A multi-mode powertrain system employing a power-split configuration to transfer torque to a driveline includes an internal combustion engine fluidly coupled to an exhaust aftertreatment system having a catalytic device. A method for controlling the multi-mode powertrain system includes identifying permitted transition paths between a plurality of engine states. The plurality of engine states includes a default state, a pre-light-off state, a light-off state, and a post-light-off state. A preferred one of the plurality of engine states is selected in response to an output torque request and an operating temperature of the catalytic device. Engine operation is transitioned to the preferred one of the plurality of engine states via the permitted transition paths, and the engine is operated in the preferred one of the plurality of engine states.