CRYSTALLINE MODIFICATION OF A WATER-INSOLUBLE MONOAZO DYE
    1.
    发明申请
    CRYSTALLINE MODIFICATION OF A WATER-INSOLUBLE MONOAZO DYE 审中-公开
    水不溶性单氧基染料的晶体修饰

    公开(公告)号:WO00040795A1

    公开(公告)日:2000-07-13

    申请号:PCT/EP2000/000046

    申请日:2000-01-05

    CPC classification number: C09B67/0015 C09B67/0029 Y10S8/922

    Abstract: A water-insoluble monoazo dye represented by structural formula (II) having a crystal modification characterized by an X-ray diffraction pattern (CuK alpha ) showing one strong peak at a diffraction angle (2 theta ) of about 11.1 DEG and also four intermediate peaks at about 8.1 DEG , about 21.8 DEG , about 23.1 DEG and about 25.2 DEG .

    Abstract translation: 由结构式(II)表示的水不溶性单偶氮染料具有结晶改性,其特征在于X射线衍射图(CuKα)在约11.1°的衍射角(2θ)处显示一个强峰,还有四个中间峰 约8.1°,约21.8°,约23.1°和约25.2°。

    MONOAZOQUINOLONE PIGMENTS, PROCESS FOR THEIR PREPARATION AND THEIR USE
    2.
    发明申请
    MONOAZOQUINOLONE PIGMENTS, PROCESS FOR THEIR PREPARATION AND THEIR USE 审中-公开
    MONOAZOQUINOLONE颜料,其制备方法及其使用

    公开(公告)号:WO2004085540A1

    公开(公告)日:2004-10-07

    申请号:PCT/EP2004/050308

    申请日:2004-03-15

    CPC classification number: C08K5/0041 C08K5/3437 C09B29/0048 C09B29/337

    Abstract: Monoazoquinolone pigments which, in one of their tautomeric forms, correspond to formula (1), wherein W is unsubstituted or substituted C 6 -C 24 aryl or unsubstituted or substituted heteroaryl or is a radical of formula (1a), wherein Ar 2 is unsubstituted or substituted C 6 -C 24 aryl or unsubstituted or substituted heteroaryl, Ar 1 is unsubstituted or substituted C 6 -C 24 aryl or unsubstituted or substituted heteroaryl, R, R 1 and R 2 are each independently of the others hydrogen, C 1 -C 6 alkyl, halogen, cyano, CF 3 , nitro, NR 3 R 4 , COOR 4 , NR 4 COR 3 , COO - X + , COR 4 , OR 4 , SR 3 , S0 2 R 3 , SO 2 NR 3 R 4 , SO 3 - X + , or C 6 -C 24 aryl which is unsubstituted or mono- or poly­substituted by R 5 , R 3 is C 1 -C 6 alkyl, or C 6 -C 12 aryl which is unsubstituted or mono- or poly-substituted by halogen, hydroxy, OR 7 , cyano, nitro, SR 7 , NR 6 R 7 , COOR 7 , CONR 6 R 7 , NR 6 COR 7 , NR 6 COOR 7 , COO - X + , COR 4 , OR 4 , SO 2 R 7 , SO 2 NR 6 R 7 , SO 3 - X + or by S0 3 R 7 , R 4 is hydrogen or has the meanings of R 3 , R 5 is hydrogen, C 1 -C 4 alkyl, halogen, nitro, NR 7 R 8 or OR 7 , R 6 is hydrogen or C 1 -C 3 alkyl, R 7 and R 8 are each independently of the other hydrogen; C 1 -C 3 alkyl; phenyl which is unsubstituted or mono- or poly-substituted by halogen, nitro, OR 5 , NR 16 R 17 ; or benzyl which is unsubstituted or mono- or poly-substituted by halogen, nitro, OR 5 , NR 16 R 17 , and X + is a cation H + , Li + , Na + , K + , Mg ++ 1/2 , Ca ++ 1/2 , Sr ++ 1/2 , Ba ++1/2 , Cu + , Cu ++ 1/2 , Zn ++ 1/2 , Mn ++ 1/2 , Al +++ 1/3 or [NR 9 R 10 R 11 R 12 ] + , wherein R 9 , R 10 , R 11 and R 12 are each independently of the others hydrogen; C 1 -C 6 alkyl; phenyl which is unsubstituted or mono- or poly-substituted by C 1 -C 6 alkyl, halogen, nitro, OR 5 , NR 16 R 17 ; or benzyl which is unsubstituted or mono- or poly-substituted by C 1 -C 6 alkyl, halogen, nitro, OR 5 , NR 16 R 17 , and R 16 and R 17 are each independently of the other hydrogen or C 1 -C 6 alkyl, are suitable for the colouring of high molecular weight material and are distinguished by good fastness properties of the resulting colourations.

    Abstract translation: 以其互变异构形式之一对应于式(1)的单唑喹诺酮颜料,其中W是未取代或取代的C 6 -C 24芳基或未取代或取代的杂芳基或者是式(1a)的基团,其中Ar 2是未取代的或取代的C6- C24芳基或未取代或取代的杂芳基,Ar1是未取代或取代的C6-C24芳基或未取代或取代的杂芳基,R,R1和R2各自独立地为氢,C1-C6烷基,卤素,氰基,CF3,硝基,NR3R4,COOR4, NR4COR3,COO,X +,COR4,OR4,SR3,SO2R3,SO2NR3R4,SO3 X6或未被R5单取代或多取代的C6-C24芳基,R3是C1-C6烷基 或未被取代或被卤素,羟基,OR7,氰基,硝基,SR7,NR6R7,COOR7,CONR6R7,NR6COR7,NR6COOR7,COO - ,X +,COR4,OR4,SO2R7, SO 2 NR 6 R 7,SO 3 X X或SO 3 R 7,R 4是氢或具有R 3,R 5是氢,C 1 -C 4烷基,卤素,硝基,NR 7 R 8或OR 7的含义, R6是氢或C1-C3烷基,R7和R8各自独立地是氢; C1-C3烷基; 未被取代或被卤素,硝基,OR5,NR16R17单取代或多取代的苯基; 或未取代的或被卤素,硝基,OR 5,NR 16 R 17和X +单取代或多取代的苄基是阳离子H +,Li +,Na +,K +,Mg <++> 1/2,Ca ++,1/2,Ba +++,Cu ++,Cu ++,Zn, 其中R 9,R 10,R 11和R 12各自独立地为氢;其中R 1,R 2,R 3, C1-C6烷基; 未被取代或被C1-C6烷基,卤素,硝基,OR5,NR16R17单取代或多取代的苯基; 或未取代的或被C 1 -C 6烷基,卤素,硝基,OR 5,NR 16 R 17和R 16和R 17单独或多取代的苄基各自独立于另一个氢或C 1 -C 6烷基,适用于高分子量着色 并且由所得着色的良好的牢度特性区分。

    WATER-INSOLUBLE AZO DYES, THEIR MANUFACTURE AND USE
    3.
    发明申请
    WATER-INSOLUBLE AZO DYES, THEIR MANUFACTURE AND USE 审中-公开
    水不溶性AZO染料,其制造和使用

    公开(公告)号:WO1991013941A1

    公开(公告)日:1991-09-19

    申请号:PCT/EP1991000384

    申请日:1991-03-01

    Abstract: Water-insoluble azo colorants, their preparation and use The invention relates to monoazo and disazo compounds of the formula (I) (I) in which D is the radical of a carbocyclic or heterocyclic diazo or bisdiazo component, R1 and R2, independently of one another, are each a substituted or unsubstituted aryl or heteroaryl radical, X1 and X2, independently of one another, are each ring-forming ether oxygen or a substituted or unsubstituted imide grouping and n has the value 0 or 1, in which rings A and B, independently of one another, can each be additionally substituted and/or carry substituted or unsubstituted fused rings. These new compounds of the formula (I) are obtained by coupling diazotized amines or diamines of the type D-NH2 or H2N-D-NH2 with (benzoxazol-2-yl)- or (benzimidazol-2-yl)-arylacetamides. Depending on the presence and length of alkyl chains, the compounds of the formula (I) are suitable for use as pigments, disperse dyes or oil-soluble dyes.

    CO-PROCESSED YELLOW PIGMENTS
    5.
    发明申请
    CO-PROCESSED YELLOW PIGMENTS 审中-公开
    共处理黄色素

    公开(公告)号:WO02055610A1

    公开(公告)日:2002-07-18

    申请号:PCT/US2001/042300

    申请日:2001-09-25

    CPC classification number: C09D11/037 C09B67/0033 C09D7/41

    Abstract: One aspect of the invention relates to a yellow pigment composition containing at least one yellow nickel titanate and at least one yellow organic pigment containing a benzimidazolone moiety. Another aspect of the invention relates to a method of making a yellow pigment composition involving the steps of combining at least one yellow nickel titanate and at least one yellow benzimidazolone pigment to form a mixture; and mixing the mixture to form a homogenous mixture of the yellow pigment composition.

    Abstract translation: 本发明的一个方面涉及含有至少一种黄色钛酸镍和至少一种含有苯并咪唑酮部分的黄色有机颜料的黄色颜料组合物。 本发明的另一方面涉及一种制备黄色颜料组合物的方法,其包括将至少一种黄色钛酸镍和至少一种黄色苯并咪唑酮颜料混合以形成混合物的步骤; 并混合该混合物以形成黄色颜料组合物的均匀混合物。

    アゾ顔料、該アゾ顔料を含む顔料分散物及び着色組成物
    6.
    发明申请
    アゾ顔料、該アゾ顔料を含む顔料分散物及び着色組成物 审中-公开
    AZO颜料,含有AZO颜料的颜料分散体和着色组合物

    公开(公告)号:WO2009110553A1

    公开(公告)日:2009-09-11

    申请号:PCT/JP2009/054176

    申请日:2009-03-05

    Abstract:  着色力、色相等の色彩的特性に優れ、かつ耐光性、耐オゾン性等の耐久性にも優れるアゾ顔料、該アゾ顔料を含む顔料分散体及び着色組成物を提供する。  下記一般式(1)で表されるアゾ顔料、その互変異性体、それらの塩または水和物。  一般式(1): (一般式(1)中、G 0 、G 1 はそれぞれ独立に5~6員ヘテロ環基を構成する事ができる非金属原子団を表し、それぞれのヘテロ環基は無置換であっても、置換基を有していてもよい。また、それぞれのヘテロ環基は単環であっても縮環していてもよい。Xはヘテロ原子を表す。nは1~4の整数を表す。n=2の場合は、G 0 、G 1 で表されるヘテロ環基またはAを介した2量体を表す。n=3の場合はG 0 、G 1 で表されるヘテロ環基及び/またはAを介した3量体を表す。n=4の場合はG 0 、G 1 で表されるヘテロ環基及び/またはAを介した4量体を表す。Aは、特定の置換基の群から選ばれるいずれかを表す。)

    Abstract translation: 公开了具有优异的着色力和色调等颜色特性的偶氮颜料,同时具有耐光性和耐臭氧性优异的耐久性。 还公开了含有偶氮颜料和着色组合物的颜料分散体。 具体公开的是由通式(1)表示的偶氮颜料,其互变异构体,或颜料的盐或水合物或其互变异构体。 (通式(1)中,G 0和G 1独立地表示可以形成可以是单环或稠环的未取代或取代的五元或六元杂环基的非金属原子团; X表示 n表示1〜4的整数,A表示选自特定取代基的取代基,当n = 2时,式(1)的化合物表示通过A连接的二聚体或由G0表示的杂环基 当n = 3时,式(1)的化合物表示通过A和/或由G0或G1表示的杂环基连接的三聚体,当n = 4时,式(1)的化合物表示连接的四聚体 A和/或由G0或G1表示的杂环基)

    AROMATIC-ALIPHATIC AZO DERIVATIVES PARTICULARLY AS MARKERS FOR PETROLEUM PRODUCTS, METHOD FOR SYNTHESIZING THEM, USE THEREOF AND DERIVED COMPOSITIONS
    8.
    发明申请
    AROMATIC-ALIPHATIC AZO DERIVATIVES PARTICULARLY AS MARKERS FOR PETROLEUM PRODUCTS, METHOD FOR SYNTHESIZING THEM, USE THEREOF AND DERIVED COMPOSITIONS 审中-公开
    特别是作为石油产品标记的芳族脂族偶氮衍生物,合成它们的方法,其使用和衍生的组合物

    公开(公告)号:WO2006069664A2

    公开(公告)日:2006-07-06

    申请号:PCT/EP2005013661

    申请日:2005-12-19

    Inventor: TRAVERSO ENRICO

    Abstract: Products having the general formula A, particularly useful as non-coloring markers in a process for tagging mineral oils, petroleum derivatives in general and solvents. A method is also described for synthesizing the products by resorting to a classical diazocoupling reaction between a derivative of an aromatic amine and a coupling agent, preferably a functionalized ester. The invention also relates to the use of these tagging and dyeing molecules and mixtures which comprise them. In particular, the mixtures comprise the markers according to the invention and the markers and/or dyes classically used in the petroleum sector.

    Abstract translation: 具有通式A的产品,特别可用作标记矿物油,通常的石油衍生物和溶剂的方法中的非着色标记。 还描述了通过使用芳族胺的衍生物和偶联剂,优选官能化酯之间的典型的重氮偶联反应来合成产物的方法。 本发明还涉及这些标记和染色分子和包含它们的混合物的用途。 特别地,混合物包含根据本发明的标记物和经典地用于石油部门的标记物和/或染料。

    SORBITAN ESTER TREATED PIGMENTS FOR PLASTICS APPLICATIONS
    9.
    发明申请
    SORBITAN ESTER TREATED PIGMENTS FOR PLASTICS APPLICATIONS 审中-公开
    SORBITAN ESTER处理用于塑料应用的颜料

    公开(公告)号:WO01025335A1

    公开(公告)日:2001-04-12

    申请号:PCT/EP2000/009375

    申请日:2000-09-26

    CPC classification number: C09B67/0065 C08K5/0041 C08K5/1535 C09B67/0072

    Abstract: Composition comprising (a) from 1 to 20, preferably from 1 to 10 % by weight of a sorbitan ester of formula (I) wherein R1 and R2, independently from each other, stand for C1-C20alkyl or C2-C20alkenyl, and (b) from 99 to 80, preferably from 99 to 90 % by weight of a metal or ammonium laked monoazo pigment of formula (II) or formula (III) wherein R3, R4, R5, R6, R7 and R8 independently from each other stand for hydrogen, C1-C20alkyl, C1-C20alkoxy, C2-C20alkenyl, C1-C20alkylthiol, C1-C20alkoxycarbonyl, hydroxyC1-C4alkoxy, phenyl, benzyl, phenylthio, fluoro, chloro, bromo, iodo, -CN, -NO2, -CF3, -COR9, -COOR9, -CONR9R10, -SO2R9, -SO2NR9R10, -NR9NR10 in which each R9 and R10 are each independently from each other hydrogen, -OH, C1-4-alkyl or phenyl, where at least one of R3, R4, R5, R6, R7 and R8 is either -COOH or -SO3H, and M may be NH4 , or a cation of an alkali metal, an alkaline earth metal, such as Na, K, Mg, Ca, Sr, Ba, or a cation of a transition metal such as Mn, Co, Ni, Cu, Fe or Al, as well as a process for its preparation and its use as well as the use of the sorbitan ester I as additive to improve color strength and dispersion properties.

    Abstract translation: 组合物,其包含(a)1至20,优选1至10重量%的式(I)的脱水山梨糖醇酯,其中R 1和R 2彼此独立地代表C 1 -C 20烷基或C 2 -C 20链烯基,和(b )99至80,优选99至90重量%的式(II)或式(III)的金属或铵盐的单偶氮颜料,其中R 3,R 4,R 5,R 6,R 7和R 8彼此独立地代表 氢,C1-C20烷基,C1-C20烷氧基,C2-C20链烯基,C1-C20烷基硫醇,C1-C20烷氧基羰基,羟基C1-C4烷氧基,苯基,苄基,苯硫基,氟,氯,溴,碘,-CN,-NO2,-CF3, COR9,-COOR9,-CONR9R10,-SO2R9,-SO2NR9R10,-NR9NR10,其中每个R9和R10各自独立地为氢,-OH,C1-4烷基或苯基,其中R3,R4, R5,R6,R7和R8是-COOH或-SO3H,M可以是NH4 +,或碱金属,碱土金属如Na,K,Mg,Ca,Sr,Ba ,或Mn,Co,Ni,Cu,Fe等过渡金属的阳离子 或Al,以及其制备和使用的方法以及使用脱水山梨醇酯I作为添加剂来改善着色强度和分散性能。

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