AZO DYES, A PROCESS FOR THE PREPARATION THEREOF AND THE USE THEREOF
    1.
    发明申请
    AZO DYES, A PROCESS FOR THE PREPARATION THEREOF AND THE USE THEREOF 审中-公开
    AZO染料,其制备方法及其用途

    公开(公告)号:WO2010046192A2

    公开(公告)日:2010-04-29

    申请号:PCT/EP2009062300

    申请日:2009-09-23

    Abstract: The present invention relates to dyes of formula (I) wherein R1 and R2 are each independently of the other hydrogen, vinyl, allyl or C1-C6alkyl which is unsubstituted or substituted by cyano, carboxy, hydroxy, C1-C6alkoxy or C6-C24aryl, R3 is hydrogen, C1-C6alkyl or C6-C24aryl, R4 is hydrogen, C1-C6alkyl or C6-C24aryl, 2-Cyano-C1-C6alkyl, 2-Alkoxy-C1-C6alkyl, 2-Oxo-C1-C6alkyl, n is 0, 1 or 2, and D denotes a radical of formula (2), (3), (4), (5), (6) or (7) wherein R5 is hydrogen, nitro, cyano or halogen, R6 and R7 are each independently of the other hydrogen, nitro, cyano or halogen, R8 and R9 are each independently of the other hydrogen, nitro, cyano or halogen, R10 and R11 are each independently of the other nitro, cyano, trifluoromethyl, carboxy, C1-C6alkyl, C1-C6alkoxy, C1-C6acylamino or halogen, R12 and R13 are each independently of the other hydrogen, nitro, cyano, trifluoromethyl, carboxy, C1-C6alkoxycarbonyl, C1-C6alkylsulfonyl, C1-C6alkylsulfonylamino, C1-C6acylamino or halogen, R14 represents nitro, cyano or halogen and R15 is C1-C6alkyl, and R16 is nitro, cyano, trifluoromethyl, carboxy, C1-C6alkylsulfonyl, C1-C6alkylsulfonylamino, C1-C6acylamino or halogen, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fibre materials, more especially textile materials.

    Abstract translation: 本发明涉及式(I)的染料,其中R 1和R 2各自独立地为未被取代或被氰基,羧基,羟基,C 1 -C 6烷氧基或C 6 -C 24芳基取​​代的其它氢,乙烯基,烯丙基或C 1 -C 6烷基, R3是氢,C1-C6烷基或C6-C24芳基,R4是氢,C1-C6烷基或C6-C24芳基,2-氰基-C1-C6烷基,2-烷氧基-C1-C6烷基,2-氧代-C1-C6烷基, (2),(3),(4),(5),(6)或(7)的基团,其中R5是氢,硝基,氰基或卤素,R6和R7 各自独立为氢,硝基,氰基或卤素,R 8和R 9各自独立地为氢,硝基,氰基或卤素,R 10和R 11各自独立地为其他硝基,氰基,三氟甲基,羧基,C1- C6烷基,C1-C6烷氧基,C1-C6烷氨基或卤素,R12和R13各自独立地为氢,硝基,氰基,三氟甲基,羧基,C1-C6烷氧基羰基,C1-C6烷基磺酰基,C1-6烷基磺酰基氨基, R14代表硝基,氰基或卤素,R15代表C1-C6烷基,R16代表硝基,氰基,三氟甲基,羧基,C1-C6烷基磺酰基,C1-C6烷基磺酰氨基,C1-C6酰氨基或卤素,和其制备方法和 涉及其在染色或印刷半合成和特别合成的疏水性纤维材料,尤其是纺织材料中的用途。

    MONO AZO DYES
    3.
    发明申请
    MONO AZO DYES 审中-公开

    公开(公告)号:WO2004044057A1

    公开(公告)日:2004-05-27

    申请号:PCT/IB2003/005096

    申请日:2003-11-11

    Inventor: HASEMANN, Ludwig

    CPC classification number: C09D11/328 C09B29/0088 C09B29/3656

    Abstract: The invention relates to novel azo dyestuffs of formula (I), the use of such compounds and/or mixtures for printing recording materials, especially paper or papery substrates, textile fibre materials, plastic films and plastic transparencies by the inkjet printing process and also to the recording materials printed thereby.

    Abstract translation: 本发明涉及式(I)的新型偶氮染料,通过喷墨印刷方法使用这些化合物和/或混合物来印刷记录材料,特别是纸或纸质基材,纺织纤维材料,塑料膜和塑料透明胶片,并且还涉及 由此印制的记录材料。

    MONOAZOQUINOLONE PIGMENTS, PROCESS FOR THEIR PREPARATION AND THEIR USE
    4.
    发明申请
    MONOAZOQUINOLONE PIGMENTS, PROCESS FOR THEIR PREPARATION AND THEIR USE 审中-公开
    MONOAZOQUINOLONE颜料,其制备方法及其使用

    公开(公告)号:WO02034839A1

    公开(公告)日:2002-05-02

    申请号:PCT/EP2001/012178

    申请日:2001-10-22

    CPC classification number: C09B29/0048 C09B29/332 C09B29/337

    Abstract: Monoazoquilolone pigments which, in one of the tautomeric forms thereof, correspond to formula (1), wherein Ar is a radical of formula (2a), (2b), (2c), (2d), 2(e) or (2f) wherein R1 is C1-C4alkyl, R2 and R3 are each independently of the other hydrogen, halogen, C1-C4alkyl, carboxy, sulfo, cyano, C1-C4alkoxycarbonal, C1-C4alkylcarbonyl,, C1-C4alkanoylamino, benzoylamino that is unsubstituted or substituted in the phenyl ring by halogen, nitro, C1-C4alkyl or by C1-C4alkoxy; carbamoyl, N-C1-C4alkylaminocarbonyl, N-arylaminocarbonyl that is unsubstituted or substituted in the aryl moiety by halogen, nitro, C1-C4alkyl or by C1-C4alkoxy; N,N-di-C1-C4alkylaminocarbonyl, C1-C4alkoxysulfonyl, C1-C4alkylsulfonyl, sulfamoyl, N-C1-C4alkylaminosulfonyl, N-arylaminosulfonyl that is unsubstituted or substituted in the aryl moiety by halogen, nitro, C1-C4alkyl or by C1-C4alkoxy; or N,N-di-C1-C4alklaminosulfonyl, wherein carboxy and sulfo are in the form of the free aci or in salt form, R8 and R9 are each independently of the other hydrogen, halogen, C1-C4alkyl, C1-C4alkoxy, carboxy, sulfo, cyano, C1-C4alkoxycarbonyl, C1-C4alkylcarbonyl, C1 -C4alkanoylamino, benzoylamino that is unsubstituted or substituted in the phenyl ring by halogen, nitro, C1-C4alkyl or by C1-C4alkoxy; carbamoyl, N-C1-C4alkylaminocarbonyl, N-arylaminocarbonyl that is unsubstituted or substituted in the aryl moiety by halogen, nitro, C1-C4alkyl or C1-C4alkoxy, N,N-di-C1-C4alkylaminocarbonyl, C1-C4alkoxysulfonyl, C1-C4alkylsulfonyl, sulfamoyl, N-C1-C4alkylaminosulfonyl, N-arylaminosulfonyl that is unsusbstituted or substituted in the aryl moiety by halogen, nitro, C1-C4alkyl or by C1-C4alkoxy; or N,N-di-C1-C4alkylaminosulfonyl, wherein carboxy and sulfo are in the form of the free acid or in salt form, Ar1 is an aryl radical, p is a number 0, 1 or 2, and r is a number 0, 1 or 2, wherein (R8)r in formula (2f) denodes r identical or different radicals R8, are suitable for the colouring of high molecular weight material and are distinguished by good fastness properties of the resulting colourations.

    Abstract translation: 其中Ar为式(2a),(2b),(2c),(2d),2(e)或(2f)所示基团的式(1)中的一种互变异构形式的单偶氮喹啉酮颜料, 其中R 1为C 1 -C 4烷基,R 2和R 3各自独立地为氢,卤素,C 1 -C 4烷基,羧基,磺基,氰基,C 1 -C 4烷氧基羰基,C 1 -C 4烷基羰基,C 1 -C 4烷酰基氨基,未取代或取代的苯甲酰氨基 苯基环由卤素,硝基,C 1 -C 4烷基或被C 1 -C 4烷氧基取代; 氨基甲酰基,N-C 1 -C 4烷基氨基羰基,未被取代或在芳基部分被卤素,硝基,C 1 -C 4烷基或被C 1 -C 4烷氧基取代的N-芳基氨基羰基; N,N-二-C 1 -C 4烷基氨基羰基,C 1 -C 4烷氧基磺酰基,C 1 -C 4烷基磺酰基,氨磺酰基,N-C 1 -C 4烷基氨基磺酰基,在芳基部分被卤素,硝基,C 1 -C 4烷基或C 1 -C 4烷基取代的N-芳基氨基磺酰基, C4烷氧基; 或N,N-二-C1-C4烷基氨基磺酰基,其中羧基和磺基为游离酰基或盐形式,R 8和R 9各自独立地为另一个氢,卤素,C 1 -C 4烷基,C 1 -C 4烷氧基,羧基 磺酰基,氰基,C 1 -C 4烷氧基羰基,C 1 -C 4烷基羰基,C 1 -C 4烷酰基氨基,苯甲酰氨基,其未被取代或在苯环中被卤素,硝基,C 1 -C 4烷基或被C 1 -C 4烷氧基取代; 硝基,C 1 -C 4烷基或C 1 -C 4烷氧基,N,N-二-C 1 -C 4烷基氨基羰基,C 1 -C 4烷氧基磺酰基,C 1 -C 4烷基磺酰基,C 1 -C 4烷基氨基羰基,N-C 1 -C 4烷基氨基羰基, 硝基,C 1 -C 4烷基或被C 1 -C 4烷氧基取代或取代的氨磺酰基,N-C 1 -C 4烷基氨基磺酰基,N-芳基氨基磺酰基, 或N,N-二-C 1 -C 4烷基氨基磺酰基,其中羧基和磺基为游离酸或盐形式,Ar 1为芳基,p为0,1或2,r为数0 1或2,其中式(2f)中的(R8)r表示相同或不同的基团R8,适用于高分子量材料的着色,并且由所得着色的良好牢度特性区分。

    아조 화합물의 제조방법
    5.
    发明申请

    公开(公告)号:WO2022039525A1

    公开(公告)日:2022-02-24

    申请号:PCT/KR2021/011046

    申请日:2021-08-19

    Abstract: 아조 화합물의 제조방법에 관해 개시되어 있다. 개시된 아조 화합물의 제조방법은 반응시스템 내에서 하이드라조 화합물 및 적어도 1종의 MaXb를 포함하는 제 1 용액을 전기분해하여 Xb 분자를 생성하는 제1단계, 상기 생성된 Xb 분자로 상기 하이드라조 화합물을 산화하여 아조 화합물, MaXb, 및 HX를 포함하는 제2 용액을 수득하는 제2단계, 상기 제2 용액을 상기 반응시스템 외부로 배출하고, 이로부터 MaXb 및 HX를 포함하는 제3 용액을 분리하여 고체 아조 화합물을 수득하는 제3단계 및 상기 하이드라조 화합물과 동등한 추가 하이드라조 화합물과 상기 제3 용액을 상기 반응시스템 내로 투입하고, 상기 추가 하이드라조 화합물, MaXb, 및 HX를 포함하는 제4 용액을 전기분해하여 Xb 분자를 생성하는 제4단계를 포함할 수 있다. 상기 제4단계, 상기 제2단계 및 상기 제3단계를 1 사이클로 하여 상기 사이클을 반복 수행할 수 있다. 여기서, 상기 X는 할로겐 원소일 수 있고, 상기 M은 수소, Li, Na, K, Mg, Ca, Mn, Fe, Ni, Cu, Ag, Zn, Sn, Zr, Ti 중에서 선택된 적어도 하나이거나, 1급 암모늄 이온, 2급 암모늄 이온, 3급 암모늄 이온 중에서 선택된 적어도 하나일 수 있다. 상기 H는 수소를 나타낼 수 있고, 상기 a 및 b는 서로 독립적으로 1 내지 4 중 어느 하나의 정수일 수 있다.

    AZO DYES, A PROCESS FOR THE PREPARATION THEREOF AND THE USE THEREOF

    公开(公告)号:WO2010046192A3

    公开(公告)日:2010-04-29

    申请号:PCT/EP2009/062300

    申请日:2009-09-23

    Abstract: The present invention relates to dyes of formula (I) wherein R 1 and R 2 are each independently of the other hydrogen, vinyl, allyl or C 1 -C 6 alkyl which is unsubstituted or substituted by cyano, carboxy, hydroxy, C 1 -C 6 alkoxy or C 6 -C 24 aryl, R 3 is hydrogen, C 1 -C 6 alkyl or C 6 -C 24 aryl, R 4 is hydrogen, C 1 -C 6 alkyl or C 6 -C 24 aryl, 2-Cyano-C 1 -C 6 alkyl, 2-Alkoxy-C 1 -C 6 alkyl, 2-Oxo-C 1 -C 6 alkyl, n is 0, 1 or 2, and D denotes a radical of formula (2), (3), (4), (5), (6) or (7) wherein R 5 is hydrogen, nitro, cyano or halogen, R 6 and R 7 are each independently of the other hydrogen, nitro, cyano or halogen, R 8 and R 9 are each independently of the other hydrogen, nitro, cyano or halogen, R 10 and R 11 are each independently of the other nitro, cyano, trifluoromethyl, carboxy, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 1 -C 6 acylamino or halogen, R 12 and R 13 are each independently of the other hydrogen, nitro, cyano, trifluoromethyl, carboxy, C 1 -C 6 alkoxycarbonyl, C 1 -C 6 alkylsulfonyl, C 1 -C 6 alkylsulfonylamino, C 1 -C 6 acylamino or halogen, R 14 represents nitro, cyano or halogen and R 15 is C 1 -C 6 alkyl, and R 16 is nitro, cyano, trifluoromethyl, carboxy, C 1 -C 6 alkylsulfonyl, C 1 -C 6 alkylsulfonylamino, C 1 -C 6 acylamino or halogen, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fibre materials, more especially textile materials.

    DYE MIXTURES
    10.
    发明申请
    DYE MIXTURES 审中-公开
    染料混合物

    公开(公告)号:WO2005071016A2

    公开(公告)日:2005-08-04

    申请号:PCT/EP2005/050104

    申请日:2005-01-12

    CPC classification number: C09B67/0033 Y10T428/2933

    Abstract: The present invention discloses mixtures of dyes, dye compositions comprising them and the use of said mixtures and compositions, optionally in combination with UV absorbers, to dye or print textile materials, particularly hydrophobic textile materials such as polyester, that must meet stringent lightfastness requirements. Fibers dyed with the inventive dye mixtures exhibit exceptional high temperature light fastness and good all-round fastness properties.

    Abstract translation: 本发明公开了染料的混合物,包含它们的染料组合物以及所述混合物和组合物的用途,所述混合物和组合物任选地与UV吸收剂组合用于染色或印花纺织材料,特别是疏水纺织材料如聚酯 必须符合严格的耐光要求。 用本发明染料混合物染色的纤维表现出特殊的高温耐光性和良好的全面牢固性。

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