Invention Grant
- Patent Title: Sol containing nano zirconia particles for use in additive manufacturing processes for the production of 3-dimensional articles
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Application No.: US15574646Application Date: 2016-05-26
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Publication No.: US11339095B2Publication Date: 2022-05-24
- Inventor: Helmar B. Mayr , Malte Korten , Christine M. Andres , Brant U. Kolb , Holger Hauptmann , Gallus Schechner , Michael Jahns , Kathleen M. Humpal , Melissa A. Lackey , Paul D. Pennington
- Applicant: 3M INNOVATIVE PROPERTIES COMPANY
- Applicant Address: US MN St. Paul
- Assignee: 3M INNOVATIVE PROPERTIES COMPANY
- Current Assignee: 3M INNOVATIVE PROPERTIES COMPANY
- Current Assignee Address: US MN St. Paul
- Agency: 3M Innovative Properties Company
- Priority: EP15169570 20150528
- International Application: PCT/US2016/034273 WO 20160526
- International Announcement: WO2016/191534 WO 20161201
- Main IPC: C04B35/486
- IPC: C04B35/486 ; B28B1/00 ; A61C13/00 ; A61C13/083 ; C04B35/624 ; C04B35/64 ; A61C5/73 ; A61C5/77 ; A61C13/09 ; B33Y70/00 ; A61C5/70 ; A61K6/17 ; A61K6/82 ; A61K6/802 ; A61K6/807 ; A61K6/818 ; A61K6/822 ; B33Y10/00 ; B33Y80/00

Abstract:
The invention relates to the use of a printing sol as construction material in an additive manufacturing process for producing a 3-dim article, the printing sol comprising solvent(s), nano-sized crystalline zirconia particles in an amount from 2 to 25 vol.-% with respect to the volume of the sol, the average primary particle size of the nano-sized crystalline zirconia particles being in a range up to 50 nm, a first monomer being a polymerizable surface modification agent represented by formula A-B, with A being capable of attaching to the surface of the nano-sized crystalline zirconia particles and B being a radiation curable group, optionally a second monomer, the second monomer comprising at least one radiation curable moiety but no acidic or silane group(s), photo initiator(s). The invention also relates to a ceramic article obtainable according to such a process.
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