发明授权
- 专利标题: Process for producing rubber-modified thermoplastic resin
- 专利标题(中): 橡胶改性热塑性树脂的制造方法
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申请号: US16182申请日: 1993-02-11
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公开(公告)号: US5306778A公开(公告)日: 1994-04-26
- 发明人: Atushi Ishida , Katsuro Oomura , Yuji Yamamoto , Yuji Nakagawa , Tateki Furuyama , Hisao Nagai , Toshio Teramoto , Yasuo Takahashi , Hideki Ueda , Kazuhiko Yamamoto , Toshihiro Shimamura , Yoshinobu Suzuki
- 申请人: Atushi Ishida , Katsuro Oomura , Yuji Yamamoto , Yuji Nakagawa , Tateki Furuyama , Hisao Nagai , Toshio Teramoto , Yasuo Takahashi , Hideki Ueda , Kazuhiko Yamamoto , Toshihiro Shimamura , Yoshinobu Suzuki
- 申请人地址: JPX Tokyo
- 专利权人: Japan Synthetic Rubber Co., Ltd.
- 当前专利权人: Japan Synthetic Rubber Co., Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX63-209827 19880824; JPX1-124964 19890518
- 主分类号: C08F279/02
- IPC分类号: C08F279/02 ; C08F287/00 ; C08L23/02 ; C08L51/04 ; C08L75/04 ; C08L77/00 ; C08F379/02 ; C08F387/00
摘要:
A process for producing a rubber-modified thermoplastic resin, which comprises polymerizing (B) 30-100% by weight of an aromatic alkenyl compound monomer and/or an alkyl (meth)acrylate monomer and (C) 70-0% by weight of at least one other monomer compound copolymerizable therewith, in the presence of (A) a hydrogenated diene copolymer obtained by hydrogenating a diene copolymer comprising a rndom copolymer of 50% by weight or more of at least one conjugated diene and 50% by weight or less of an alkenyl aromatic compound until at least 70% by weight of the olefinic unsaturation of the diene copolymer is hydrogenated. The hydrogenated diene copolymer (A) may be a hydrogenated copolymer consisting of an A-B block copolymer or an A-B-C block copolymer (A is an alkenyl aromatic compound polymer block, B is an alkenyl aromatic compound-conjugated diene random copolymer block, and C is a polymer block composed mainly of an alkenyl aromatic compound), wherein(i) the weight ratio of the alkenyl aromatic compound/the conjugated diene is 5-50/95-50,(ii) the total amount of the alkenyl aromatic compounds of the block A and the block C in the copolymer is 3-40% by weight, and(iii) the vinyl configuration content in the conjugated diene portion of the block B is 10-90%, and wherein at least 90% of the double bonds of the conjugated diene is saturated.
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