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公开(公告)号：WO2019002686A1
公开(公告)日：2019-01-03
申请号：PCT/FI2018/050506
申请日：2018-06-27
申请人： KEMIRA OYJ
发明人： LU, Chen , RABIDEAU, Jenna
摘要： A method to enhance alkenyl succinic anhydride sizing on paper is disclosed there. Methods to make paper products with increased ink penetrations time are provided. Paper products with increased ink penetration time are also disclosed.
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公开(公告)号：WO2016106300A1
公开(公告)日：2016-06-30
申请号：PCT/US2015/067327
申请日：2015-12-22
申请人： WESTROCK MWV, LLC
发明人： MEYERS, Jeremy
摘要： Substrates for paperboard packing with improved internal sizing including the use of a combination of a dispersed rosin size (DRS) with an alkenylsuccinic anhydride size for reducing edgewicking with less use of the sizing agents.
摘要翻译： 用于具有改进的内部施胶的纸板包装的基材，包括使用分散松香尺寸（DRS）与烯基琥珀酸酐尺寸的组合，以减少使用上浆剂的吸收。
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公开(公告)号：WO2015118227A1
公开(公告)日：2015-08-13
申请号：PCT/FI2015/050075
申请日：2015-02-06
申请人： KEMIRA OYJ
摘要： The present invention relates to sizing agent formulations, especially to stabilizing a sizing formulation by a modified non-food polysaccharide. The method for preparation of the modified non-food polysaccharide is further provided.
摘要翻译： 本发明涉及上浆剂制剂，特别涉及通过改良的非食品多糖稳定上浆制剂。 还提供了制备改性非食品多糖的方法。
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公开(公告)号：WO2012090496A1
公开(公告)日：2012-07-05
申请号：PCT/JP2011/007325
申请日：2011-12-27
IPC分类号： D21H21/16 , B01F17/12 , B01F17/22 , B01F17/50 , B01F17/52 , D21H17/09 , D21H17/16 , D21H17/37
摘要： 本発明は、填料等を含有した希釈液に対する分散安定性が優れることでサイズ剤に由来する汚れを低減でき、サイズ効果の優れる水分散性サイズ剤及び紙例えば板紙の製造方法を提供することを課題とし、ナフタレンスルホン酸ホルマリン縮合物アルカリ金属塩若しくはナフタレンスルホン酸ホルマリン縮合物アンモニウム塩及び／又はリグニンスルホン酸アルカリ金属塩若しくはリグニンスルホン酸アンモニウム塩である分散剤と置換コハク酸無水物とを含む水分散性サイズ剤であり、抄紙系内のイオン性がアニオン性を示す水分散性サイズ剤であり、パルプスラリー、特にｐＨが６．５～８．５、アルカリ度が５０～４００ｐｐｍ、及び電導度が５０～２５０ｍＳ／ｍであるパルプスラリーに、前記水分散性サイズ剤を添加して抄紙を行うことを特徴とする紙特に板紙の製造方法を手段とする。
摘要翻译： 本发明的目的是提供一种水分散性上浆剂，其具有优异的施胶效果，并且由于相对于含有装载材料等的稀释剂具有优异的分散稳定性，可以通过施胶剂减少污染; 并且提供一种制造纸的方法，例如纸板。 水分散性上浆剂含有分散剂，其为萘磺酸甲醛缩合物的碱金属盐或萘磺酸福尔马林缩合物的铵盐，和/或木质素磺酸的碱金属盐或木质素磺酸的铵盐; 和取代的琥珀酸酐。 水分散性上浆剂的离子性在造纸系统中显示出阴离子性。 特别是纸和纸板的制造方法的特征在于，通过将水分散性上浆剂添加到纸浆中，特别是pH为6.5〜8.5，碱度为50〜 400ppm，电导率为50-250mS / m。
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公开(公告)号：WO0181678A3
公开(公告)日：2002-02-21
申请号：PCT/US0111556
申请日：2001-04-10
申请人： HERCULES INC
发明人： LAUZON RODRIGUE V
摘要： There is disclosed a process for preparing an aqueous size composition by emulsifying a cellulose reactive size not solid at 25 DEG C into a starch stabilized aqueous polymer dispersion. The emulsification is carried out at a temperature substantially lower than 70 DEG C.
摘要翻译： 公开了通过在25℃下将不固体的纤维素反应性大小乳化到淀粉稳定的含水聚合物分散体中来制备水性组合物的方法。 乳化在基本上低于70℃的温度下进行。
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公开(公告)号：WO01088262A2
公开(公告)日：2001-11-22
申请号：PCT/US2001/015354
申请日：2001-05-11
摘要： This invention relates to paper sizing compositions comprised of at least one sizing agent selected from ASA, AKD and rosin where the at least one sizing agent is emulsified in water, at least one emulsion stabilizer, and from about 0.01% to about 15% by weight of at least one hydrophobic substance, based on the total weight of sizing agent present, provided that the hydrophobic substance is not highly alkoxylated. The sizing promotion efficiency of the paper sizing compositions, as determined by at least one method selected from the Cytec size testing method, the Hercules size testing method, and the Cobb size testing method, is greater than or equal to about 4. Exemplary hydrophobic substances include fatty acid esters, triglycerides, hydrocarbons, esters and/or amides derived from ASA, silicone oils, alcohols, and stearic anhydride. The invention also relates to methods for sizing paper products with these paper sizing compositions and paper or paperboard treated with these sizing compositions.
摘要翻译： 本发明涉及由至少一种选自ASA，AKD和松香的上浆剂组成的纸浆施胶组合物，其中至少一种施胶剂在水中乳化，至少一种乳化稳定剂和约0.01重量％至约15重量％ 的至少一种疏水性物质，基于存在的施胶剂的总重量，条件是疏水性物质不是高度烷氧基化的。 通过选自Cytec尺寸测试方法，Hercules尺寸测试方法和Cobb尺寸测试方法中的至少一种方法测定的纸浆施胶组合物的施胶效率大于或等于约4.示例性疏水物质 包括衍生自ASA，脂肪酸酯，甘油三酸酯，烃，酯和/或酰胺衍生自ASA，硅油，醇和硬脂酸酐。 本发明还涉及用这些上胶组合物和用这些施胶组合物处理的纸或纸板来调整纸制品的方法。
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公开(公告)号：WO01059214A1
公开(公告)日：2001-08-16
申请号：PCT/SE2001/000289
申请日：2001-02-14
摘要： A sizing composition and a method of sizing a cellulosic fibre material, such as paper, board or paper board, are described. The sizing composition comprises an aqueous dispersion of a rosin material and is characterised in that it also contains (a) 0.05-20 % by weight, based on the dry weight of the composition of a dicarboxylic acid derivative with the general formula (I): R1OOC-Q-COOR2; where R1 and R2 which are the same or different represent H, M, where M is a metal of Groups IA or IIA, or a straight or branched alkyl or alkenyl group having 1-30 carbon atoms; Q represents (i) R3 which is a straight alkylene group or alkenylene group of the formula: -CnH2n-2z-, where n = 0-12 and z = 0-3; (ii) Formula (II), where R3 is as defined above and R4 is a straight or branched alkyl or alkenyl group having 1-30 carbon atoms; with the proviso that the compound of formula (I) includes at least 6 and at most 34 carbon atoms in total; and (b) an aluminium compound which is selected from the group consisting of: aluminium sulphate; aluminium polymers of the general formula (III): [Al(OH)x(A)(3-x)]n; aluminium polymers of the general formula (IV): [Al(OH)x(H3PO4)y (A)(3-x)]n; where A = Cl , NO3 , HCOO , CH3COO ; aluminium polymers of the general formula (V): [Al(OH)x(SO4)(3-x)/2]n; aluminium polymers of the general formula (VI): [Al(OH)x(H3PO4)y (SO4)(3-x)/2]n; where "x" is in the range 0.03 to 2.7, "y" in the range 0.01 to 0.8 and n ≥ 2; and mixtures of these. According to the method the sizing composition is added to a cellulosic fibre material in an amount of 0.01-10 % by weight, calculated as dry sizing agent on dry cellulosic fibres.
摘要翻译： 描述了上浆组合物和纤维素纤维材料如纸，板或纸板的施胶方法。 上浆组合物包含松香材料的水性分散体，其特征在于它还含有（a）基于组合物的干重为0.05-20重量％的具有通式（I）的二羧酸衍生物： R 1 OOC-Q-COOR2; 其中相同或不同的R 1和R 2表示H，M，其中M是IA或IIA族的金属，或具有1-30个碳原子的直链或支链烷基或烯基; Q表示（i）R 3，其为下式的直链亚烷基或亚烯基：-C n H 2n-2 z - ，其中n = 0-12且z = 0-3; （ii）式（II），其中R3如上定义，R4是具有1-30个碳原子的直链或支链烷基或烯基; 条件是式（I）化合物总共包含至少6个且至多34个碳原子; 和（b）铝化合物，其选自：硫酸铝; 通式（III）的铝聚合物：[Al（OH）x（A）（3-x）] n; 通式（IV）的铝聚合物：[Al（OH）x（H 3 PO 4）y（A）（3-x）] n; 其中A = Cl - ，NO 3 - ，HCOO - ，CH 3 COO - 具有通式（V）：[Al（OH）x（SO 4）（3-x）/ 2] n的铝聚合物; 通式（VI）的铝聚合物：[Al（OH）x（H 3 PO 4）y（SO 4）（3-x）/ 2] n; 其中“x”在0.03至2.7的范围内，“y”在0.01至0.8和n≥2的范围内; 和这些的混合物。 根据该方法，施胶组合物以0.01-10重量％的量添加到纤维素纤维材料中，以干燥上浆剂计算在干纤维素纤维上。
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公开(公告)号：WO01044575A1
公开(公告)日：2001-06-21
申请号：PCT/SE2000/002501
申请日：2000-12-12
摘要： The present invention relates to a substantially water-free sizing composition, an aqueous sizing dispersion, the use for sizing or surface sizing paper and board and a process for the production of paper and board. The substantially water-free sizing composition comprises a cellulose reactive sizing agent and an esterified copolymer which is obtainable from a mixture comprising aliphatic olefins and derivatives of unsaturated carboxylic acids. More specifically, the composition comprises an esterified copolymer obtainable form a mixture comprising alpha -olefins and derivatives of alpha , beta -unsaturated dicarboxylic acids.
摘要翻译： 本发明涉及一种基本上无水的施胶组合物，水性上浆分散体，用于上浆或表面施胶纸和纸板的用途以及用于生产纸和纸板的方法。 基本上无水的施胶组合物包含纤维素反应性施胶剂和可由包含脂族烯烃和不饱和羧酸衍生物的混合物获得的酯化共聚物。 更具体地说，组合物包含由α烯烃和α，β-不饱和二羧酸的衍生物形成的混合物得到的酯化共聚物。
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公开(公告)号：WO99037857A1
公开(公告)日：1999-07-29
申请号：PCT/AT1999/000019
申请日：1999-01-25
IPC分类号： C08J3/03 , C08K5/1539 , D21H17/14 , D21H17/16 , D21H17/17 , D21H17/29 , D21H17/60 , D21H17/62 , D21H17/66 , D21H21/16 , D21H17/71
CPC分类号： C08J3/03 , C08J2393/00 , C08K5/1539 , D21H17/14 , D21H17/16 , D21H17/17 , D21H17/29 , D21H17/60 , D21H17/62 , D21H17/66 , D21H17/72 , D21H17/74 , D21H21/16 , C08L93/00
摘要： Aqueous paper sizing dispersions for internal and surface sizing contain colophonium resins or compounds derived from colophonium resins, a minimum amount of an anionic, cationic or non-ionic emulsifier, a subsequently added polymer for stabilising the dispersion, an optional aluminium-ion-containing fixator, an optional synthetic sizing agent and an optional extender. These new dispersions are suitable for finishing paper and cardboard. Also disclosed is a process for producing these aqueous paper sizing dispersions characterised in that during a first stage, a metastable dispersion of a colophonium resin or compound derived therefrom is prepared with a minimum amount of a synthetic emulsifier, this dispersion is immediately cooled, then converted at low temperatures with a polymer solution or dispersion into a stable dispersion.
摘要翻译： 描述的是Papierleimungsmitteldispersionen含水用于质量和表面施胶中，松香或松香化合物衍生，阴离子，阳离子或非离子乳化剂的最小量，随后加入聚合物来稳定分散体，任选地含有铝的离子定影剂，任选的合成施胶剂，和任选地 含有增量剂，以及它们的制备的方法。 新的分散体适合用于纸和纸板的精加工。 用于制备水性Papierleimungsmitteldispersionen该方法的特征在于：一个准备松香或用在第一步骤中，合成乳化剂的最小化的量的辅助下衍生的化合物的亚稳态分散，立即冷却该分散体，然后在冷用聚合物溶液或 聚合物分散体，得到稳定的分散体。
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公开(公告)号：WO9833982A3
公开(公告)日：1998-11-12
申请号：PCT/SE9800191
申请日：1998-02-03
申请人： AKZO NOBEL NV , EKA CHEMICALS AB , FROELICH STEN , LINDGREN ERIK , SIKKAR REIN
发明人： FROELICH STEN , LINDGREN ERIK , SIKKAR REIN
IPC分类号： D21H17/25 , D21H20060101 , D21H11/00 , D21H11/22 , D21H17/16 , D21H17/17 , D21H17/26 , D21H21/16 , D21H17/72
摘要： The invention relates to the use of an aqueous sizing dispersion containing a cellulose-reactive sizing agent and a hydrophobically modified dispersing agent for sizing cellulosic fibres by addition of the sizing dispersion to a stock containing cellulosic fibres, and optional fillers, and dewatering the stock on a wire to obtain a web containing cellulosic fibres, wherein the stock has a cationic demand of at least 50 νeq/litre stock filtrate. The invention further relates to an aqueous dispersion containing a cellulose-reactive sizing agent and an anionic hydrophobically modified cellulose-derivative, its preparation and use in the production of paper. The invention also relates to a substantially water-free composition containing a cellulose-reactive sizing agent and an anionic hydrophobically modified cellulose-derivative, its preparation and use in the preparation of an aqueous dispersion of cellulose-reactive sizing agent.
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