公开(公告)号：WO01096947A2

公开(公告)日：2001-12-20

申请号：PCT/US2001/018215

申请日：2001-06-06

IPC: G03C7/46 ,  G03C1/42 ,  G03C1/498 ,  G03C7/305 ,  G03C7/392 ,  G03C7/407 ,  G03C7/413 ,  G03C8/06 ,  G03C8/40 ,  G03C

CPC classification number: G03C7/30541 ,  G03C1/42 ,  G03C1/49845 ,  G03C7/30552 ,  G03C7/407 ,  G03C7/4136 ,  G03C8/4013 ,  G03C8/408 ,  G03C2200/43 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16

Abstract: The present invention is directed to a method of processing color photographic film that has been imagewise exposed in a camera, said film having at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, binder, and dye-providing coupler, which method in order comprises: (a) thermally developing the film step without any externally applied developing agent, comprising heating said film to a temperature greater than 80 DEG C in an essentially dry process, such that an internally located blocked developing agent in reactive association with each of said three light-sensitive units becomes unblocked to form a developing agent, whereby the unblocked developing agent forms dyes by reacting with the dye-providing couplers to form a color negative image; (b) processing the developed film of step (a) by contacting it with a non-blocked developing agent, under agitation at a temperature of 30 to 50 DEG C under aqueous alkaline conditions, without forming a color negative image in the film by reaction of the non-blocked developing agent with dye-proving couplers inside the silver-halide emulsions, and (c) desilvering said film in one more desilvering solutions to remove unwanted silver and/or silver halide, thereby forming a color negative image; and (d) thereafter forming a positive-image color print from the desilvered film.

Abstract translation: 本发明涉及一种在相机中成像曝光的彩色照相胶片的处理方法，所述胶片具有至少三个在不同波长区域具有各自敏感度的光敏单元，每个单元包括至少一个 感光卤化银乳剂，粘合剂和染料提供成色剂，该方法依次包括：（a）不用任何外用显影剂将膜步骤热显影，包括将所述膜加热至大于80℃的温度 使得与所述三个感光单元中的每一个反应性相关联的内部定位的阻挡显影剂变得未封闭以形成显影剂，由此未封闭的显影剂通过与提供染料的成色剂反应形成染料以形成 彩色负像 （b）在水性碱性条件下，在30〜50℃的温度搅拌下，通过与未封闭的显影剂接触来处理显影的步骤（a）的膜，而不通过反应在膜中形成彩色负像 的非阻挡显影剂，其中染料验证成色剂在卤化银乳剂内，和（c）将一种更多的脱银溶液除去所述膜以除去不需要的银和/或卤化银，从而形成彩色负像; 和（d）之后从脱膜膜形成正像彩色印刷品。

公开(公告)号：WO01096943A2

公开(公告)日：2001-12-20

申请号：PCT/US2001/016885

申请日：2001-05-24

IPC: G03C5/08 ,  G03C1/42 ,  G03C1/498 ,  G03C5/26 ,  G03C7/30 ,  G03C7/305 ,  G03C7/407 ,  G03C7/42 ,  G03C8/40 ,  G03C11/24 ,  G03C

CPC classification number: G03C7/30541 ,  G03C1/42 ,  G03C1/498 ,  G03C1/49827 ,  G03C1/49881 ,  G03C5/261 ,  G03C7/30 ,  G03C7/3041 ,  G03C7/407 ,  G03C2007/3043

Abstract: The present invention is directed to a method of processing color photographic film that has been imagewise exposed in a camera, said film having at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, one or more organic silver salts, a binder, and dye-providing coupler, which method in order comprises: (a) thermally developing the film step without any externally applied developing agent, comprising heating said film to a temperature greater than 80 DEG C in an essentially dry process, such that an internally located blocked developing agent in reactive association with each of said three light-sensitive units becomes unblocked to form a developing agent, whereby the unblocked developing agent forms dyes by reacting with the dye-providing couplers to form a color image; and (b) scanning the color image to provide a digital electronic record capable of generating a positive color image in a display element, wherein the silver halide and the organic silver salts in the film are removed and/or stabilized before or after step (b), such that the film is in an archival state. Typically, a positive-image color print from the desilvered film. Optionally, the developed metallic silver can also be removed.

Abstract translation: 本发明涉及一种在相机中成像曝光的彩色照相胶片的处理方法，所述胶片具有至少三个在不同波长区域具有各自敏感度的光敏单元，每个单元包括至少一个 感光卤化银乳剂，一种或多种有机银盐，粘合剂和染料提供成色剂，该方法依次包括：（a）不用任何外用显影剂将薄膜步骤热显影，包括将所述薄膜加热至 在基本上干燥的过程中温度大于80℃，使得与所述三个感光单元中的每一个反应性结合的内部定位的阻挡显影剂变得未封闭以形成显影剂，由此未封闭的显影剂通过使 染料提供成色剂形成彩色图像; 和（b）扫描彩色图像以提供能够在显示元件中产生正彩色图像的数字电子记录，其中，在步骤（b）之前或之后，膜中的卤化银和有机银盐被去除和/或稳定 ），使得电影处于档案状态。 通常，来自脱膜膜的正像彩色印刷品。 任选地，还可以除去显影的金属银。

公开(公告)号：WO0196943A3

公开(公告)日：2002-05-30

申请号：PCT/US0116885

申请日：2001-05-24

Applicant: EASTMAN KODAK CO

Inventor： IRVING MARK EDWARD ,  SZAJEWSKI RICHARD PETER

IPC: G03C5/08 ,  G03C1/42 ,  G03C1/498 ,  G03C5/26 ,  G03C7/30 ,  G03C7/305 ,  G03C7/407 ,  G03C7/42 ,  G03C8/40 ,  G03C11/24

CPC classification number: G03C7/30541 ,  G03C1/42 ,  G03C1/498 ,  G03C1/49827 ,  G03C1/49881 ,  G03C5/261 ,  G03C7/30 ,  G03C7/3041 ,  G03C7/407 ,  G03C2007/3043

Abstract: The present invention is directed to a method of processing color photographic film that has been imagewise exposed in a camera, said film having at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, one or more organic silver salts, a binder, and dye-providing coupler, which method in order comprises: (a) thermally developing the film step without any externally applied developing agent, comprising heating said film to a temperature greater than 80 DEG C in an essentially dry process, such that an internally located blocked developing agent in reactive association with each of said three light-sensitive units becomes unblocked to form a developing agent, whereby the unblocked developing agent forms dyes by reacting with the dye-providing couplers to form a color image; and (b) scanning the color image to provide a digital electronic record capable of generating a positive color image in a display element, wherein the silver halide and the organic silver salts in the film are removed and/or stabilized before or after step (b), such that the film is in an archival state. Typically, a positive-image color print from the desilvered film. Optionally, the developed metallic silver can also be removed.

Abstract translation: 本发明涉及一种在相机中成像曝光的彩色照相胶片的处理方法，所述胶片具有至少三个在不同波长区域具有各自敏感度的光敏单元，每个单元包括至少一个 感光卤化银乳剂，一种或多种有机银盐，粘合剂和染料提供成色剂，该方法依次包括：（a）不用任何外用显影剂将薄膜步骤热显影，包括将所述薄膜加热至 在基本上干燥的过程中温度大于80℃，使得与所述三个感光单元中的每一个反应性结合的内部定位的阻挡显影剂变得未封闭以形成显影剂，由此未封闭的显影剂通过使 染料提供成色剂形成彩色图像; 和（b）扫描彩色图像以提供能够在显示元件中产生正彩色图像的数字电子记录，其中，在步骤（b）之前或之后，膜中的卤化银和有机银盐被去除和/或稳定 ），使得电影处于档案状态。 通常，来自脱膜膜的正像彩色印刷品。 任选地，还可以除去显影的金属银。

公开(公告)号：WO0196954A2

公开(公告)日：2001-12-20

申请号：PCT/US0118753

申请日：2001-06-08

Applicant: EASTMAN KODAK CO

Inventor： YANG XIQIANG ,  OWCZARCZYK ZBYSLAW ROMAN ,  SOUTHBY DAVID THOMAS

IPC: G03C7/407 ,  G03C1/42 ,  G03C1/43 ,  G03C1/498 ,  G03C5/08 ,  G03C7/30 ,  G03C7/305 ,  G03C7/392 ,  G03C7/413 ,  G03C7/46 ,  G03C8/40 ,  G03C8/00

CPC classification number: G03C7/39216 ,  G03C1/42 ,  G03C1/43 ,  G03C1/49827 ,  G03C1/49845 ,  G03C7/3003 ,  G03C7/30511 ,  G03C7/30541 ,  G03C7/413 ,  G03C8/4013 ,  G03C8/402 ,  G03C8/408 ,  G03C2200/43 ,  G03C2200/52 ,  G03C2200/60 ,  Y10S430/158 ,  Y10S430/159 ,  Y10S430/165

Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a phenolic activating agent in combination with a blocked color-forming agent of Structure (I) wherein PUG is a photographically useful color-forming agent, LINK 1 and LINK 2 are linking groups; TIME is a timing group; HET is a heterocyclic group, and the other groups are as defined in the specification.

Abstract translation: 本发明包括成像元件，该成像元件具有与其相关联的酚类活化剂与其中PUG是照相用的成色剂的结构（I）的阻挡着色剂组合的成像层，LINK 1和LINK 2是连接基团 ; TIME是一个时间组; HET是杂环基团，其它基团如说明书中所定义。

公开(公告)号：WO1998015874A1

公开(公告)日：1998-04-16

申请号：PCT/JP1997003629

申请日：1997-10-09

Applicant: KONICA CORPORATION ,  IWASAKI, Toshihiko ,  IWAGAKI, Masaru

Inventor： KONICA CORPORATION

IPC: G03C01/00

CPC classification number: G03C7/30 ,  G03C1/815 ,  G03C3/00 ,  G03C7/3029 ,  G03C7/30541 ,  G03C7/3225 ,  G03C7/333 ,  G03C7/34 ,  G03C7/36 ,  G03C7/38 ,  G03C2003/006 ,  G03C2007/3034 ,  G03C2200/16

Abstract: A silver halide photosensitive material, wherein at least one of yellow, magenta and cyan couplers is contained in a mixed state in a layer of the same photosensitivity on a transparent support, a monochromatic picture being formed thereon by color developing a picture after it has been exposed, characterized in that, among the yellow, magenta and cyan couplers, the magenta coupler has the highest relative coupling speed with respect to an oxidation product of a color developing agent.

Abstract translation: 一种卤化银感光材料，其中黄色，品红色和青色成色剂中的至少一种在透明支撑体上具有相同光敏性的层中的混合状态，通过在其上形成图像之后通过彩色显影来形成单色图像 其特征在于，在黄色，品红色和青色成色剂中，洋红色成色剂相对于彩色显影剂的氧化产物具有最高的相对耦合速度。

公开(公告)号：WO2006059061A1

公开(公告)日：2006-06-08

申请号：PCT/GB2005/004274

申请日：2005-11-03

Applicant: EASTMAN KODAK COMPANY ,  TSOI, Siu, Chung ,  STANLEY, Paul ,  ZUBERI, Tania ,  SINGER, Stephen ,  LUSHINGTON, Kenneth

Inventor： TSOI, Siu, Chung ,  STANLEY, Paul ,  ZUBERI, Tania ,  SINGER, Stephen ,  LUSHINGTON, Kenneth

IPC: G03C7/305

CPC classification number: G03C7/30541 ,  G03C7/30552 ,  G03C7/30558 ,  G03C2200/33

Abstract: The present invention provides a photographic element comprising a support bearing at least one silver halide emulsion layer and associated therewith a coupler capable of releasing a development accelerator on colour development in the presence of a bi-nucleophilic agent, the coupler having the Formula (I) wherein COUP is a coupler moiety; T is a timing group and n is 0, 1 or 2; X 1 and X 2 are independently selected from an unsubstituted or substituted alkyl, -CH 2 OCOR-, -CH 2 COOR'-, -CH 2 NHCOR­-CH 2 NRCOR', aryl or heterocyclic group, wherein R and R' are each an unsubstituted or substituted alkyl, aryl or heterocyclic group and R' may also be hydrogen; or X 1 and X 2 may combine to form an unsubstituted or substituted cycloalkyl ring, which may include one, or more heteroatoms selected from nitrogen, oxygen and sulfur; X 3 and X 4 are independently selected from hydrogen or an unsubstituted or substituted alkyl, aryl or heterocyclic group; or X 1 to X 4 may combine to form an unsubstituted or substituted cycloalkyl ring which may include one or more heteroatoms selected from nitrogen, oxygen and sulfur; L is a linking group and r is 0 or 1 or 2; and A is a group capable of being adsorbed to the silver halide surface. The elements comprising the DARCs allow a speed and contrast increase under standard processing conditions. In addition, they can provide synergistic speed improvement when used in combination with electron transfer agent-releasing couplers.

Abstract translation: 本发明提供了一种照相元件，其包含支承至少一个卤化银乳剂层的支持体，并与其相关联，在双亲核剂存在下能够释放显影促进剂的显影促进剂，所述成色剂具有式（I） 其中COUP是成色剂部分; T是定时组，n是0,1或2; X 1和X 2独立地选自未取代或取代的烷基，-CH 2 OROR，-CH 2， 芳基或杂环基，其中R和R'各自为未取代或取代的烷基，芳基或取代的烷基，芳基或杂环基， 杂环基和R'也可以是氢; 或X 1和X 2可以结合形成未取代或取代的环烷基环，其可以包括一个或多个选自氮，氧和硫的杂原子; X 3和X 4独立地选自氢或未取代或取代的烷基，芳基或杂环基; 或X 1至X 4可以结合形成未取代或取代的环烷基环，其可以包括一个或多个选自氮，氧和硫的杂原子; L为连接基团，r为0或1或2; 而A是能够吸附在卤化银表面上的基团。 包括DARC的元件允许在标准加工条件下的速度和对比度增加。 此外，当与电子转移剂释放成色剂组合使用时，它们可以提供协同的速度改进。

公开(公告)号：WO01096948A2

公开(公告)日：2001-12-20

申请号：PCT/US2001/018843

申请日：2001-06-11

IPC: G03C1/42 ,  G03C1/498 ,  G03C5/26 ,  G03C7/30 ,  G03C7/305 ,  G03C7/392 ,  G03C7/407 ,  G03C7/46 ,  G03C8/40 ,  G03C1/00

CPC classification number: G03C8/408 ,  G03C1/42 ,  G03C1/498 ,  G03C5/261 ,  G03C7/30 ,  G03C7/3005 ,  G03C7/30511 ,  G03C7/30541 ,  G03C7/407 ,  G03C2200/21 ,  Y10S430/156 ,  Y10S430/16

Abstract: A light sensitive silver halide color photographic element having a common chromogenic coupler and a distinct developer associated with each color forming layer unit is disclosed. In a first embodiment, the light sensitive silver halide color photographic element has a red light sensitive silver halide layer unit and a first blocked coupling developer, a green light sensitive silver halide layer unit and a second blocked coupling developer and a blue light sensitive silver halide layer unit having a third blocked coupling developer and wherein each layer unit has the same chromogenic coupler. In a second embodiment, the light sensitive silver halide color photographic element has a red light sensitive silver halide layer unit and a first blocked coupling developer, a green light sensitive silver halide layer unit and a second blocked coupling developer, and a blue light sensitive silver halide layer unit having a third blocked coupling developer. By means of the present invention, light sensitive color photothermographic elements can form yellow, magenta and cyan dye records of consistent density forming ability and conistent stability in all three color records. The present invention also relates to a novel blocked phenylenediamine developer useful in the imaging elements according to the present invention.

Abstract translation: 公开了具有共同显色成色剂的感光卤化银彩色照相元件和与每种颜色形成层单元相关联的不同显影剂。 在第一实施例中，感光卤化银彩色照相元件具有红色感光卤化银层单元和第一阻挡耦合显影剂，绿色感光卤化银层单元和第二阻挡耦合显影剂和蓝色感光卤化银 层单元具有第三阻塞耦合显影剂，并且其中每个层单元具有相同的显色成色剂。 在第二实施方案中，感光卤化银彩色照相元件具有红色感光卤化银层单元和第一阻挡耦合显影剂，绿色感光卤化银层单元和第二阻挡耦合显影剂，以及蓝色感光银 卤化物层单元具有第三阻塞耦合显影剂。 通过本发明，光敏彩色光热敏成像元件可以形成一致的密度形成能力的黄色，品红色和青色染料记录，并且在所有三种颜色记录中均具有一致的稳定性。 本发明还涉及可用于根据本发明的成像元件的新型封端苯二胺显影剂。

公开(公告)号：WO1997021147A1

公开(公告)日：1997-06-12

申请号：PCT/GB1996002775

申请日：1996-11-11

Applicant: ILFORD LIMITED ,  JONES, Steven, Leslie ,  CROUCHMAN, James, Clive ,  NOXON, Raymond, Geoffrey

Inventor： ILFORD LIMITED

IPC: G03C07/30

CPC classification number: G03C7/30 ,  G03C1/035 ,  G03C7/30541 ,  G03C2001/03517 ,  G03C2200/16

Abstract: There is described a method of preparing black and white photographic print material which comprises imagewise exposing photographic black and white print material which comprises on an opaque base at least one silver halide emulsion layer of which the halide is at least 90 % silver chloride and which layer comprises a bleach-inhibitor releasing compound, processing the exposed material by means of a colour development step using a colour photographic developing agent and then through either a bleaching step followed by a fixing step or through a bleach/fix step to yield a fixed silver image in the black and white print material.

Abstract translation: 描述了一种制备黑白照相印刷材料的方法，该方法包括成像曝光照相黑白印刷材料，其包含在不透明基底上，至少一个卤化银乳剂层，其卤化物为至少90％氯化银，并且该层 包括漂白抑制剂释放化合物，通过使用彩色照相显影剂的显色步骤，然后通过漂白步骤，然后进行定影步骤或通过漂白/固定步骤处理曝光的材料，得到固定的银图像 在黑白打印材料中。

公开(公告)号：WO01096945A3

公开(公告)日：2002-06-06

申请号：PCT/US2001/016919

申请日：2001-05-24

IPC: G03C7/46 ,  G03C1/42 ,  G03C1/498 ,  G03C5/08 ,  G03C7/30 ,  G03C7/305 ,  G03C7/392 ,  G03C7/407 ,  G03C8/06 ,  G03C8/40

CPC classification number: G03C7/30541 ,  G03C1/42 ,  G03C1/498 ,  G03C1/49881 ,  G03C5/08 ,  G03C7/30 ,  G03C7/3041 ,  G03C7/407 ,  G03C8/4013 ,  G03C8/408 ,  G03C2007/3043 ,  G03C2200/21 ,  G03C2200/43

Abstract: This invention relates to a method of processing color photographic film that has been imagewise exposed in a camera, said film having at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, binder, and dye-providing coupler, which method in order comprises (a) thermally developing the film step without any externally applied developing agent, comprising heating said film to a temperature greater than 80 DEG C in an essentially dry process, such that an internally located blocked developing agent in reactive association with each of said three light-sensitive units becomes unblocked to form a developing agent, whereby the unblocked developing agent forms dyes by reacting with the dye-providing couplers to form a color image; (b) scanning the color image in the film without desilvering; (c) desilvering said film in one or more desilvering solutions to remove at least silver halide, thereby forming an improved color image suitable for scanning or optical printing, and (d) either optically printing or scanning the color image in the film following desilvering. In one embodiment of the invention, the film is scanned a first time in step (b) to obtain a relatively low quality scan and then scanned a second time after step (c) to obtain a relatively high quality scan that is used for making the positive image print.

Abstract translation: 本发明涉及一种在相机中成像曝光的彩色照相胶片的处理方法，所述胶片具有至少三个在不同波长区域具有各自敏感度的感光单元，每个单元包括至少一个发光元件， 敏感卤化银乳剂，粘合剂和染料提供成色剂，该方法依次包括：（a）不用任何外用显影剂将膜步骤热显影，包括在基本干燥的条件下将所述膜加热到大于80℃的温度 使得与所述三个感光单元中的每一个反应性结合的内部定位的阻挡显影剂变得未封闭以形成显影剂，由此未封闭的显影剂通过与提供染料的成色剂反应形成染料以形成彩色图像 ; （b）扫描胶片中的彩色图像而不脱色; （c）在一个或多个脱溶液中除去所述薄膜以除去至少卤化银，从而形成适于扫描或光学印刷的改进的彩色图像，以及（d）在脱银后光学打印或扫描薄膜中的彩色图像。 在本发明的一个实施例中，在步骤（b）中第一次扫描胶片以获得相对较低质量的扫描，然后在步骤（c）之后第二次扫描，以获得相对高质量的扫描，用于制作 正面图像打印。

公开(公告)号：WO0196947A3

公开(公告)日：2002-05-23

申请号：PCT/US0118215

申请日：2001-06-06

Applicant: EASTMAN KODAK CO

Inventor： IRVING MARK EDWARD ,  SOUTHBY DAVID THOMAS

IPC: G03C7/46 ,  G03C1/42 ,  G03C1/498 ,  G03C7/305 ,  G03C7/392 ,  G03C7/407 ,  G03C7/413 ,  G03C8/06 ,  G03C8/40

CPC classification number: G03C7/30541 ,  G03C1/42 ,  G03C1/49845 ,  G03C7/30552 ,  G03C7/407 ,  G03C7/4136 ,  G03C8/4013 ,  G03C8/408 ,  G03C2200/43 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16

Abstract: The present invention is directed to a method of processing color photographic film that has been imagewise exposed in a camera, said film having at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, binder, and dye-providing coupler, which method in order comprises: (a) thermally developing the film step without any externally applied developing agent, comprising heating said film to a temperature greater than 80 DEG C in an essentially dry process, such that an internally located blocked developing agent in reactive association with each of said three light-sensitive units becomes unblocked to form a developing agent, whereby the unblocked developing agent forms dyes by reacting with the dye-providing couplers to form a color negative image; (b) processing the developed film of step (a) by contacting it with a non-blocked developing agent, under agitation at a temperature of 30 to 50 DEG C under aqueous alkaline conditions, without forming a color negative image in the film by reaction of the non-blocked developing agent with dye-proving couplers inside the silver-halide emulsions, and (c) desilvering said film in one more desilvering solutions to remove unwanted silver and/or silver halide, thereby forming a color negative image; and (d) thereafter forming a positive-image color print from the desilvered film.

Abstract translation: 本发明涉及一种在相机中成像曝光的彩色照相胶片的处理方法，所述胶片具有至少三个在不同波长区域具有各自敏感度的光敏单元，每个单元包括至少一个 感光卤化银乳剂，粘合剂和染料提供成色剂，该方法依次包括：（a）不用任何外用显影剂将膜步骤热显影，包括将所述膜加热至大于80℃的温度 使得与所述三个感光单元中的每一个反应性相关联的内部定位的阻挡显影剂变得未封闭以形成显影剂，由此未封闭的显影剂通过与提供染料的成色剂反应形成染料以形成 彩色负像 （b）在水性碱性条件下，在30〜50℃的温度搅拌下，通过与未封闭的显影剂接触来处理显影的步骤（a）的膜，而不通过反应在膜中形成彩色负像 的非阻挡显影剂，其中染料验证成色剂在卤化银乳剂内，和（c）将一种更多的脱银溶液除去所述膜以除去不需要的银和/或卤化银，从而形成彩色负像; 和（d）之后从脱膜膜形成正像彩色印刷品。