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    BIOGAS CONVERSION TO MIXED ALCOHOLS
    1.
    发明申请
    BIOGAS CONVERSION TO MIXED ALCOHOLS 审中-公开

    公开(公告)号：WO2022159408A1

    公开(公告)日：2022-07-28

    申请号：PCT/US2022/012843

    申请日：2022-01-19

    申请人： STANDARD ALCOHOL COMPANY OF AMERICA, INC.

    发明人： RIDLEY JR., Richard ,  PARDUN, Michael

    IPC分类号： C07C29/151 ,  C01B3/22 ,  C07C27/00 ,  C10K3/00 ,  C10L3/06 ,  C10L3/08 ,  C10L3/10

    摘要： Some variations provide a process for producing mixed alcohols, comprising: purifying a biogas feedstock to generate a renewable natural gas stream comprising methane; introducing the renewable natural gas stream into a methane-to-syngas unit operated at effective conditions to convert the methane to a first syngas stream containing at least H2, CO, and CO2; purifying the first syngas stream, including separating the CO2 from the first syngas stream, and optionally separating some of the H2 from the first syngas stream, thereby generating a clean syngas stream; introducing the clean syngas stream into a mixed-alcohol reactor operated at effective alcohol synthesis conditions with an alcohol-synthesis catalyst, thereby generating mixed alcohols; and purifying the mixed alcohols to generate a mixed-alcohol product. The mixed-alcohol product may be blended with a hydrocarbon fuel, such as gasoline, to produce a blended fuel. The blended fuel has significantly lower carbon intensity than the base hydrocarbon fuel.

    METHOD AND SYSTEM FOR EXTRACTING METHANE GAS, CONVERTING THE GAS TO CLATHRATES, AND TRANSPORTING THE GAS FOR USE
    2.
    发明申请
    METHOD AND SYSTEM FOR EXTRACTING METHANE GAS, CONVERTING THE GAS TO CLATHRATES, AND TRANSPORTING THE GAS FOR USE 审中-公开

    公开(公告)号：WO2021216413A1

    公开(公告)日：2021-10-28

    申请号：PCT/US2021/027902

    申请日：2021-04-19

    申请人： KEZIRIAN, Michael

    发明人： KEZIRIAN, Michael

    IPC分类号： C07C27/00 ,  B01J12/00

    摘要： Methods and systems for extracting natural gas are described herein. The source of the natural gas may be a reservoir of natural gas or natural gas and crude oil found on land or in a subterranean or subsea environment. The natural gas also may be that extracted from a subsea reservoir of naturally formed clathrate hydrate. The methods may be performed on land, at the sea surface or at the seafloor. The methods feature providing a suitable promoter to facilitate selective formation of a structure II (sII) methane clathrate hydrate to thereby store natural gas in a readily transportable form. The methods may also feature separating both natural gas and associated water involved in producing it from impurities.

    POLYMER COMPOSITION FOR FILMS HAVING IMPROVED MECHANICAL PROPERTIES AND DEGRADABILITY
    3.
    发明申请
    POLYMER COMPOSITION FOR FILMS HAVING IMPROVED MECHANICAL PROPERTIES AND DEGRADABILITY 审中-公开

    公开(公告)号：WO2021130106A1

    公开(公告)日：2021-07-01

    申请号：PCT/EP2020/086872

    申请日：2020-12-17

    申请人： NOVAMONT S.P.A.

    发明人： BASTIOLI, Catia ,  GESTI GARCIA, Sebastià ,  SALICE, Patrizio

    IPC分类号： B01D3/00 ,  B01D3/14 ,  C07C27/00 ,  C08G63/06 ,  C08G63/16 ,  C08G63/181 ,  C08J5/18 ,  C08L67/00 ,  C08L67/02 ,  C08L67/04 ,  C08J2300/16 ,  C08J2367/02 ,  C08J2403/02 ,  C08J2467/04

    摘要： Polymeric composition comprising, with respect to the total composition: i) 30-95% by weight, preferably between 50-85% by weight with respect to the sum of components i) -vi), of at least one polyester comprising: a) a dicarboxylic component comprising, with respect to the total of the dicarboxylic component: a1) 30-70% by moles of units deriving from at least one aromatic dicarboxylic acid; a2) 70-30% by moles of units deriving from at least one saturated aliphatic dicarboxylic acid; a3) 0-5% by moles of units deriving from at least one unsaturated aliphatic dicarboxylic acid; b) a diol component comprising, with respect to the total diol component: b1) 95-100% by moles of units deriving from at least one saturated aliphatic diol; b2) 0-5% by moles of units deriving from at least one unsaturated aliphatic diol; ii) 0.1-50% by weight with respect to the sum of components i) -vi), of at least one polymer of natural origin; iii) 0.1-10% by weight with respect to the sum of components i) -vi) of at least one polyhydroxy alkanoate different from a lactic acid polyester referred to in point iv); iv) 0-3% by weight with respect to the sum of components i) - vi) of at least one lactic acid polyester; v) 0-1% by weight, preferably 0-0.5% by weight, with respect to the sum of the components i) -vi) of at least one cross-linking agent and / or a chain extender and / or hydrolytic stabilizer comprising at least one compound di- and / or polyfunctional containing isocyanate, peroxide, carbodiimide, isocyanurate, oxazoline, epoxide, anhydride, diviniether groups and mixtures of these; vi) 0 - 15% by weight, with respect to the sum of components i) -vi), of at least one inorganic filling agent.

    PROCESS FOR THE PRODUCTION OF 1,4-BUTANEDIOL FROM RENEWABLE SOURCES AND POLYESTERS OBTAINED THEREFROM
    6.
    发明申请
    PROCESS FOR THE PRODUCTION OF 1,4-BUTANEDIOL FROM RENEWABLE SOURCES AND POLYESTERS OBTAINED THEREFROM 审中-公开

    公开(公告)号：WO2019102030A1

    公开(公告)日：2019-05-31

    申请号：PCT/EP2018/082668

    申请日：2018-11-27

    申请人： NOVAMONT S.P.A.

    发明人： COTTI COMETTINI, Marco ,  VALLERO, Roberto ,  BASTIOLI, Catia ,  CAPUZZI, Luigi

    IPC分类号： B01D3/14 ,  B01D3/00 ,  C07C27/00

    摘要： The invention relates to a process for the production of 1,4-butanediol comprising the preparation of a fermentation broth comprising 1,4- butanediol from renewable sources and water, separation of a liquid fraction comprising said 1,4-butanediol and water from one or more solid fractions, said liquid fraction comprising 2-pyrrolidone in an amount higher than 80 ppm, one or more passages of the resulting liquid fraction through a bed comprising one or more cation-exchange resins thereby providing an output pH of said liquid fraction from 4 to 2, one or more passages of the resulting liquid fraction through a bed comprising one or more anion-exchange resins thereby providing an output pH of said liquid fraction from 8 to 11, and the distillation of the liquid fraction thereby provided so as to obtain a composition having a concentration of said 1,4-butanediol higher than 99.0% by weight and comprising 2-pyrrolidone in an amount lower than 6 ppm. The resulting composition should exhibit an APHA color value after ageing of less than 30.

    ケトン及び／又はアルコールの製造方法及びそのシステム
    7.
    发明申请
    ケトン及び／又はアルコールの製造方法及びそのシステム 审中-公开
    酮和/或醇的制造方法和系统的

    公开(公告)号：WO2017099072A1

    公开(公告)日：2017-06-15

    申请号：PCT/JP2016/086217

    申请日：2016-12-06

    申请人： 宇部興産株式会社

    发明人： 杉村　欣則 ,  黒澤　和徳 ,  倭　和夫 ,  釘本　純一 ,  河井　譲治 ,  シリスクスコン　ワンナ　 ,  ナムサップ　ナンタリヤ　

    IPC分类号： C07C27/00 ,  C07C29/00 ,  C07C35/08 ,  C07C45/53 ,  C07C49/403

    CPC分类号： C07C27/00 ,  C07C29/00 ,  C07C35/08 ,  C07C45/53 ,  C07C49/403

    摘要： ハイドロパーオキサイドをアルカリ水溶液を用いて速やかに且つ高選択率で分解するとともに、アルカリを回収及びリサイクルすることによって、対応する目的のケトン及び／又はアルコールを安価に製造する方法及びそのシステムを提供する。　本製造方法は、酸化反応液とアルカリ金属の炭酸塩を含んだ第１アルカリ液とを接触させることにより、前記酸化反応液中のカルボン酸の少なくとも一部を中和し、反応系を第１の油相と第１の水相とに分離する中和工程と、前記第１の油相と前記第１アルカリ液よりｐＨが高い第２アルカリ液とを接触させることにより、前記第１の油相中のハイドロパーオキサイド及びエステル化合物を分解させ、反応系を第２の油相と第２の水相とに分離するケン化工程と、前記第１の水相からアルカリ金属の炭酸塩を回収して前記第１アルカリ液にリサイクルするアルカリ回収工程とを含んでいる。

    摘要翻译： 被

    氢过氧化物如通过使用碱性水溶液，通过回收和再利用碱，低成本生产相应的对象的酮和/或醇的迅速且以高选择性分解 提供一种方法和系统。 该制造方法，通过使含有氧化反应的液体和碱金属碳酸盐的第一碱性溶液中，所述第一中和至少所述羧酸在氧化反应中，反应系统的一部分 中和的步骤，通过将pH接触比第一油相和第一种碱溶液更高的第二碱溶液，所述第一种油的油相并将其分离成第一水相 以分解氢过氧化物和在相位的酯化合物，使反应体系分离成第二油相和第二水相，从所述第一水相回收碱金属碳酸盐的皂化步骤 和碱回收步骤循环至第一碱性溶液。

    VERFAHREN ZUR HERSTELLUNG VON DIALKYLCARBONATEN
    9.
    发明申请
    VERFAHREN ZUR HERSTELLUNG VON DIALKYLCARBONATEN 审中-公开
    制备二烷基碳酸酯的方法

    公开(公告)号：WO2014079835A1

    公开(公告)日：2014-05-30

    申请号：PCT/EP2013/074150

    申请日：2013-11-19

    申请人： BAYER MATERIALSCIENCE AG

    发明人： OOMS, Pieter ,  RISSE, Friedhelm ,  DÜX, Andre ,  BUCHALY, Carsten ,  PANCUR, Thomas ,  SUSANTO, Arthur ,  RONGE, Georg ,  VANDE EYNDE, Johan ,  WUYTACK, Wim

    IPC分类号： C07C27/00 ,  C07C68/06 ,  C07C69/96 ,  C07C29/128 ,  C07C31/20

    CPC分类号： C07C68/065 ,  C07C29/128 ,  C07C29/1285 ,  C07C69/96 ,  C07C31/202

    摘要： Die vorliegende Erfindung betrifft ein kontinuierliches Verfahren zur Herstellung von niederen Dialkylcarbonaten als Hauptprodukt und Alkylenglykol als Nebenprodukt durch Umesterung eines zyklischen Alkylencarbonats (z.B. Ethylen- oder Propylencarbonat) mit niederen Alkylalkoholen in Gegenwart eines Katalysators sowie die erforderliche Aufreinigung des Dialkylcarbonats in einem nachfolgenden Verfahrensschritt. Zur Optimierung der Wirtschaftlichkeit und Energieeffizienz des Verfahrens werden zusätzliche Vorrichtungen zur Zwischenerhitzung der apparateintemen Flüssigkeitströme eingesetzt.

    摘要翻译：

    本发明涉及一种用低级烷基醇制备下碳酸二烷基酯作为主要产物和亚烷基二醇作为由环状碳酸亚烷基酯的酯基转移反应的副产物（如乙烯或碳酸亚丙酯）在催化剂的存在和的必要纯化的连续方法 在随后的工艺步骤中使用碳酸二烷基酯。 为了优化工艺的经济性和能量效率，使用附加装置来对设备内部液体流进行中间加热。