The present invention provides a method for forming a sensitive film for neutron detection, wherein the sensitive film is formed by electrophoresis coating, the liquid used for electrophoresis coating includes neutron sensitive material, electrophoresis paint and deionized water, and the neutron sensitive material is 10B single substance, 10B compound or mixture containing 10B. The sensitive film for neutron detection has the high detection efficiency because of the high content of 10B. The sensitive film for neutron detection has the uniform and stable film thickness, and excellent consistency. The production efficiency and the cost of the sensitive film are improved.