The invention relates to a bis-silicon-bridged dinuclear metallocene compound and preparation and application thereof. The bridged cyclopentadienyl rings of the bis-silicon-bridged dinuclear metallocene compound contain different substituents. Dimethyldichlorosilane reacts with cyclopentadienyl sodium, so that light yellow solution is obtained; the light yellow solution reacts with n-butyl lithium, and dimethyldichlorosilane is then added for reaction, so that bis-silicon-bridged dicyclopentadiene is obtained; the bis-silicon-bridged dicyclopentadiene reacts with n-butyl lithium, halogenide is then added for reaction, n-butyl lithium is then added for reaction, and finally, another halogenide is added for reaction, so that ligand L is obtained; and cyclopentadienyl titanium trichloride or cyclopentadienyl zirconium trichloride or substituetd cyclopentadienyl titanium trichloride or substituetd cyclopentadienyl zirconium trichloride is added in the ligand L, so that the compound is obtained. The synthesis route is reasonable, the yield is high, separation and purification are easy, the amount of needed cocatalysts is less when the compound is used for catalyzing the copolymerization of ethylene, such as ethylene/hexene-1, ethylene/octene-1 and ethylene/decylene, and long-chain Alpha-alkene, the catalytic activity is high, the insertion rate of the long-chain Alpha-alkene is high, and molecular weight distribution is wide.