Unsaturated group and fluorine containing block copolymers, process for
preparing the same and use
    1.
    发明授权
    Unsaturated group and fluorine containing block copolymers, process for preparing the same and use 失效
    不饱和基团和含氟嵌段共聚物,其制备方法和用途

    公开(公告)号:US5428108A

    公开(公告)日:1995-06-27

    申请号:US192133

    申请日:1994-02-03

    CPC分类号: C08F299/00 C08F8/26

    摘要: The present block copolymer contains a structural unit (A) derived from a compound represented by the general formula (I): CH.sub.2 .dbd.CR.sub.1 COOR.sub.2 R.sub.f, and also contains a structural unit (B) consisting of a polymer moiety represented by at least one of the structural formulae (III) and (IV) and another polymer moiety derived from a compound represented by the general formula (II): CH.sub.2 .dbd.CR.sub.3 R.sub.4. For preparing the above block copolymer, a block copolymer consisting of the structural unit (A) derived from a compound represented by the general formula (I): CH.sub.2 .dbd.CR.sub.1 COOR.sub.2 R.sub.f and the structural unit (B1) derived from a compound represented by the general formula (II): CH.sub.2 .dbd.CR.sub.3 R.sub.4 and a compound represented by the general formula (V): CH.dbd.CR.sub.6 COO(R.sub.9).sub.t H are reacted with a compound represented by the general formula (VI): R.sub.10 COCl to allow a dehydrochlorination reaction to take place. Thus, an unsaturated group and fluorine containing block copolymer having excellent water and oil repellent properties and excellent sensitivity to activation energy rays can be prepared. The block copolymer is utilized as a surface modifier for activation energy-curing resins.

    摘要翻译: 本发明的嵌段共聚物含有由通式(I)表示的化合物衍生的结构单元(A):CH2 = CR1COOR2Rf,并且还含有由结构单元(B)构成的结构单元, 式(III)和(IV)表示的另一聚合物部分和由通式(II)表示的化合物衍生的另一聚合物部分:CH 2 = CR 3 R 4。 为了制备上述嵌段共聚物,由由通式(I)表示的化合物衍生的结构单元(A):CH 2 = CR 1 COOR 2 R f和由通式(I)表示的化合物衍生的结构单元(B1) (II):CH 2 = CR 3 R 4和由通式(V)表示的化合物:CH = CR 6 COO(R 9)t H与通式(VI)表示的化合物:R 10 COCl反应,以进行脱氯化氢反应。 因此,可以制备具有优异的防斥油性和对激活能量射线具有优异敏感性的不饱和基团和含氟嵌段共聚物。 嵌段共聚物用作活化能量固化树脂的表面改性剂。

    Anti-fog coating composition
    3.
    发明授权
    Anti-fog coating composition 有权
    防雾涂料组合物

    公开(公告)号:US08921455B2

    公开(公告)日:2014-12-30

    申请号:US13514871

    申请日:2010-12-21

    摘要: Provided is an anti-fog coating composition that rarely suffers from blushing when applied and dried even under high-humidity conditions and that can be heat-cured even at low temperature in a short time and form a coating film that exhibits excellent tight adhesion to a substrate and excellent heat resistance and anti-fog properties. The anti-fog coating composition comprises (A) a copolymer prepared from a monomer mixture of a monomer (A1), a monomer (A2) and a monomer (A3); (B) a basic compound such as amines; and (C) a surfactant such as anionic surfactants. The monomer (A1) is a vinyl monomer that has an N-methylol group or an N-alkoxymethylol group. The monomer (A2) is a vinyl monomer that has a sulfonic acid group. The monomer (A3) is an alkyl(meth)acrylate monomer.

    摘要翻译: 提供了即使在高湿度条件下施加和干燥也很少受到白化的防雾涂料组合物,并且即使在短时间内也可在低温下进行热固化,并形成对于 基材和优异的耐热性和防雾性能。 防雾涂料组合物包含(A)由单体(A1),单体(A2)和单体(A3)的单体混合物制备的共聚物; (B)碱性化合物如胺; 和(C)表面活性剂如阴离子表面活性剂。 单体(A1)是具有N-羟甲基或N-烷氧基羟甲基的乙烯基单体。 单体(A2)是具有磺酸基的乙烯基单体。 单体(A3)是(甲基)丙烯酸烷基酯单体。

    ANTI-FOG COATING COMPOSITION
    4.
    发明申请
    ANTI-FOG COATING COMPOSITION 有权
    防雾涂料组合物

    公开(公告)号:US20120245250A1

    公开(公告)日:2012-09-27

    申请号:US13514871

    申请日:2010-12-21

    IPC分类号: C09K3/18

    摘要: Provided is an anti-fog coating composition that rarely suffers from blushing when applied and dried even under high-humidity conditions and that can be heat-cured even at low temperature in a short time and form a coating film that exhibits excellent tight adhesion to a substrate and excellent heat resistance and anti-fog properties. The anti-fog coating composition comprises (A) a copolymer prepared from a monomer mixture of a monomer (A1), a monomer (A2) and a monomer (A3); (B) a basic compound such as amines; and (C) a surfactant such as anionic surfactants. The monomer (A1) is a vinyl monomer that has an N-methylol group or an N-alkoxymethylol group. The monomer (A2) is a vinyl monomer that has a sulfonic acid group. The monomer (A3) is an alkyl(meth)acrylate monomer.

    摘要翻译: 提供了即使在高湿度条件下施加和干燥也很少受到白化的防雾涂料组合物,并且即使在短时间内也可在低温下进行热固化,并形成对于 基材和优异的耐热性和防雾性能。 防雾涂料组合物包含(A)由单体(A1),单体(A2)和单体(A3)的单体混合物制备的共聚物; (B)碱性化合物如胺; 和(C)表面活性剂如阴离子表面活性剂。 单体(A1)是具有N-羟甲基或N-烷氧基羟甲基的乙烯基单体。 单体(A2)是具有磺酸基的乙烯基单体。 单体(A3)是(甲基)丙烯酸烷基酯单体。

    Composite dielectric material composition, and film, substrate, electronic part and molded article produced therefrom
    6.
    发明授权
    Composite dielectric material composition, and film, substrate, electronic part and molded article produced therefrom 失效
    复合介电材料组合物,以及由其制成的膜,基材,电子部件和模塑制品

    公开(公告)号:US06420476B1

    公开(公告)日:2002-07-16

    申请号:US09292842

    申请日:1999-04-16

    IPC分类号: C08L900

    摘要: The invention has for its object to provide a composite dielectric material having any desired dielectric constant selectable from a relatively wide range in a high-frequency band and a low dielectric loss tangent, and a film, substrate, electronic part or molded or otherwise formed article using the same. To accomplish this object, there is provided a composite dielectric material composition comprising a heat-resistant, low-dielectric polymeric material that is a resin composition comprising one or two or more resins having a weight-average absolute molecular weight of at least 1,000, wherein the sum of carbon atoms and hydrogen atoms in said composition is at least 99%, and some or all resin molecules have a chemical bond therebetween, and a filler. A film, substrate, electronic part or molded or otherwise formed article is obtained using this composition.

    摘要翻译: 本发明的目的是提供一种具有从高频带和低介电损耗角正切相对较宽范围内选择的任何所需介电常数的复合电介质材料,以及膜,基片,电子部件或模制或其它形成的制品 使用相同 为了实现该目的,提供了一种复合介电材料组合物,其包括耐热低介电聚合物材料,其是包含一种或两种或更多种重均分子量绝对分子量至少为1,000的树脂组合物,其中 所述组合物中碳原子和氢原子的总和为至少99%,并且部分或全部树脂分子之间具有化学键和填料。 使用该组合物获得薄膜,基材,电子部件或模制或其它成型制品。