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公开(公告)号：EP0900242A1
公开(公告)日：1999-03-10
申请号：EP97925679.0
申请日：1997-05-21
CPC分类号： C08F210/02 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/916 , C08F212/04 , C08F210/10
摘要： Substantially random ethylene copolymers containing at least 3.0 mole percent of geminally disubstituted olefin monomers are described. The geminally disubstituted olefin monomers can be represented by the generic formula R1 = R2(R3)(R4), where R1 is CH2, R2 is C, and R3 and R4 are, independently, essentially linear hydrocarbyl groups having from 1 to 30 carbon atoms, or more, and containing one carbon atom bound directly to R2. The copolymers can be prepared by coordination polymerization by means of contacting at least one geminally disubstituted olefin monomer and ethylene, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl, heteroatom-containing Group 4 transition metal catalyst component.
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2.发明公开SUPPORTED IONIC TRANSITION METAL CATALYSTS FOR OLEFIN POLYMERIZATION 失效离子ÜBERGANGSMETALLKATALYSATOREREN的相关支持烯烃
公开(公告)号：EP0702700A1
公开(公告)日：1996-03-27
申请号：EP93918651.0
申请日：1993-08-05
发明人： UPTON, David, Jonathan , CANICH, Jo, Ann, Marie , HLATKY, Gregory, George , TURNER, Howard, William
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65916 , C08F4/6592
摘要： A supported catalyst for olefin polymerization comprising a monocyclopentadienyl Group 4 transition metal component, an ionic activator component comprising a cation capable or irreversibly reacting with a ligand of the transition metal component and a chemically stable, non-nucleophilic anionic complex having a molecular diameter about or greater than 4 angstroms, and a support material.
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3.发明授权SUPPORTED MONOCYCLOPENTADIENYL TRANSITION METAL OLEFIN POLYMERIZATION CATALYSTS 失效与过渡金属MONOZYKLOPENTADIENYLKOMPLEXEN载波烯烃聚合催化剂
公开(公告)号：EP0548257B1
公开(公告)日：1996-01-03
申请号：EP91917626.3
申请日：1991-09-13
IPC分类号： C08F4/642
CPC分类号： C08F10/00 , C07F7/10 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , Y10S526/943 , C08F2500/01 , C08F2500/03 , C08F2500/17 , C08F2500/24 , C08F2500/10 , C08F232/08 , C08F2500/25 , C08F210/08 , C08F210/14 , C08F236/20
摘要： A supported catalyst system comprises in inert support material, a Group IV B transition metal component and an alumoxane component; it may be employed to polymerize olefins to produce a high molecular weight polymer.
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公开(公告)号：EP0648230B1
公开(公告)日：1999-09-15
申请号：EP93916905.8
申请日：1993-07-01
发明人： CROWTHER, Donna, Jean , FISHER, Richard, Allen , CANICH, Jo, Ann, Marie , HLATKY, Gregory, George , TURNER, Howard, William
CPC分类号： C08F10/00 , B01J31/122 , B01J31/146 , B01J31/1805 , B01J31/2295 , B01J2531/0227 , B01J2531/57 , B01J2531/58 , B01J2531/66 , C07F9/005 , C07F11/00 , C07F11/005 , C07F17/00 , C08F4/639 , C08F4/63908 , C08F4/63912 , C08F10/02 , C08F2420/04 , Y10S526/904 , C08F4/62 , C08F4/623 , C08F4/6392
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5.发明公开PROCESS FOR PRODUCING AMORPHOUS POLY-$g(a)-OLEFINS WITH A MONOCYCLOPENTADIENYL TRANSITION METAL CATALYST SYSTEM 失效用于生产聚α-烯烃与过渡金属MONOZYKLOPENTADIENYLKOMPLEXEN的
公开(公告)号：EP0705283A1
公开(公告)日：1996-04-10
申请号：EP93916743.0
申请日：1993-06-24
CPC分类号： C08F110/06 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F2500/03 , C08F2500/02
摘要： The invention is a catalytic process using a Group IV B transition metal component and an alumoxane component to polymerize α-olefins to produce amorphous poly-α-olefins.
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6.发明公开
公开(公告)号：EP0668880A1
公开(公告)日：1995-08-30
申请号：EP93923784.0
申请日：1993-10-05
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/6592
摘要： An ionic catalyst system for polymerizing monomers comprising a reaction product of a Group 4 transition metal compounds containing a single cyclopentadienyl ligand and a heteroatom contacting group and a non-coordinating anion precursor, and a Group 13 element organo compound additive. The catalyst system described, employing the organoadditive, results in a catalyst of enhanced productivity for the polymerization of olefins. Said catalyst system and additive may optionally be placed on an inert support media and prepolymerized if desired. The catalyst system may be used to polymerize monomers under high pressure, solution, liquid, bulk, slurry or gas phase polymerization conditions.
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7.发明公开HIGH TEMPERATURE POLYMERIZATION PROCESS USING IONIC CATALYSTS TO PRODUCE POLYOLEFINS 失效用于制备聚烯烃通过使用离子催化剂高温聚合过程
公开(公告)号：EP0646140A1
公开(公告)日：1995-04-05
申请号：EP93916548.0
申请日：1993-06-15
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/6592 , C08F210/16 , C08F2/00 , C08F2/06 , C08F210/08 , C08F2500/17
摘要： This invention relates to a process for polymerizing olefins at high pressures in a polymerization medium at high temperature utilizing an ionic olefin polymerization catalyst derived from the reaction of a cyclopentadienyl-containing transition metal compound having a hydrolyzable alkyl or hydride ligand with an ion exchange activator. The ionic catalyst system has been found to be highly active at temperatures of 160 °C or greater, to provide a process capable of producing polymer products of desired chemical and physical properties at high production rates.
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8.发明公开PROCESS FOR PRODUCING CRYSTALLINE POLY-ALPHA-OLEFINS WITH A MONOCYCLOPENTADIENYL TRANSITION METAL CATALYST SYSTEM 失效工艺生产结晶聚α-烯烃与MONOZYKLOPENTADIENYLKOMPEX过渡金属。
公开(公告)号：EP0548277A1
公开(公告)日：1993-06-30
申请号：EP91918649.0
申请日：1991-09-13
CPC分类号： C08F10/00 , C07F7/10 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , Y10S526/943 , C08F2500/17 , C08F2500/03 , C08F2500/24 , C08F2500/01 , C08F2500/10 , C08F232/08 , C08F2500/25 , C08F210/08 , C08F210/14 , C08F236/20
摘要： Procédé catalytique servant à polymériser les alpha-oléfines pourproduire des poly-alpha-oléfines de grande cristallinité et d'un poids moléculaire élevé en utilisant un constituant de métal de transition du Groupe IV-B et un constituant d'alumoxane.
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公开(公告)号：EP0907665A1
公开(公告)日：1999-04-14
申请号：EP97930038.0
申请日：1997-06-17
发明人： VAUGHAN, George, Alan , CANICH, Jo, Ann, Marie , MATSUNAGA, Phillip, T. , GINDELBERGER, David, Edward , SQUIRE, Kevin, Richard
CPC分类号： C08F10/00 , B01J31/143 , B01J31/146 , B01J31/1616 , B01J31/1805 , B01J2531/847 , C08F10/02 , C08F110/02 , C08F2/34 , C08F2500/10 , C08F2500/12 , C08F2500/03 , C08F4/7006
摘要： The invention encompasses late transition metal catalyst systems immobilized on solid supports and their use in heterogenous polymerization processes, particularly in gas phase polymerization of olefin monomers. Preferred embodiments include a late transition metal catalyst system comprising a Group 9, 10, or 11 metal complex stabilized by a bidentate ligand structure immobilized on a solid porous metal or metalloid oxide particle support, particularly those comprising silica. The gas phase polymerization process for olefin monomers comprises contacting one or more olefins with these catalyst systems under gas phase polymerization conditions.
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10.发明授权HIGH TEMPERATURE POLYMERIZATION PROCESS USING IONIC CATALYSTS TO PRODUCE POLYOLEFINS 失效用于制备聚烯烃通过使用离子催化剂高温聚合过程
公开(公告)号：EP0646140B1
公开(公告)日：1998-12-30
申请号：EP93916548.6
申请日：1993-06-15
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/6592 , C08F210/16 , C08F2/00 , C08F2/06 , C08F210/08 , C08F2500/17
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