Abstract:
The present disclosure relates to a new method for producing alkali salt of bis(fluorosulfonyl)imide of high purity, as industrial scale, and with a reasonable cost when compared to the other available methods. Said method comprises the steps of reacting a bis(chlorosulfonyl)imide or a salt thereof with an onium chloride to produce an onium salt of bis(chlorosulfonyl)imide; reacting an onium salt of bis(chlorosulfonyl)imide with anhydrous hydrogen fluoride in at least one organic solvent to produce onium salt of bis(fluorosulfonyl)imide; and reacting the onium salt of bis(fluorosulfonyl)imide with an alkali salt to obtain alkali salt of bis(fluorosulfonyl)imide.
Abstract:
The invention provides a method of reversibly producing a source of hydrogen gas comprising mixing together a plurality of hydrogen-containing starting materials; and then heating the mixed materials at a temperature sufficient to release hydrogen. Upon release of hydrogen, there is formed a residue which comprises at least one material different from the starting materials. There is also synergy whereby it is possible to regenerate at least one of the hydrogen-containing starting materials by exposing hydrogen gas to the aforesaid residue.
Abstract:
Electrolytes and electrolyte additives for energy storage devices comprising metal amide bases are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode and an electrolyte composition comprising at least one electrolyte additive comprising a metal amide base compound.
Abstract:
The invention relates to a method for producing an alkali salt of bis(fluorosulfonyl)imide, comprising the step of reacting, within a reaction medium, an ammonium salt of bis(fluorosulfonyl)imide with an alkali agent, to produce alkali salt of bis(fluorosulfonyl)imide and ammonia; and simultaneously contacting the reaction medium with an inert gas stream to strip out ammonia.
Abstract:
La présente invention concerne un procédé de préparation d'un composé de formule (II) suivante : (II) dans laquelle R 1 représente F ou un radical alkyle, linéaire ou ramifié, substitué par au moins un atome de fluor, ledit procédé comprenant une étape de mise en contact d'un flux anhydre F1 comprenant de l'ammoniac (NH 3 ) avec un composé de formule (I) : (I) R 1 étant tel que défini ci-dessus.
Abstract:
In one aspect, the invention provides a novel quaternary hydrogen storage composition having a hydrogenated state and a dehydrogenated state. Further, the present invention provides methods of storing hydrogen in a hydrogen storage composition, and methods of releasing hydrogen by reaction a nitride composition and hydride composition.
Abstract:
The invention concerns a fluorination method for obtaining fluorinated compounds. The method consists in reacting with an ionic fluoride of a monovalent cation a compound of formula (I), wherein: M represents H, an alkaline metal, a quaternary phosphonium group or a quaternary ammonium group; Y represents SO2, and m is 1, or Y is PO and m is 2; Z represents CR , N or P; R represents a carbonaceous and/or electron-attracting group which has a Hammet parameter sigma P higher than 0.4; R represents a carbonaceous and/or electron-attracting group; X represents a halogen other than a fluorine. The fluorinated compounds obtained are useful in particular as electrolyte in lithium batteries.
Abstract translation:本发明涉及获得含氟化合物的氟化方法。 该方法包括与式(I)化合物的一价阳离子的离子氟化物反应,其中:M表示H,碱金属,季鏻基或季铵基; Y表示SO 2,m表示1,Y表示PO,m表示2。 Z表示CR 2,N或P; R 1表示具有高于0.4的Hammet参数σP的碳质和/或吸电子基团; R 2表示含碳和/或吸电子基团; X表示氟以外的卤素。 获得的氟化化合物尤其可用作锂电池中的电解质。
Abstract:
The present disclosure relates to a method for preparing salts of bis(fluorosulfonyl)imide and to a method for preparing alkali metal salts of bis(fluorosulfonyl)imide from said bis(fluorosulfonyl)imide salts. More specifically, the invention provides a new method for producing these salts of bis(fluorosulfonyl)imide which is implementable at industrial scale and providing high-purity bis(fluorosulfonyl)imide salts.
Abstract:
The invention relates to a new method for producing alkali salt of bis(fluorosulfonyl)imide of high purity, as industrial scale, and with a reasonable cost when compared to the other available methods. Said method comprises the steps of reacting bis(chlorosulfonyl)imide or salts thereof with ammonium fluoride to produce ammonium salt of bis(fluorosulfonyl)imide; crystallizing and separating the ammonium salt of bis(fluorosulfonyl)imide; and reacting the crystallized ammonium salt of bis(fluorosulfonyl)imide with an alkali salt to obtain alkali salt of bis(fluorosulfonyl)imide.