摘要:
A catalyst for converting C9+ aromatics to lighter aromatics includes a metallic function derived from a metal such as platinum constrained within cages and/or channels of a microporous material, such as chabazite, wherein the cages and/or channels of the microporous material are defined by 8 tetrahedral atoms or fewer; and an acidic function derived from an additional zeolite having cages and/or channels defined by 10 or more tetrahedral atoms, wherein the microporous material providing the metallic function and additional zeolite providing the acidic function are coupled by a binder.
摘要:
A modified UZM-14 zeolite is described. The modified UZM-14 zeolite has a Modification Factor of 6 or more. The modified UZM-14 zeolite may have one or more of: a Si/Al 2 ratio of 14 to 30; a total pore volume in a range of 0.5 to 1.0 cc/g; at least 5% of a total pore volume being mesopores having a diameter of 10 nm of less; a cumulative pore volume of micropores and mesopores having a diameter of 100 Å or less of 0.25 cc/g or more; or a Collidine IR Bronsted acid site distribution greater than or equal to an area of 3/mg for a peak in a range of 1575 to 1700 cm -1 after desorption at 150C. Processes of making the modified UZM-14 zeolite and transalkylation processes using the modified UZM-14 zeolite are also described.
摘要:
The present invention relates to a catalyst comprising a carrier substrate of the length L extending between substrate ends a and b and two washcoat zones A and B, wherein washcoat zone A comprises a zeolite having a smallest lower channel width of at least 0.4 nm and extends starting from substrate end a over a part of the length L, and washcoat zone B comprises the same components as washcoat A and palladium and extends from substrate end b over a part of the length L, wherein L = L A + L B , wherein L A is the length of washcoat zone A and L B is the length of substrate length B.
摘要:
A method of forming composite zeolite catalyst particles includes combining a silicon source, an aqueous organic structure directing agent having a polyquaternary ammonium compound, water and an aluminum source to form a catalyst gel. The method also includes heating the catalyst gel to form the composite zeolite catalyst particle having an intergrowth region with a mixture of both Mordenite crystals and ZSM-5 crystals. An associated method of making xylene includes feeding heavy reformate to a reactor, the reactor containing the composite zeolite catalyst particles, and producing xylene by simultaneously performing dealkylation and transalkylation of the heavy reformate in the reactor, where each composite zeolite catalyst particle is able to catalyze both the dealkylation and transalkylation reactions.
摘要:
A selective catalytic reduction catalyst composition for converting oxides of nitrogen (NOx) in an exhaust gas using a nitrogenous reductant comprises a mixture of a first component and a second component, wherein the first component is an admixture of the H-form of an aluminosilicate mordenite zeolite (MOR) and an iron-promoted aluminosilicate MFI zeolite; and the second component is a vanadium oxide supported on a metal oxide support, which is titania, silica-stabilized titania or amixture of both titania and silica-stabilized titania, wherein the weight ratio of the first component to the second component is 10:90 to 25:75.
摘要:
A process for oxidizing methyl-substituted biphenyl compounds comprises contacting a mixture comprising isomers of at least one methyl-substituted biphenyl compound with a source of oxygen, wherein the mixture comprises at least 20 wt% of isomer(s) having a methyl group at a 2-position or a 3-position on at least one benzene ring and at least 50 wt% of isomer(s) having a methyl group at a 4-position on at least one benzene ring, wherein said percentages are based on the total weight of the at least one methylbiphenyl compound in the mixture.
摘要:
A process for oxidizing methyl-substituted biphenyl compounds comprises contacting a mixture comprising isomers of at least one methyl-substituted biphenyl compound with a source of oxygen, wherein the mixture comprises at least 20 wt% of isomer(s) having a methyl group at a 2-position or a 3-position on at least one benzene ring and at least 50 wt% of isomer(s) having a methyl group at a 4-position on at least one benzene ring, wherein said percentages are based on the total weight of the at least one methylbiphenyl compound in the mixture.
摘要:
La présente invention concerne notamment un procédé de fabrication d'un catalyseur destiné à être intégré dans un système de pot catalytique utile pour le traitement d'un gaz d'échappement d'un moteur d'un véhicule, ledit procédé comprenant au moins l'étape suivante : traitement par une phase gazeuse d'une structure comprenant au moins une zéolithe, du palladium et du cérium afin d'obtenir le catalyseur, la phase gazeuse comprenant de la vapeur d'eau en une teneur volumique comprise entre 5% et 20% et une température comprise entre 450°C et 550°C étant imposée durant ledit traitement.
摘要:
A process for treating a zeolite catalyst for the carbonylation of dimethyl ether to produce methyl acetate in which the catalyst is contacted with a treatment gas comprising water vapour in an amount of at least 1 mol% and at a temperature below which dealumination of the zeolite structure occurs.
摘要:
A process for the preparation of methyl acetate and/or acetic acid by carbonylating dimethyl ether and/or methanol with carbon monoxide in the presence of a catalyst, which catalyst is a H-mordenite bound with a mesoporous binder selected from silicas, aluminas, silica-aluminas, magnesium silicates and magnesium aluminum silicates.