发明授权
- 专利标题: VERFAHREN ZUR HERSTELLUNG VON 1,4- BUTANDIOL
- 专利标题(英): Method for the production of 1,4- butanediol
- 专利标题(中): 用于生产1,4丁二醇
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申请号: EP03757050.4申请日: 2003-06-10
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公开(公告)号: EP1515932B1公开(公告)日: 2010-06-16
- 发明人: HESSE, Michael , SCHLITTER, Stephan , BORCHERT, Holger , SCHUBERT, Markus , RÖSCH, Markus , BOTTKE, Nils , FISCHER, Rolf-Hartmuth , WECK, Alexander , WINDECKER, Gunther , HEYDRICH, Gunnar
- 申请人: BASF SE
- 申请人地址: 67056 Ludwigshafen DE
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: 67056 Ludwigshafen DE
- 优先权: DE10225926 20020611
- 国际公布: WO2003104174 20031218
- 主分类号: C07C29/149
- IPC分类号: C07C29/149 ; C07C31/20
摘要:
The invention relates to a method for producing optionally alkyl-substituted 1,4-butanediol by means of two-stage catalytic hydration in the gas phase, comprising the following steps: a) a gas stream of C4-dicarboxylic acid or a derivative thereof is fed into a first reactor and the gas phase is catalytically hydrated so as to obtain a product mainly containing optionally alkyl-substituted y-butyrolactone; b) the obtained product stream is fed into a second reactor and the gas phase is catalytically hydrated so as to obtain optionally alkyl-substituted 1,4-butanediol; c) the desired product is separated from intermediate products, by-products, and an optionally unreacted starting material. A catalyst comprising = 95 percent by weight of CuO and = 5 percent by weight of an oxidic carrier is used in each hydration stage. The product mixture obtained in the first hydration step is introduced into the second hydration stage without further cleaning said product mixture.
公开/授权文献
- EP1515932A1 VERFAHREN ZUR HERSTELLUNG VON 1,4- BUTANDIOL 公开/授权日:2005-03-23
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