发明授权
- 专利标题: Reactivating iridium and selenium containing catalysts with hydrogen halide and oxygen
- 专利标题(中): 用卤化氢和氧气重新激活含铱和硒的催化剂
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申请号: US547874申请日: 1983-11-02
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公开(公告)号: US4491635A公开(公告)日: 1985-01-01
- 发明人: Shun C. Fung , Walter Weissman , James L. Carter , Walter S. Kmak
- 申请人: Shun C. Fung , Walter Weissman , James L. Carter , Walter S. Kmak
- 申请人地址: NJ Florham Park
- 专利权人: Exxon Research & Engineering Co.
- 当前专利权人: Exxon Research & Engineering Co.
- 当前专利权人地址: NJ Florham Park
- 优先权: FIX831532 19830504; JPX58-78847 19830504
- 主分类号: B01J23/96
- IPC分类号: B01J23/96 ; B01J27/30 ; C10G35/09 ; B01J27/02 ; C10G35/085
摘要:
A process is disclosed for reactivating an agglomerated iridium and selenium containing catalyst and particularly platinum-iridium-selenium on alumina reforming catalysts. The process includes contacting a substantially decoked agglomerated catalyst with a reducing gas such as hydrogen to reduce agglomerated iridium oxides present to the free metal, a hydrogen halide pretreatment step to increase the halogen level of the catalyst to about 1.3 weight percent and above, and a redispersion step involving hydrogen halide and elemental oxygen. Use of hydrogen halide and elemental oxygen in the redispersion treatment eliminates the need for use of elemental chlorine gas. If no iridium oxides are initially present, the hydrogen reduction step is optional.
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