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    MESOPORÖSES METALLORGANISCHES GERÜSTMATERIAL
    4.
    发明授权
    MESOPORÖSES METALLORGANISCHES GERÜSTMATERIAL 有权
    中孔金属 - 有机骨架

    公开(公告)号：EP1917228B1

    公开(公告)日：2010-11-24

    申请号：EP06792831.7

    申请日：2006-08-16

    Applicant: BASF SE

    Inventor： SCHUBERT, Markus ,  MÜLLER, Ulrich ,  MATTENHEIMER, Hendrick ,  TONIGOLD, Markus

    IPC: C07C51/41 ,  C07F5/06 ,  C01B3/00

    CPC classification number: C07F5/069 ,  C01B3/001 ,  C01B3/0015 ,  C01B3/0026 ,  C07C51/418 ,  Y02E60/327 ,  Y02E60/328 ,  C07C63/307

    Abstract: The invention relates to porous metal-organic framework comprising Al'' and at least one at least bidentate compound. The at least one at least bidentate compound is a six-membered aromatic hydrocarbon ring A, wherein one ore more ring carbon atoms may be replaced by nitrogen and the three substituents X and optionally one or more substituents selected from the group including R, NRR', OR, SR, F, Cl, and Br, wherein R, R' independently represent hydrogen, methyl which is optionally substituted by one or more fluorine atoms or ethyl which is optionally substituted by one or more fluorine atoms and every X independently represents C(=O)O-, C(=S)O-, C(=O)S-, C(=S)S- or the protonized form thereof. The invention also relates to methods for producing said framework and to the use of the novel metal-organic framework.

    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS
    6.
    发明公开
    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS 有权
    方法用于分离的支链烃不会从支化异构

    公开(公告)号：EP2176201A1

    公开(公告)日：2010-04-21

    申请号：EP08774533.7

    申请日：2008-06-30

    Applicant: BASF SE

    Inventor： SCHUBERT, Markus ,  MÜLLER, Ulrich ,  KIENER, Christoph ,  RICHTER, Ingo ,  WILLIAM, Dolan ,  POPLOW, Frank

    IPC: C07C7/135 ,  C07C7/12

    CPC classification number: C07C7/12 ,  B01J20/22 ,  B01J20/226 ,  B01J2220/56 ,  C07C7/135 ,  C10G25/003 ,  C07C9/00

    Abstract: The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of-contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

    PORÖSES METALLORGANISCHES GERÜSTMATERIAL BASIEREND AUF PYRROLEN UND PYRIDINONEN
    7.
    发明公开
    PORÖSES METALLORGANISCHES GERÜSTMATERIAL BASIEREND AUF PYRROLEN UND PYRIDINONEN 有权
    PORÖSESMETALLORGANISCHESGERÜSTMATERIALBASIEREND AUF PYRROLEN UND PYRIDINONEN

    公开(公告)号：EP2019874A1

    公开(公告)日：2009-02-04

    申请号：EP07729020.3

    申请日：2007-05-11

    Applicant: BASF SE

    Inventor： RICHTER, Ingo ,  SCHUBERT, Markus ,  MÜLLER, Ulrich

    IPC: C25B3/12 ,  C07D233/54 ,  C07D235/22

    CPC classification number: C07D233/54 ,  B01J20/226 ,  C07D235/22 ,  C25B3/12

    Abstract: The present invention relates to a process for preparing a porous metal organic framework containing at least one organic compound coordinated to at least one metal ion, which comprises the step of oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of the at least one organic compound, where the at least one organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived at least from one of the heterocycles selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens, where the ring system is unsubstituted or has one or more substituents selected independently from the group consisting of halogen, C1-6-alkyl, phenyl, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OC1-6-alkyl, where the substituents C1-6-alkyl and phenyl are unsubstituted or have one or more substituents selected independently from the group consisting of halogen, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OC1-6-alkyl.

    Abstract translation: 本发明涉及制备含有至少一种与至少一种金属离子配位的有机化合物的多孔金属有机骨架的方法，该方法包括以下步骤：将至少一种含金属的阳极与对应于 在所述至少一种有机化合物存在下的反应介质，其中所述至少一种有机化合物是单环，双环或多环体系，其衍生自至少一种选自以下的杂环化合物：吡咯， 吡啶酮和γ-吡啶酮并且具有至少两个环氮，其中环系未被取代或具有一个或多个独立选自卤素，C 1-6 - 烷基，苯基，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，Ophenyl和OC 1-6 - 烷基，其中取代基C 1-6 - 烷基和苯基未被取代或具有一个或多个独立选自下列的取代基：卤素 O 2，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，Ophenyl和OC 1-6 - 烷基。

    VERFAHREN ZUR HERSTELLUNG PORÖSER METALLORGANISCHER GERÜSTMATERIALIEN
    8.
    发明公开
    VERFAHREN ZUR HERSTELLUNG PORÖSER METALLORGANISCHER GERÜSTMATERIALIEN 有权
    VERFAHREN ZUR HERSTELLUNGPORÖSERMETALLORGANISCHERGERÜSTMATERIALIEN

    公开(公告)号：EP2004589A1

    公开(公告)日：2008-12-24

    申请号：EP07704355.2

    申请日：2007-02-05

    Applicant: BASF SE

    Inventor： SCHUBERT, Markus ,  MÜLLER, Ulrich ,  HESSE, Michael ,  DIEHLMANN, Uwe

    IPC: C07C51/41 ,  C07C63/307 ,  C07F3/00 ,  B01J20/26

    CPC classification number: C07C51/418 ,  C07C63/307

    Abstract: The present invention relates to processes for preparing a porous metal-organic framework material that comprise the step of reacting in the liquid phase a reaction mixture composed of at least one copper compound with at least one at least bidentate organic compound able to coordinate to the copper, in the presence of a non-aqueous solvent, said at least one at least bidentate organic compound deriving from a polycarboxylic acid having at least three carboxyl groups, and the reaction taking place under atmospheric pressure at more than 80°C.

    Abstract translation: 本发明涉及多孔金属 - 有机骨架材料的制造方法，该方法包括使具有至少一种至少二齿的有机化合物的至少一种铜化合物的液相中的反应混合物反应，该有机化合物可通过配位与 铜在非水溶剂的存在下，所述至少一种至少二齿的有机化合物衍生自具有至少三个羧基的多元羧酸，并且所述反应在大气压下高于80℃进行。

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