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11 条记录 (耗时 0.021 秒)

    Unsaturated group and fluorine containing block copolymers, process for preparing the same and use
    1.
    发明授权
    Unsaturated group and fluorine containing block copolymers, process for preparing the same and use 失效
    不饱和基团和含氟嵌段共聚物，其制备方法和用途

    公开(公告)号：US5428108A

    公开(公告)日：1995-06-27

    申请号：US192133

    申请日：1994-02-03

    申请人： Yoshihiro Oshibe ,  Michihisa Yamada ,  Hisao Yamamoto ,  Hiroshi Ohmura

    发明人： Yoshihiro Oshibe ,  Michihisa Yamada ,  Hisao Yamamoto ,  Hiroshi Ohmura

    IPC分类号： C08F8/26 ,  C08F299/00 ,  C08F259/08

    CPC分类号： C08F299/00 ,  C08F8/26

    摘要： The present block copolymer contains a structural unit (A) derived from a compound represented by the general formula (I): CH.sub.2 .dbd.CR.sub.1 COOR.sub.2 R.sub.f, and also contains a structural unit (B) consisting of a polymer moiety represented by at least one of the structural formulae (III) and (IV) and another polymer moiety derived from a compound represented by the general formula (II): CH.sub.2 .dbd.CR.sub.3 R.sub.4. For preparing the above block copolymer, a block copolymer consisting of the structural unit (A) derived from a compound represented by the general formula (I): CH.sub.2 .dbd.CR.sub.1 COOR.sub.2 R.sub.f and the structural unit (B1) derived from a compound represented by the general formula (II): CH.sub.2 .dbd.CR.sub.3 R.sub.4 and a compound represented by the general formula (V): CH.dbd.CR.sub.6 COO(R.sub.9).sub.t H are reacted with a compound represented by the general formula (VI): R.sub.10 COCl to allow a dehydrochlorination reaction to take place. Thus, an unsaturated group and fluorine containing block copolymer having excellent water and oil repellent properties and excellent sensitivity to activation energy rays can be prepared. The block copolymer is utilized as a surface modifier for activation energy-curing resins.

    摘要翻译： 本发明的嵌段共聚物含有由通式（I）表示的化合物衍生的结构单元（A）：CH2 = CR1COOR2Rf，并且还含有由结构单元（B）构成的结构单元， 式（III）和（IV）表示的另一聚合物部分和由通式（II）表示的化合物衍生的另一聚合物部分：CH 2 = CR 3 R 4。 为了制备上述嵌段共聚物，由由通式（I）表示的化合物衍生的结构单元（A）：CH 2 = CR 1 COOR 2 R f和由通式（I）表示的化合物衍生的结构单元（B1） （II）：CH 2 = CR 3 R 4和由通式（V）表示的化合物：CH = CR 6 COO（R 9）t H与通式（VI）表示的化合物：R 10 COCl反应，以进行脱氯化氢反应。 因此，可以制备具有优异的防斥油性和对激活能量射线具有优异敏感性的不饱和基团和含氟嵌段共聚物。 嵌段共聚物用作活化能量固化树脂的表面改性剂。

    Composition of ultraviolet curing antifogging agent and process for forming antifogging coating film
    7.
    发明授权
    Composition of ultraviolet curing antifogging agent and process for forming antifogging coating film 失效
    紫外线固化防雾剂的组成和形成防雾涂膜的方法

    公开(公告)号：US5244935A

    公开(公告)日：1993-09-14

    申请号：US924363

    申请日：1992-07-31

    申请人： Yoshihiro Oshibe ,  Yasuhiro Yamamoto ,  Hiroshi Ohmura ,  Keiji Kumazawa

    发明人： Yoshihiro Oshibe ,  Yasuhiro Yamamoto ,  Hiroshi Ohmura ,  Keiji Kumazawa

    IPC分类号： C03C17/32 ,  C09D4/06 ,  C09K3/18

    CPC分类号： C09K3/18 ,  C03C17/32 ,  C09D4/06

    摘要： An ultraviolet curing antifogging agent is disclosed. The composition includes block copolymer (a) having a hydrophilic polymer segment (a1) and a hydrophobic polymer segment (a2). A polar solvent (c) is provided in which the hydrophilic polymer segment (a1) can easily be dissolved while the hydrophobic polymer segment (a2) can not. It further includes a photopolymerizable compound (b), and a photopolymerization initiator (d). The block copolymer (a) contains at least one hydrophilic monomer selected from the group of: a (meth) acrylamide compound represented by the general formula: CH.sub.2 .dbd.CR.sub.1 CONR.sub.2 R.sub.3 ; a cyclic (meth)acrylamide compound represented by the general formula ##STR1## and a hydroxyalkyl (meth)acrylate. Further, the hydrophilic polymer segment (a1) is formed by a radically polymerizable monomer having a functional group such as glycidyl group. The hydrophobic polymer segment (a2) is formed by a radically polymerizable monomer and a hydrophobic monomer which is copolymerizable with the former radically polymerizable monomer. The weight ratio of the hydrophilic polymer segment (a1) to the hydrophobic polymer segment (a2) is 50/50 to 95/5. The photopolymerizable compound (b) can be represented by the general formula CH.sub.2 .dbd.CR.sub.1 COO(CH.sub.2 CR.sub.4 HO).sub.n OCCR.sub.1 .dbd.CH.sub.2. The weight ratio of the component (a) to the component (b) is in the range of 10/90 to 90/10 in terms of the solid content. Such compositions have excellent antifogging properties and can be applied to transparent plastic materials to prevent fogging.

    摘要翻译： 公开了一种紫外线固化防雾剂。 该组合物包括具有亲水性聚合物链段（a1）和疏水性聚合物链段（a2）的嵌段共聚物（a）。 提供极性溶剂（c），其中疏水性聚合物链段（a2）不能容易地溶解亲水性聚合物链段（a1）。 还包括光聚合化合物（b）和光聚合引发剂（d）。 嵌段共聚物（a）含有选自以下通式中的至少一种亲水性单体：由通式：CH2 = CR1CONR2R3表示的（甲基）丙烯酰胺化合物; 由通式（IMAGE）表示的环状（甲基）丙烯酰胺化合物和（甲基）丙烯酸羟烷基酯。 此外，亲水性聚合物链段（a1）由具有缩水甘油基等官能团的自由基聚合性单体形成。 疏水性聚合物链段（a2）由可自由基聚合的单体和与前者的可自由基聚合的单体共聚的疏水单体形成。 亲水性聚合物链段（a1）与疏水性聚合物链段（a2）的重量比为50/50〜95/5。 可光聚合化合物（b）可以由通式CH 2 = CR 1 COO（CH 2 CR 4 HO）n OCCR 1 = CH 2表示。 组分（a）与组分（b）的重量比在固体含量方面在10/90至90/10的范围内。 这种组合物具有优异的防雾性能，并且可以应用于透明塑料材料以防止起雾。