Invention Grant
- Patent Title: Direct synthesis of metal-containing CHA zeolites
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Application No.: US16723145Application Date: 2019-12-20
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Publication No.: US11278875B2Publication Date: 2022-03-22
- Inventor: Lifeng Wang , Bjorn Moden , James Thomas Hughes , Hong-Xin Li
- Applicant: Lifeng Wang , Bjorn Moden , James Thomas Hughes , Hong-Xin Li
- Applicant Address: US PA Bryn Mawr; US PA West Chester; US PA Devon; US PA Lansdale
- Assignee: Lifeng Wang,Bjorn Moden,James Thomas Hughes,Hong-Xin Li
- Current Assignee: Lifeng Wang,Bjorn Moden,James Thomas Hughes,Hong-Xin Li
- Current Assignee Address: US PA Bryn Mawr; US PA West Chester; US PA Devon; US PA Lansdale
- Agency: Finnegan, Henderson, Farabow, Garrett & Dunner, LLP
- Main IPC: B01J29/76
- IPC: B01J29/76 ; B01D53/94 ; B01J37/00 ; B01J37/03 ; B01J37/04 ; B01J37/08 ; C01B39/48 ; G01N30/74

Abstract:
A metal-containing chabazite zeolite, which has an FTIR peak area ratio between the peak at 900-1300 cm−1 (Si—O—Si asymmetric stretch) and the peak at 765-845 cm−1 (˜805 cm−1 is Si—O—Si symmetric stretch) of at least 55. A method for preparing metal-containing CHA zeolites with high SCR activity at low reaction temperatures from alkali cation-free reaction mixtures that contain the three OSDA structures: metal-polyamine, N,N,N-trimethyl-1-adamantyl ammonium (TMAda+) and TMAOH. The metal-containing CHA zeolites produced by the disclosed method can be identified by XRD, FTIR spectroscopy, FT-VIS spectroscopy, and scanning electron microscopy. A method of selective catalytic reduction of NOx in exhaust gas using the material described herein is also disclosed.
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