的均聚物或共聚物，其与1-甲基-2-吡咯烷酮（NMP），任选地添加水结合剂的生物量， 被提取，从在温度> / = 40℃，然后将PHA沉淀所得粘性悬浮液含PHA的溶液中分离。

公开(公告)号：WO99051760A1

公开(公告)日：1999-10-14

申请号：PCT/US1999/007689

申请日：1999-04-08

IPC: C12P7/62 ,  C08G63/89 ,  C08G63/90 ,  C08G63/06 ,  C08G63/88 ,  C08G63/91 ,  C08L67/04

CPC classification number: C08G63/90 ,  C08G63/89

Abstract: Methods for the recovery and purification of polyhydroxyalkanoates (PHAs) from biomass containing PHAs, wherein the methods include treating the biomass or partially purified PHA with ozone, in at least one step of a purification process, have been developed. Treatment of PHA-containing biomass or partially purified PHA with ozone yields an enhanced level of purity suitable for coating and other applications. The ozone treatment also has the added advantage that the resulting PHA polymer or polymer latex is essentially odor-free. The ozone treatment may be used alone or in combination with other treatment, extraction, and separation stages, and is especially suitable for the treatment of PHA-containing latexes, slurries, suspensions, and organic solutions.

Abstract translation: 已经开发了用于从包含PHAs的生物质中回收和纯化聚羟基链烷酸酯（PHA）的方法，其中所述方法包括在纯化过程的至少一个步骤中用臭氧处理生物质或部分纯化的PHA。 用臭氧处理含PHA的生物质或部分纯化的PHA产生适于涂层和其它应用的增强的纯度。 臭氧处理还具有附加的优点，即所得PHA聚合物或聚合物胶乳基本上不含气味。 臭氧处理可以单独使用或与其他处理，提取和分离阶段组合使用，特别适用于处理含PHA的胶乳，浆液，悬浮液和有机溶液。

公开(公告)号：WO1997015681A1

公开(公告)日：1997-05-01

申请号：PCT/US1996016921

申请日：1996-10-23

Applicant: METABOLIX, INC.

Inventor： METABOLIX, INC. ,  MARTIN, David, P. ,  PEOPLES, Oliver, P. ,  WILLIAMS, Simon, F.

IPC: C12P07/62

CPC classification number: C08G63/89 ,  C12P7/625

Abstract: Methods are provided for separating polyhydroxyalkanoates ("PHAs") from plants, such as transgenic oil crop plants. The methods advantageously permit both the oil and the PHAs to be recovered from the plant biomass. To isolate the PHAs, in one embodiment, a biomass derived from an oil crop plant is pre-processed, for example by grinding, crushing or rolling. The oil then is extracted from the biomass with a first solvent in which the oil is soluble and in which the PHAs are not highly soluble to remove the oil. The biomass then can be extracted with a second solvent in which the PHA is soluble, to separate the PHA from the biomass. Alternatively, the PHA-containing biomass is treated with a chemical or biochemical agent, such as an enzyme, to chemically transform the PHA into a PHA derivative. The PHA derivative then is separated from the mixture using, for example, a physical separation process such as distillation, extraction or chromatography. Advantageously, using the method, the plant oils, the PHAs and PHA derivatives can be recovered and purified on a large scale from oil containing plants such as transgenic oil crop plants.

Abstract translation: 提供了从植物如转基因油料作物植物中分离聚羟基链烷酸酯（“PHAs”）的方法。 该方法有利地允许从植物生物质中回收油和PHA。 为了分离PHA，在一个实施方案中，来自油料作物植物的生物质被预处理，例如通过研磨，破碎或轧制。 然后用第一溶剂从生物质中提取油，其中油是可溶的，并且其中PHAs不是高度可溶的以除去油。 然后生物质可以用其中PHA可溶的第二溶剂萃取，以将PHA与生物质分离。 或者，将含PHA的生物质用化学或生化剂如酶处理，以将PHA化学转化为PHA衍生物。 然后使用例如物理分离方法如蒸馏，萃取或色谱法将PHA衍生物与混合物分离。 有利地，使用该方法，植物油，PHA和PHA衍生物可以从含油植物如转基因油料作物植物大规模回收和纯化。

公开(公告)号：WO2016081902A1

公开(公告)日：2016-05-26

申请号：PCT/US2015/061991

申请日：2015-11-20

Applicant: FULL CYCLE BIOPLASTICS INC.

Inventor： ANDERSON, Jeff H. ,  ANDERSON, Dane H.

IPC: C12P7/62 ,  C02F3/00

CPC classification number: C12P7/6436 ,  B01D61/025 ,  B01D61/027 ,  B01D61/12 ,  B01D2311/2607 ,  B01D2313/34 ,  C08G63/06 ,  C08G63/89 ,  C12M23/58 ,  C12M29/04 ,  C12M41/32 ,  C12P7/625 ,  C12Q3/00

Abstract: Producing a resin from an organic waste product includes assessing a weight percent of a first volatile fatty acid and a weight percent of a second volatile fatty acid in a liquid mixture having volatile fatty acids from the organic waste product. The weight percent of the volatile fatty acids is based on the total weight of the carboxylic acids in the liquid mixture, the total weight of volatile fatty acids in the liquid mixture, or the total weight of lactic acid and volatile fatty acids in the mixture. A ratio of the weight percent of the first volatile fatty acid to the weight percent of the second volatile fatty acid in the liquid mixture is adjusted to yield a modified liquid mixture. The modified liquid is combined with polyhydroxyalkanoate-producing bacteria to yield a polyhydroxyalkanoate copolymer; and the polyhydroxyalkanoate copolymer is extracted from the polyhydroxyalkanoate-producing bacteria.

Abstract translation: 从有机废物产生树脂包括在具有来自有机废物的挥发性脂肪酸的液体混合物中评估第一挥发性脂肪酸的重量百分数和第二挥发性脂肪酸的重量百分比。 挥发性脂肪酸的重量百分比是基于液体混合物中羧酸的总重量，液体混合物中挥发性脂肪酸的总重量，或混合物中乳酸和挥发性脂肪酸的总重量。 调节液体混合物中第一挥发性脂肪酸的重量百分数与第二挥发性脂肪酸的重量百分比的比例，得到改性的液体混合物。 将改性液体与产生聚羟基链烷酸酯的细菌结合产生聚羟基链烷酸酯共聚物; 从聚羟基链烷酸酯生产菌中提取聚羟基链烷酸酯共聚物。

公开(公告)号：WO2007037968A3

公开(公告)日：2010-09-02

申请号：PCT/US2006035364

申请日：2006-09-13

Applicant: EASTMAN CHEM CO

Inventor： PARKER KENNY RANDOLPH ,  LIN ROBERT ,  ISAAC RAYMOND ,  HALL DUANE ALAN

IPC: B01J8/22 ,  B01D9/00 ,  B01D63/06 ,  B01J8/00 ,  B29B9/00 ,  C08G63/88

CPC classification number: C08G63/89 ,  B01D61/18 ,  B01D61/20 ,  B01J8/006 ,  B01J8/007 ,  B01J8/22 ,  B01J8/228 ,  B01J2208/00539 ,  B01J2208/00672 ,  B01J2208/00761 ,  B01J2208/00778 ,  B01J2219/00162 ,  B01J2219/00252

Abstract: A process and apparatus which reduces the fines in a liquid discharge stream and/or increases the dryness of a solids discharge stream while under a pressure equal to or greater than the vapor pressure of the liquid. There is provided a process for separating particles such as polyethylene terephthalate or polyethylene naphthalate from a liquid in a slurry comprising: a. feeding a slurry comprising solid particles and a liquid into a within a separation zone maintained at a pressure equal to or greater than the vapor pressure of the liquid; b. contacting the slurry in the separation zone with a porous filter, optionally a microfilter, nanofilter, reverse osmosis filter, or ultrafilter, and separating liquid from the particles, wherein the liquid flows through the filter into an outer annulus defined as a space between the wall of the separation device and the filter, and said porous filter optionally having a terminal point beyond which the separated liquid does not pass from the outer annulus back through the filter; c. accumulating no liquid in the outer annulus or accumulating liquid in the outer annulus at a level below or in front of the terminal point, and continuously discharging the separated liquid from the outer annulus through a liquid outlet; d. decoupling the particles from the separation zone through the solids outlet to a low pressure below the vapor pressure of the liquid at the liquid temperature within the separation zone while maintaining a pressure on the particles prior to decoupling at or above the vapor pressure of the liquid within the separation zone.

Abstract translation: 一种在液体排出流中减少细粉和/或在等于或大于液体的蒸气压的压力下增加固体排出流的干度的方法和装置。 提供了一种用于从浆液中的液体分离颗粒如聚对苯二甲酸乙二醇酯或聚萘二甲酸乙二醇酯的方法，包括：a。 将包含固体颗粒和液体的浆料进料到保持在等于或大于液体的蒸气压的压力的分离区内; 湾 使分离区中的浆料与多孔过滤器，任选的微过滤器，纳米过滤器，反渗透过滤器或超滤器接触，并将液体从颗粒中分离，其中液体流过过滤器，形成外壁，其被定义为壁之间的空间 分离装置和过滤器，并且所述多孔过滤器任选地具有终点，超过该终点，分离的液体不从外环通过过滤器; C。 在外环形空间中没有液体或在外环空中积聚液体在终点下方或前方的水平，并且通过液体出口连续排出来自外环的分离的液体; 天。 在分离区内的液体温度下将来自分离区的颗粒通过固体出口分离成低于液体蒸气压的低压，同时在等于或高于液体的蒸汽压力的去耦之前保持颗粒上的压力， 分离区。