发明公开
- 专利标题: MIXED TRANSITION METAL CATALYST SYSTEMS FOR OLEFIN POLYMERIZATION
- 专利标题(中): 用于烯烃聚合的混合过渡金属催化剂体系
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申请号: EP97928992.0申请日: 1997-06-17
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公开(公告)号: EP0906343A2公开(公告)日: 1999-04-07
- 发明人: CANICH, Jo, Ann, Marie , VAUGHAN, George, Alan , MATSUNAGA, Phillip, T. , GINDELBERGER, David, Edward , SHAFFER, Timothy, Daniel , SQUIRE, Kevin, Richard
- 申请人: EXXON CHEMICAL PATENTS INC.
- 申请人地址: 5200 Bayway Drive Baytown, TX 77520-5200 US
- 专利权人: EXXON CHEMICAL PATENTS INC.
- 当前专利权人: EXXON CHEMICAL PATENTS INC.
- 当前专利权人地址: 5200 Bayway Drive Baytown, TX 77520-5200 US
- 代理机构: Frohwitter, Bernhard, Dipl.-Ing., et al
- 优先权: US19960019626P 19960617
- 国际公布: WO1997048735 19971224
- 主分类号: C08F4
- IPC分类号: C08F4 ; C08F10 ; C08F110 ; C08F210
摘要:
The invention encompasses a mixed transition metal olefin polymerization catalyst system suitable for the polymerization of olefin monomers comprising one late transition metal catalyst system and at least one different catalyst system selected from the group consisting of late transition metal catalyst systems, transition metal metallocene catalyst systems or Ziegler-Natta catalyst systems. Preferred embodiments include at least one late transition metal catalyst system comprising a Group 9, 10, or 11 metal complex stabilized by a bidentate ligand structure and at least one transition metal metallocene catalyst system comprising a Group 4 metal complex stabilized by at least one ancillary cyclopentadienyl ligand. The polymerization process for olefin monomers comprises contacting one or more olefins with these catalyst systems under polymerization conditions.
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