METHOD FOR PRODUCING ALKALI SULFONYL IMIDE SALTS

    公开(公告)号:WO2022248215A1

    公开(公告)日:2022-12-01

    申请号:PCT/EP2022/062660

    申请日:2022-05-10

    Inventor: SCHMITT, Etienne

    Abstract: The present disclosure relates to a new method for producing alkali salt of bis(fluorosulfonyl)imide of high purity, as industrial scale, and with a reasonable cost when compared to the other available methods. Said method comprises the steps of reacting a bis(chlorosulfonyl)imide or a salt thereof with an onium chloride to produce an onium salt of bis(chlorosulfonyl)imide; reacting an onium salt of bis(chlorosulfonyl)imide with anhydrous hydrogen fluoride in at least one organic solvent to produce onium salt of bis(fluorosulfonyl)imide; and reacting the onium salt of bis(fluorosulfonyl)imide with an alkali salt to obtain alkali salt of bis(fluorosulfonyl)imide.

    COMBINATIONS OF HYDROGEN STORAGE MATERIALS INCLUDING AMIDE/IMIDE
    2.
    发明申请
    COMBINATIONS OF HYDROGEN STORAGE MATERIALS INCLUDING AMIDE/IMIDE 审中-公开
    氢化物储存材料的组合,包括酰胺/

    公开(公告)号:WO2005023706A3

    公开(公告)日:2005-06-30

    申请号:PCT/US2004020405

    申请日:2004-06-24

    Abstract: The invention provides a method of reversibly producing a source of hydrogen gas comprising mixing together a plurality of hydrogen-­containing starting materials; and then heating the mixed materials at a temperature sufficient to release hydrogen. Upon release of hydrogen, there is formed a residue which comprises at least one material different from the starting materials. There is also synergy whereby it is possible to regenerate at least one of the hydrogen-containing starting materials by exposing hydrogen gas to the aforesaid residue.

    Abstract translation: 本发明提供了可逆地生产氢气源的方法,包括将多个含氢原料混合在一起; 然后在足以释放氢气的温度下加热混合物。 在释放氢时,形成残渣,该残渣包含至少一种不同于原料的材料。 还有协同作用,通过将氢气暴露于上述残留物中,可以再生含氢原料中的至少一种。

    METHOD FOR FLUORINATING A COMPOUND COMPRISING A HALOSULPHONYL OR DIHALOPHOSPHONYL GROUP
    8.
    发明申请
    METHOD FOR FLUORINATING A COMPOUND COMPRISING A HALOSULPHONYL OR DIHALOPHOSPHONYL GROUP 审中-公开
    用于氟化含有羟基磷酰基或二羟基磷酰基的化合物的方法

    公开(公告)号:WO02053494A1

    公开(公告)日:2002-07-11

    申请号:PCT/FR2001/004164

    申请日:2001-12-21

    Abstract: The invention concerns a fluorination method for obtaining fluorinated compounds. The method consists in reacting with an ionic fluoride of a monovalent cation a compound of formula (I), wherein: M represents H, an alkaline metal, a quaternary phosphonium group or a quaternary ammonium group; Y represents SO2, and m is 1, or Y is PO and m is 2; Z represents CR , N or P; R represents a carbonaceous and/or electron-attracting group which has a Hammet parameter sigma P higher than 0.4; R represents a carbonaceous and/or electron-attracting group; X represents a halogen other than a fluorine. The fluorinated compounds obtained are useful in particular as electrolyte in lithium batteries.

    Abstract translation: 本发明涉及获得含氟化合物的氟化方法。 该方法包括与式(I)化合物的一价阳离子的离子氟化物反应,其中:M表示H,碱金属,季鏻基或季铵基; Y表示SO 2,m表示1,Y表示PO,m表示2。 Z表示CR 2,N或P; R 1表示具有高于0.4的Hammet参数σP的碳质和/或吸电子基团; R 2表示含碳和/或吸电子基团; X表示氟以外的卤素。 获得的氟化化合物尤其可用作锂电池中的电解质。

    METHOD FOR PRODUCING ALKALI SULFONYL IMIDE SALTS

    公开(公告)号:WO2020099527A1

    公开(公告)日:2020-05-22

    申请号:PCT/EP2019/081252

    申请日:2019-11-14

    Applicant: SOLVAY SA

    Abstract: The invention relates to a new method for producing alkali salt of bis(fluorosulfonyl)imide of high purity, as industrial scale, and with a reasonable cost when compared to the other available methods. Said method comprises the steps of reacting bis(chlorosulfonyl)imide or salts thereof with ammonium fluoride to produce ammonium salt of bis(fluorosulfonyl)imide; crystallizing and separating the ammonium salt of bis(fluorosulfonyl)imide; and reacting the crystallized ammonium salt of bis(fluorosulfonyl)imide with an alkali salt to obtain alkali salt of bis(fluorosulfonyl)imide.

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