发明授权
- 专利标题: Ternary catalyst systems for the polymerization of cycle olefins
- 专利标题(中): 用于循环烯烃聚合的第三催化剂体系
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申请号: US3689471D申请日: 1968-08-26
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公开(公告)号: US3689471A公开(公告)日: 1972-09-05
- 发明人: JUDY WILLIAM ALLEN
- 申请人: GOODYEAR TIRE & RUBBER
- 专利权人: Goodyear Tire & Rubber
- 当前专利权人: Goodyear Tire & Rubber
- 优先权: US75537468 1968-08-26
- 主分类号: C08F2/00
- IPC分类号: C08F2/00 ; C08F4/12 ; C08F4/42 ; C08F10/00 ; C08G61/08 ; C08F1/28 ; C08F3/02 ; C08F15/04
摘要:
A METHOD FOR THE RING OPENING POLYMERIZATION OF UNSATURATED ALICYCLIC COMPOUNDS CONTAINING AT LEAST 4 AND NOT MORE THAN 5 CARBON ATOMS AND ONE DOUBLE BOND IN THE CYCLIC RING AND UNSATURATED ALICYCLIC COMPOUNDS CONTAINING AT LEAST 8 CARBON ATOMS AND AT LEAST ONE DOUBLE BOND IN THE CYCLIC RING IS DISCLOSED WHICH COMPRISES SUBJECTING SUCH UNSATURATED ALICYCLIC COMPOUNDS TO A CATALYST SYSTEM COMPRISING (A) A TUNGSTEN OR MOLYBDENUM HALIDE OR OXYHALIDE, (B) AT LEAST ONE LEWIS ACID OF THE FORMULA MXN WHERE M IS A METAL REPRESENTED BY ALUMINUM, ZINC, GALLIUM, TIN AND ANTIMONY; X IS A HALOGEN SUCH AS BROMINE, CHLORINE, IODINE AND FLUORINE AND N IS AN INTEGER EQUAL TO THE VALENCE OF M AND (C) A REFUCING AGENT SELECTED FROM THE GROUP CONSISTING OF METALS, METAL HYDRIDES, ALKYL SECONDARY AMINES, ALKYL TERTIARY AMINES, SATURATED ALKYL ALCOHOLS, ALKYL PHOSPHINES AND HYDROGEN.
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