发明授权
- 专利标题: Process for the oxidation of carbon monoxide to carbon dioxide
- 专利标题(中): 将一氧化碳氧化成二氧化碳的方法
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申请号: US858555申请日: 1977-12-08
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公开(公告)号: US4124689A公开(公告)日: 1978-11-07
- 发明人: James M. Whelan
- 申请人: James M. Whelan
- 申请人地址: CA Los Angeles
- 专利权人: University of Southern California
- 当前专利权人: University of Southern California
- 当前专利权人地址: CA Los Angeles
- 主分类号: B01D53/86
- IPC分类号: B01D53/86 ; B01D53/94 ; B01J23/10 ; B01J23/22 ; B01J23/26 ; B01J23/34 ; B01J23/78 ; B01J23/83 ; B01J23/835 ; C01B5/00 ; C01B17/69 ; C01B17/78 ; C01B21/22 ; C01B21/26 ; C01B32/50 ; C01B31/20 ; B01D53/34
摘要:
A process for the oxidation of carbon monoxide to carbon dioxide in the presence of elemental nitrogen with minimal oxidation thereof which comprises combining the carbon monoxide with a predetermined amount of oxygen containing gas to give at least 1% stoichiometric excess of oxygen for the oxidation of carbon monoxide to carbon dioxide and passing the resulting mixture over a ceramic catalyst of the following empirical formula at a temperature between about 100.degree. C and about 1,000.degree. C;w.sub.k X.sub.n J(1-k-n).sup.ZO (3.+-.m)WhereinW is Zirconium, Tin or Thorium or mixtures thereof;X is an alkaline earth metal or mixture thereof;J is scandium, ytrrium, a rare-earth element or mixture thereof;Z is a metal of the first transition series or a mixture thereof, at least 0.01% of said metal having an oxidation state other than +3;k is a number having a value between 0 and about 0.1;m is a number having a value of from 0 to about 0.26; andn is a number having a value from 0 to about 0.51, provided when n has a value of 0, k has a value between 0 and about 0.05.
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