摘要:
A metal-containing chabazite zeolite, which has an FTIR peak area ratio between the peak at 900-1300 cm−1 (Si—O—Si asymmetric stretch) and the peak at 765-845 cm−1 (˜805 cm−1 is Si—O—Si symmetric stretch) of at least 55. A method for preparing metal-containing CHA zeolites with high SCR activity at low reaction temperatures from alkali cation-free reaction mixtures that contain the three OSDA structures: metal-polyamine, N,N,N-trimethyl-1-adamantyl ammonium (TMAda+) and TMAOH. The metal-containing CHA zeolites produced by the disclosed method can be identified by XRD, FTIR spectroscopy, FT-VIS spectroscopy, and scanning electron microscopy. A method of selective catalytic reduction of NOx in exhaust gas using the material described herein is also disclosed.
摘要:
There is disclosed iron-containing aluminosilicate zeolites having both framework iron and iron cations on the ion-exchange sites. There is also disclosed a direct synthesis method of making an iron-containing aluminosilicate zeolite, which does not require the use of an intermediate step, such as ion-exchange or impregnation. In addition, there is disclosed a method of using the iron-containing aluminosilicate zeolite disclosed herein in a selective catalytic reduction reaction, typically in the presence of ammonia, to reduce or remove nitric oxides from exhaust emissions.
摘要:
An as-synthesized microporous material having a CHA structure and containing at least one organic structure directing agent that has the following general structure of the quaternary ammonium cation is disclosed: A microporous crystalline material made from the as-synthesized material is also disclosed. A method of making microporous crystalline material using one or more organic structure directing agents is also disclosed. A method of selective catalytic reduction of nitrogen oxides in exhaust gas that comprises contacting exhaust gases, typically in the presence of ammonia, urea, an ammonia generating compound, or a hydrocarbon compound, with an article comprising the disclosed microporous crystalline is also disclosed.
摘要:
There is disclosed iron-containing aluminosilicate zeolites having both framework iron and iron cations on the ion-exchange sites. There is also disclosed a direct synthesis method of making an iron-containing aluminosilicate zeolite, which does not require the use of an intermediate step, such as ion-exchange or impregnation. In addition, there is disclosed a method of using the iron-containing aluminosilicate zeolite disclosed herein in a selective catalytic reduction reaction, typically in the presence of ammonia, to reduce or remove nitric oxides from exhaust emissions.
摘要:
There is disclosed a method of making, through direct synthesis, a catalyst comprising an Fe-SAPO-34 molecular sieve. There is also disclosed an Fe-SAPO-34 molecular sieve made according to the disclosed method herein, wherein the molecular sieve contains both framework iron and iron cations at ion-exchange sites. In addition, there is disclosed a method of using the Fe-SAPO-34 disclosed herein in a selective catalytic reduction reaction, typically in the presence of ammonia or urea, to reduce or remove nitric oxides from exhaust emissions.
摘要:
There is disclosed a microporous crystalline material comprising a metal containing chabazite having a crystal size greater than 0.5 microns and a silica-to-alumina ratio (SAR) greater than 15, wherein the metal containing chabazite retains at least 80% of its initial surface area and micropore volume after exposure to temperatures of up to 900° C. in the presence of up to 10 volume percent water vapor for up to 1 hour. Methods of using the disclosed crystalline material, such as in the SCR of NOx in exhaust gas are also disclosed, as are methods of making such materials.
摘要:
There is disclosed a method to synthesize microporous crystalline material comprising a metal containing chabazite having a crystal size greater than 0.5 microns and a silica-to-alumina ratio (SAR) between 5 and 15, wherein the method is carried out without the use of an organic structural directing agent and without requiring calcination. There is also disclosed a large crystal organic free chabazite made according to the disclosed method. In addition, there are disclosed methods of using the disclosed crystalline material, such as in the selective catalytic reduction of NOx in exhaust gases.
摘要:
There is disclosed an organic-free, metal-containing zeolite Beta with a silica-to-alumina ratio (SAR) ranging from 5 and 20, and a metal content of at least 0.5 wt. %. There is also disclosed a method of making such a zeolite Beta without organic structure directing agent (SDA). The metal, which may comprise Fe or Cu, can be found in amounts ranging from 1-10 wt. %. A method of selective catalytic reduction of nitrogen oxides in exhaust gases using the disclosed zeolite is also disclosed.
摘要:
There is disclosed a hydrothermally stable microporous crystalline material comprising a molecular sieve or zeolite having an 8-ring pore opening structure, such as SAPO-34 or aluminosilicate zeolite, able to retain a specific percentage of its surface area and micropore volume after treatment with heat and moisture, such as at least 80% of its surface area and micropore volume after exposure to temperatures of up to 900° C. in the presence of up to 10 volume percent water vapor for a time ranging from 1 to 16 hours. Methods of using the disclosed crystalline material, such as in the SCR of NOx in exhaust gas are also disclosed, as are methods of making such materials.
摘要:
There is disclosed iron-containing aluminosilicate zeolites having both framework iron and iron cations on the ion-exchange sites. There is also disclosed a direct synthesis method of making an iron-containing aluminosilicate zeolite, which does not require the use of an intermediate step, such as ion-exchange or impregnation. In addition, there is disclosed a method of using the iron-containing aluminosilicate zeolite disclosed herein in a selective catalytic reduction reaction, typically in the presence of ammonia, to reduce or remove nitric oxides from exhaust emissions.