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    MIXED TRANSITION METAL CATALYST SYSTEMS FOR OLEFIN POLYMERIZATION
    3.
    发明公开
    MIXED TRANSITION METAL CATALYST SYSTEMS FOR OLEFIN POLYMERIZATION 无效
    用于烯烃聚合的混合过渡金属催化剂体系

    公开(公告)号：EP0906343A2

    公开(公告)日：1999-04-07

    申请号：EP97928992.0

    申请日：1997-06-17

    申请人： EXXON CHEMICAL PATENTS INC.

    发明人： CANICH, Jo, Ann, Marie ,  VAUGHAN, George, Alan ,  MATSUNAGA, Phillip, T. ,  GINDELBERGER, David, Edward ,  SHAFFER, Timothy, Daniel ,  SQUIRE, Kevin, Richard

    IPC分类号： C08F4 ,  C08F10 ,  C08F110 ,  C08F210

    CPC分类号： C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F10/02 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F2410/04 ,  Y10S526/943 ,  C08F4/61904 ,  C08F2500/03 ,  C08F2500/10 ,  C08F210/14 ,  C08F4/7006

    摘要： The invention encompasses a mixed transition metal olefin polymerization catalyst system suitable for the polymerization of olefin monomers comprising one late transition metal catalyst system and at least one different catalyst system selected from the group consisting of late transition metal catalyst systems, transition metal metallocene catalyst systems or Ziegler-Natta catalyst systems. Preferred embodiments include at least one late transition metal catalyst system comprising a Group 9, 10, or 11 metal complex stabilized by a bidentate ligand structure and at least one transition metal metallocene catalyst system comprising a Group 4 metal complex stabilized by at least one ancillary cyclopentadienyl ligand. The polymerization process for olefin monomers comprises contacting one or more olefins with these catalyst systems under polymerization conditions.

    摘要翻译： 本发明包括适用于烯烃单体聚合的混合过渡金属烯烃聚合催化剂体系，所述烯烃单体包含一种后过渡金属催化剂体系和至少一种不同的催化剂体系，所述催化剂体系选自后过渡金属催化剂体系，过渡金属茂金属催化剂体系或 齐格勒 - 纳塔催化剂体系。 优选实施方案包括至少一种后过渡金属催化剂体系，其包含通过二齿配体结构稳定的第9,10或11族金属络合物和至少一种过渡金属茂金属催化剂体系，所述过渡金属茂金属催化剂体系包含通过至少一种辅助环戊二烯基 配体。 烯烃单体的聚合方法包括在聚合条件下使一种或多种烯烃与这些催化剂体系接触。

    OLEFIN COPOLYMERS FROM BRIDGED BIS(ARYLAMIDO) GROUP 4 CATALYST COMPOUNDS
    6.
    发明公开
    OLEFIN COPOLYMERS FROM BRIDGED BIS(ARYLAMIDO) GROUP 4 CATALYST COMPOUNDS 失效
    用于生产烯烃来桥接的过渡金属的双（丙烯酰氨基）催化剂化合物组4

    公开(公告)号：EP0963384A1

    公开(公告)日：1999-12-15

    申请号：EP98906653.0

    申请日：1998-02-23

    申请人： EXXON CHEMICAL PATENTS INC.

    发明人： SHAFFER, Timothy, Daniel ,  SQUIRE, Kevin, Richard

    IPC分类号： C08F4 ,  C08F10 ,  C08F210

    CPC分类号： C08F10/10 ,  C08F210/02 ,  C08F210/06 ,  C08F210/14 ,  C08F4/64072 ,  C08F210/10 ,  C08F2500/02 ,  C08F2500/03

    摘要： A process for preparing substantially random olefin copolymers containing geminally disubstituted olefin monomers is described. The geminally disubstituted olefin monomers can be represented by the generic formula R1 = R2(R3)(R4), where R1 is CH2, R2 is C, and R3 and R4 are, independently, essentially linear hydrocarbyl groups having from 1 to 30 carbon atoms, or more, and containing one carbon atom bound directly to R2. The copolymers can be prepared by contacting at least one geminally disubstituted olefin monomer and one or more comonomers selected from the group consisting of ethylene and C3-C20 α-olefins, optionally with one or more other coordination polymerizable monomers, with an active coordination catalyst system comprising a bridged bis(arylamido) Group 4 catalyst component.

    COPOLYMERS OF ETHYLENE AND GEMINALLY DISUBSTITUTED OLEFINS
    7.
    发明公开
    COPOLYMERS OF ETHYLENE AND GEMINALLY DISUBSTITUTED OLEFINS 失效
    乙烯的共聚物和偕二取代的烯烃

    公开(公告)号：EP0900242A1

    公开(公告)日：1999-03-10

    申请号：EP97925679.0

    申请日：1997-05-21

    申请人： EXXON CHEMICAL PATENTS INC.

    发明人： SHAFFER, Timothy, Daniel ,  CANICH, Jo, Ann, Marie ,  SQUIRE, Kevin, Richard

    IPC分类号： C08F4 ,  C08F210

    CPC分类号： C08F210/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  Y10S526/916 ,  C08F212/04 ,  C08F210/10

    摘要： Substantially random ethylene copolymers containing at least 3.0 mole percent of geminally disubstituted olefin monomers are described. The geminally disubstituted olefin monomers can be represented by the generic formula R1 = R2(R3)(R4), where R1 is CH2, R2 is C, and R3 and R4 are, independently, essentially linear hydrocarbyl groups having from 1 to 30 carbon atoms, or more, and containing one carbon atom bound directly to R2. The copolymers can be prepared by coordination polymerization by means of contacting at least one geminally disubstituted olefin monomer and ethylene, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl, heteroatom-containing Group 4 transition metal catalyst component.