Invention Grant
- Patent Title: High heat copolycarbonate compositions having enhanced optical properties, articles formed therefrom, and methods of manufacture
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Application No.: US16302827Application Date: 2017-05-27
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Publication No.: US10947381B2Publication Date: 2021-03-16
- Inventor: Mark Adrianus Johannes Van Der Mee , Nathalie Gonzalez Vidal , Fabrizio Micciche , Roland Sebastian Assink , Kazuhiko Mitsui , Johannes De Brouwer , Shahram Shafaei , Hendrikus Petrus Cornelis Van Heerbeek , Tamara Marijke Eggenhuisen , Robert Dirk Van De Grampel
- Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
- Applicant Address: NL Bergen op Zoom
- Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee Address: NL Bergen op Zoom
- Agency: Cantor Colburn LLP
- International Application: PCT/IB2017/053139 WO 20170527
- International Announcement: WO2017/203496 WO 20171130
- Main IPC: C08L69/00
- IPC: C08L69/00 ; C08G64/06 ; G02B1/04 ; C08G64/12 ; C08J7/04

Abstract:
A thermoplastic composition comprises: a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of the formula (I) and optionally, a bisphenol A homopolycarbonate; wherein the second carbonate units are present in an amount of 10 to 49 mol % based on the sum of the moles of the copolycarbonate and the bisphenol A homopolycarbonate, the copolycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography, and the thermoplastic composition has a bisphenol A purity of at least 99.6%, or at least 99.7% as determined by high performance liquid chromatography. The thermoplastic composition has a Vicat B120 of 155° C. or higher; and an increase in yellowness index of less than 10 during 1000 hours of heat aging at 155° C.
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