Invention Grant
- Patent Title: Continuous methods of manufacture of 2-aryl-3,3-BIS(4-hydroxyaryl)phthalimidines, and polymers derived therefrom
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Application No.: US16316539Application Date: 2017-07-12
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Publication No.: US10544096B2Publication Date: 2020-01-28
- Inventor: Sivakumar Sreeramagiri , Deshmukh Sandesh Shivajirao , Samir Anapat , Vishal Keshaorao Karmore , Sanjay Katrekar , Alok Pal
- Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
- Applicant Address: NL Bergen op Zoom
- Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee Address: NL Bergen op Zoom
- Agency: Cantor Colburn LLP
- Priority: IN201611023923 20160713
- International Application: PCT/US2017/041618 WO 20170712
- International Announcement: WO2018/013623 WO 20180118
- Main IPC: C07D209/46
- IPC: C07D209/46 ; C07D209/44 ; C08G64/30 ; C08G64/12

Abstract:
A continuous method for the manufacture of a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine comprising continuously heating an anhydride with a phenol in the presence of a catalyst and a first co-catalyst, to form a first reaction mixture comprising a phenolphthalein compound; precipitating the phenolphthalein compound; combining a primary arylamine with an acid catalyst and a second co-catalyst to form a second reaction mixture; adding the phenolphthalein compound to the second reaction mixture; continuously heating the second reaction mixture to provide a third reaction mixture comprising a crude phthalimidine; and treating the crude phthalimidine to remove aminophenol and purify the phthalimidine is provided.
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