摘要:
A process is disclosed for reactivating an agglomerated iridium and selenium containing catalyst and particularly platinum-iridium-selenium on alumina reforming catalysts. The process includes contacting a substantially decoked agglomerated catalyst with a reducing gas such as hydrogen to reduce agglomerated iridium oxides present to the free metal, a hydrogen halide pretreatment step to increase the halogen level of the catalyst to about 1.3 weight percent and above, and a redispersion step involving hydrogen halide and elemental oxygen. Use of hydrogen halide and elemental oxygen in the redispersion treatment eliminates the need for use of elemental chlorine gas. If no iridium oxides are initially present, the hydrogen reduction step is optional.
摘要:
A process is disclosed for reactivating an agglomerated iridium-containing catalyst and particularly platinum-iridium on alumina reforming catalysts. The process includes contacting a substantially decoked agglomerated catalyst with a reducing gas such as hydrogen to reduce agglomerated iridium oxides present to the free metal, a hydrogen halide pretreatment step to increase the halogen level of the catalyst to about 1.3 weight percent and above, and a redispersion step involving hydrogen halide and elemental oxygen. Use of hydrogen halide and elemental oxygen in the redispersion treatment eliminates the need for use of elemental chlorine gas. If no iridium oxides are initially present, the hydrogen reduction step is optional.
摘要:
A process is described for reactivating agglomerated iridium-containing catalysts such as Pt-Ir on Al.sub.2 O.sub.3 reforming catalyst. The agglomerated catalyst is decoked to remove carbon deposits; treated with hydrogen to reduce metal oxides to the free metals; pretreated with hydrogen halide to provide at least about a 1.3 weight percent halide content; and treated with a low mass flow rate of chlorine of about one gram chlorine per 100 grams catalyst per hour. Use of a low mass halogen flow rate significantly retards ferrous metal corrosion and significantly reduces the quantity of chlorine normally used in achieving high redispersion values.
摘要翻译:描述了一种用于在Al 2 O 3重整催化剂上再结合含铱的催化剂如Pt-Ir的方法。 烧结催化剂以除去碳沉积物; 用氢气处理以将金属氧化物还原成游离金属; 用卤化氢预处理以提供至少约1.3重量%的卤化物含量; 并以每小时100克催化剂的约1克氯的低质量流量氯处理。 使用低质量卤素流速显着延缓黑色金属腐蚀,并显着降低通常用于实现高再分散值的氯的量。
摘要:
A process is described for reactivating agglomerated iridium-containing catalysts such as Pt-Ir on Al.sub.2 O.sub.3 reforming catalyst. The agglomerated catalyst is decoked to remove carbon deposits; treated with hydrogen to reduce metal oxides to the free metals; pretreated with hydrogen halide to provide at least about a 1.3 weight percent halide content; and treated with a low mass flow rate of chlorine of about one gram chlorine per 100 grams catalyst per hour. Use of a low mass halogen flow rate significantly retards ferrous metal corrosion and significantly reduces the quantity of chlorine normally used in achieving high redispersion values.
摘要:
Catalyst compositions and methods for use of such catalyst composition in the exhaust gas recycle stream of an internal combustion engine for reforming of a methane-containing fuel are provided. A reformer incorporating such a catalyst for use in an exhaust gas recycle portion of an internal combustion engine powertrain is described. A powertrain incorporating such a reformer, a method of increasing the octane rating of an exhaust gas recycle stream, and a method of operating an internal combustion engine for methane combustion are also described.
摘要:
The present invention is a heat pipe having a specified volume of working fluid determined in relation to the interior volume of the heat pipe and a target temperature TT, to provide self-temperature regulation and pressure management. The heat pipe comprises at least a evaporator region and a condenser region having a known interior volume V and a mass of working fluid given by the relationship Mwf=Dwf at TT×V where Dwf is the density of the saturated vapor of the fluid at temperature TT plus an amount of additional working fluid sufficient to have the rate of evaporation about equal to the rate of condensation for the particular heat pipe configuration. The heat pipe has at least the condenser region having an interior coating of a hydrophobic material.
摘要:
A ultra-thin polymeric membrane is made by coating a porous substrate, such as a ceramic monolith, with a solution of a polymer colloid, then drying the solution to form the film. The polymer is an associating polymer. The resulting membrane may be used for separating hydrocarbon species, for example.
摘要:
A service station is provided with a plurality of vehicle servicing islands including liquid fuel blending pumps for dispensing and blending fuel components from underground storage tanks for refueling standard gasoline engine driven vehicles, standard diesel engine vehicles, vehicles with engines requiring dual fuels, vehicles with HCCL engines require low octane gasoline blended with standard diesel fuel, and fuel cell powered vehicles having onboard reformers. Other service islands include pumps for dispensing compressed hydrogen to fuel cell powered vehicles that do not include onboard reformers. In addition, service islands are provided for recharging the batteries of pure electric powered vehicles. A service station is further provided with a wireless communicator for receiving signals indicative of a vehicle's fuel requirements and transmitting signals to direct the vehicle to a service island capable of servicing the vehicle.
摘要:
The present invention is a heat pipe having a specified volume of working fluid determined in relation to the interior volume of the heat pipe and a target temperature TT, to provide self-temperature regulation and pressure management. The heat pipe comprises at least a evaporator region and a condenser region having a known interior volume V and a mass of working fluid given by the relationship Mwf=Dwf at TT×V plus an amount of additional working fluid sufficient to have the rate of evaporation about equal to the rate of condensation for the particular heat pipe configuration.
摘要:
Tuning fuel composition delivered to a spark ignition, internal combustion engine as a function of driving cycle conditions results in improvements in one or more of fuel efficiency and combustion emissions.