公开(公告)号：US10449344B2

公开(公告)日：2019-10-22

申请号：US16095873

申请日：2017-04-28

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Maria Dolores Martinez Canovas ,  Mark Adrianus Johannes Van Der Mee ,  Robert Dirk Van De Grampel ,  Johannes De Brouwer

IPC: A61M37/00 ,  A61B5/00 ,  C08L69/00 ,  C08L83/10 ,  C08G77/448

Abstract: A microneedle includes a shaft having a proximal end and a distal end and a capillary space within the shaft, the capillary space (i) connecting the proximal and distal ends or (ii) extending from the distal end of the shaft and connecting with one or more external openings positioned between the proximal end and distal end or (iii) performing the functions of both (i) and (ii). The microneedle includes a polymer mixture which includes (a) optionally polycarbonate, (b) a polycarbonate-polysiloxane copolymer and (c) a mold release agent.

公开(公告)号：US09598577B1

公开(公告)日：2017-03-21

申请号：US14943651

申请日：2015-11-17

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Ramon Groote ,  James Franklin Hoover ,  Robert Dirk Van De Grampel ,  Mark Adrianus Johannes Van Der Mee ,  Remco Wirtz ,  Jian Yang ,  Junhua Zhang

IPC: C08L69/00 ,  C08L83/10

CPC classification number: C08L83/10 ,  C08G77/448 ,  C08L69/00 ,  C08L2205/025 ,  C08L2205/03

Abstract: A polycarbonate composition comprises: a first poly(carbonate-siloxane) copolymer, comprising a polysiloxane block with an average block length of 10 to 100, and a siloxane content from 5 wt % to 10 wt %; and a second poly(carbonate-siloxane) copolymer comprising a polysiloxane block with an average block length of 10 to 100, and a siloxane content from 30 wt % to 60 wt %; wherein the weight ratio of the first poly(carbonate-siloxane) copolymer to the second poly(carbonate-siloxane) copolymer is greater than or equal to 2 to less than 8; and a bisphenol A homopolycarbonate, wherein the polycarbonate composition has a total siloxane content of 2.5 wt % to 10 wt % based on the total weight of the composition; and a molded part of 1 mm thickness has a haze of less than 10% as measured by HazeGard (ASTM D1003-00).

公开(公告)号：US11525055B2

公开(公告)日：2022-12-13

申请号：US16320778

申请日：2017-07-28

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Maria Dolores Martinez Canovas ,  Mark Adrianus Johannes Van Der Mee ,  Robert Dirk Van De Grampel ,  Erhard Bruss

IPC: B29C45/40 ,  C08L69/00 ,  B29C45/00 ,  B29K69/00 ,  B29K105/00

Abstract: The disclosure concerns methods for molding a polycarbonate containing plastic, the method including: (a) injecting a composition into a mold, the composition including (i) about 49 wt % to about 97.9 wt % of polycarbonate, (ii) about 2.0 wt % to about 50 wt % of a polycarbonate-polysiloxane copolymer, and (iii) about 0 wt % to about 1.0 wt % of at least one release agent; and (b) releasing the composition from the mold. The mold includes at least one draft angle of about 0.1 degrees to about 7 degrees. The polycarbonate blend includes a melt flow volume rate (MVR) of at least about 25 cm3/10 min as measured according to ISO 1133 at 300° C. and 1.2 kg.

公开(公告)号：US10005902B2

公开(公告)日：2018-06-26

申请号：US15110477

申请日：2015-01-12

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Paul Dean Sybert ,  Mark Adrianus Johannes Van Der Mee ,  Roland Sebastian Assink ,  Robert Dirk Van De Grampel ,  Aditya Narayanan ,  Feng Cao ,  Kapil Chandrakant Sheth ,  Hao Zhou ,  Xiaoyu Sun ,  Remco Wirtz

IPC: C08L69/00 ,  C08L79/08 ,  B32B27/08 ,  C08J5/00 ,  C25D11/02 ,  C08K3/22

CPC classification number: C08L69/00 ,  B32B27/08 ,  C08J5/00 ,  C08J2369/00 ,  C08J2469/00 ,  C08J2479/08 ,  C08K3/22 ,  C08K5/526 ,  C08K2003/2241 ,  C08L69/005 ,  C08L79/08 ,  C08L2201/08 ,  C08L2203/12 ,  C08L2203/14 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2205/06 ,  C08L2207/04 ,  C25D11/02

Abstract: A thermoplastic composition comprises, based on the total weight of the thermoplastic composition, 10 to 45 wt. % of a poly(etherimide); 35 to 90 wt. % of a poly(carbonate-siloxane); 0.5 to 20 wt. % of compatibilizer polycarbonate component comprising a poly(carbonate-arylate ester); up to 15 wt. % of an ultraviolet light stabilizer; and 0 to 30 wt. % of TiO2; wherein a sample of the composition has a notched Izod impact energy of at least 200 J/m at 23° C. measured in accordance to ASTM D256; and an at least 50% higher notched Izod impact energy value compared to the composition without the compatibilizer component measured in accordance to ASTM D256.

公开(公告)号：US11155695B2

公开(公告)日：2021-10-26

申请号：US16061427

申请日：2016-12-12

Applicant: SABIC Global Technologies B.V.

Inventor： Tamara Marijke Eggenhuisen ,  Roland Sebastian Assink ,  Eduardus Ludovicus Louisa Broekaart ,  Robert Dirk Van De Grampel ,  David Del Agua Hernandez ,  Ignacio Vic Fernandez

IPC: C08K5/42 ,  C08K5/3475 ,  C08K5/3492 ,  C08K5/50 ,  C08K5/523 ,  C08K5/526 ,  C08K5/5393 ,  G02B1/04 ,  C08G64/22 ,  C08L69/00 ,  C08K5/5333 ,  C08K3/32 ,  C08K3/30 ,  B29C45/00 ,  B29K69/00 ,  B29K105/00

Abstract: A molded article includes a polycarbonate resin, an ultraviolet (UV) absorbing component, a heat stabilizer component and an acid stabilizer component. The polycarbonate resin is produced by an interfacial polymerization process and has an end-cap level of at least about 98%, and includes a ratio of bound UV absorbing component to free UV absorbing component of less than about 1.0 when molded under abusive molding conditions. The polycarbonate resin may include high purity polycarbonate. The acid stabilizer component may include a sulfonic acid ester. Methods of forming molded articles are also described.

公开(公告)号：US10793715B2

公开(公告)日：2020-10-06

申请号：US16061504

申请日：2016-12-12

Applicant: SABIC Global Technologies B.V.

Inventor： Tamara Marijke Eggenhuisen ,  Roland Sebastian Assink ,  Eduardus Ludovicus Louisa Broekaart ,  Robert Dirk Van De Grampel

IPC: C08L69/00 ,  B29B7/88 ,  B29C45/00 ,  C08K5/00 ,  C08K5/08 ,  B29K69/00 ,  B29K105/00

Abstract: A molded article includes a polycarbonate resin and a colorant, and the molded article, when tested using a 3 mm color plaque, includes a color difference delta E (dE*) of less than about 0.6 following molding under abusive molding conditions as compared to a reference article molded under standard processing conditions. The molded article may include a color difference delta b (db*) of less than about 0.3 after being molded under the abusive molding conditions. The molded article may also exhibit a shift in wavelength of maximum absorbance of less than about 5 nm after being molded under the abusive molding conditions and/or a difference in absorbance intensity of less than about 15% after being molded under the abusive molding conditions as compared to a reference article molded under standard processing conditions. Methods for forming a molded article in accordance with the above are also described.

公开(公告)号：US20190225549A1

公开(公告)日：2019-07-25

申请号：US16327635

申请日：2017-08-25

Applicant: SABIC Global Technologies B.V.

Inventor： Erik Schwartz ,  Thomas L. Evans ,  Theodorus Hoeks ,  Robert Dirk Van De Grampel ,  Chiel Albertus Leenders ,  Mark John Armstrong

IPC: C04B35/634 ,  C04B41/83 ,  C04B41/48 ,  C04B35/488 ,  C04B35/626 ,  C04B41/00 ,  C04B35/453 ,  C04B35/495

Abstract: Described herein are cold-sintered ceramic polymer composites and processes for making them from ceramic precursor materials and monomers and/or oligomers. The cold sintering process and wide variety of monomers permit the incorporation of diverse polymeric materials into the ceramic.

公开(公告)号：US10899877B2

公开(公告)日：2021-01-26

申请号：US16095755

申请日：2017-04-28

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Paul Dean Sybert ,  Tony Farrell ,  Rob Boonman ,  Robert Dirk Van De Grampel ,  Mark Adrianus Johannes Van Der Mee

IPC: C08G63/64 ,  C08L69/00

Abstract: A poly(carbonate-ester) copolymer including carbonate units of the formula (I); and ester units of the formula (II) wherein: T is a C2-20 alkylene, a C6-20 cycloalkylene, or a C6-20 arylene; and R1 and J are each independently a bisphenol A divalent group, or a phthalimidine divalent group or a third divalent group of the formula (III), (IV), (V), (VI) or (VII) wherein Xa is a C6-12 polycyclic aryl, C3-18 mono- or polycycloalkylene, C3-18 mono- or polycycloalkylidene, -(Q1)x-G-(Q2)y- group wherein Q1 and Q2 are each independently a C1-3 alkylene, G is a C3-10 cycloalkylene, x is 0 or 1, and y is 1, provided that the at least one bisphenol A divalent group, at least one phthalimidine divalent group, and at least one third divalent group are present in the poly(carbonate-ester) copolymer.

公开(公告)号：US10808100B2

公开(公告)日：2020-10-20

申请号：US16061473

申请日：2016-12-12

Applicant: SABIC Global Technologies B.V.

Inventor： Tamara Marijke Eggenhuisen ,  Roland Sebastian Assink ,  Eduardus Ludovicus Louisa Broekaart ,  Robert Dirk Van De Grampel

IPC: C08K5/00 ,  C08K5/3475

Abstract: A molded article includes a polycarbonate resin, an ultraviolet (UV) absorbing component, a heat stabilizer component, and a colorant. The molded article, when tested using a 2.5 mm color plaque, includes a color difference delta E* (dE*) of less than about 0.6 following molding under abusive molding conditions as compared to a reference article molded under standard processing conditions. The molded article may include a color difference delta b* (db*) of less than about 0.3 after being molded under the abusive molding conditions as compared to a reference article molded under standard processing conditions. The UV absorbing component may include a benzotriazole compound. Methods for forming a molded article in accordance with the above are also described.

公开(公告)号：US10787568B2

公开(公告)日：2020-09-29

申请号：US16319387

申请日：2017-07-25

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Mark Adrianus Johannes Van Der Mee ,  Nathalie Gonzalez Vidal ,  Fabrizio Micciche ,  Roland Sebastian Assink ,  Kazuhiko Mitsui ,  Johannes De Brouwer ,  Shahram Shafaei ,  Hendrikus Petrus Cornelis Van Heerbeek ,  Tamara Marijke Eggenhuisen ,  Robert Dirk Van De Grampel

IPC: C08L69/00 ,  C08K5/42 ,  C08K5/00

Abstract: tic composition includes: a high heat polycarbonate comprising optional bisphenol A carbonate units and high heat carbonate units of the formula (1), (2), (3), or a combination thereof; optionally a bisphenol A homopolycarbonate; and 2 to 40 ppm of an organosulfonic stabilizer of the formula (a) wherein the high heat carbonate units are present in an amount of 20 to 49 mol %, preferably 30 to 40 mol % based on the sum of the moles of the high heat polycarbonate and the bisphenol A homopolycarbonate, and optionally the high heat polycarbonate comprises less than 2 ppm by weight of each of an ion of lithium, sodium, potassium, calcium, magnesium, ammonium, chlorine, bromine, fluorine, nitrite, nitrate, phosphite, phosphate, sulfate, formate, acetate, citrate, oxalate, trimethylammonium, and triethylammonium, as measured by ion chromatography; and the thermoplastic composition has: a Vicat B120 of 160° C. or higher measured according to ISO 306; and a yellowness index of less than 12, measured according to ASTM D1925.