发明授权
- 专利标题： Unsaturated group and fluorine containing block copolymers, process for preparing the same and use
- 专利标题（中）： 不饱和基团和含氟嵌段共聚物，其制备方法和用途
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申请号： US192133申请日： 1994-02-03
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公开(公告)号： US5428108A公开(公告)日： 1995-06-27
- 发明人: Yoshihiro Oshibe , Michihisa Yamada , Hisao Yamamoto , Hiroshi Ohmura
- 申请人： Yoshihiro Oshibe , Michihisa Yamada , Hisao Yamamoto , Hiroshi Ohmura
- 申请人地址： JPX Tokyo
- 专利权人： Nippon Oil & Fats Co., Ltd.
- 当前专利权人： Nippon Oil & Fats Co., Ltd.
- 当前专利权人地址： JPX Tokyo
- 主分类号： C08F8/26
- IPC分类号： C08F8/26 ; C08F299/00 ; C08F259/08
摘要：
The present block copolymer contains a structural unit (A) derived from a compound represented by the general formula (I): CH.sub.2 .dbd.CR.sub.1 COOR.sub.2 R.sub.f, and also contains a structural unit (B) consisting of a polymer moiety represented by at least one of the structural formulae (III) and (IV) and another polymer moiety derived from a compound represented by the general formula (II): CH.sub.2 .dbd.CR.sub.3 R.sub.4. For preparing the above block copolymer, a block copolymer consisting of the structural unit (A) derived from a compound represented by the general formula (I): CH.sub.2 .dbd.CR.sub.1 COOR.sub.2 R.sub.f and the structural unit (B1) derived from a compound represented by the general formula (II): CH.sub.2 .dbd.CR.sub.3 R.sub.4 and a compound represented by the general formula (V): CH.dbd.CR.sub.6 COO(R.sub.9).sub.t H are reacted with a compound represented by the general formula (VI): R.sub.10 COCl to allow a dehydrochlorination reaction to take place. Thus, an unsaturated group and fluorine containing block copolymer having excellent water and oil repellent properties and excellent sensitivity to activation energy rays can be prepared. The block copolymer is utilized as a surface modifier for activation energy-curing resins.