发明授权
US6034257A Method for separating glycerin from reaction mixtures containing
glycerin and fatty acid amides, alkoxylated amides obtained therefrom
and the use thereof
失效
从含有甘油和脂肪酸酰胺的反应混合物中分离甘油的方法,由其获得的烷氧基化酰胺及其用途
- 专利标题: Method for separating glycerin from reaction mixtures containing glycerin and fatty acid amides, alkoxylated amides obtained therefrom and the use thereof
- 专利标题(中): 从含有甘油和脂肪酸酰胺的反应混合物中分离甘油的方法,由其获得的烷氧基化酰胺及其用途
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申请号: US308669申请日: 1999-06-03
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公开(公告)号: US6034257A公开(公告)日: 2000-03-07
- 发明人: Alfred Oftring , Gunter Oetter , Richard Baur , Oliver Borzyk , Bernd Burkhart , Christian Ott , Martin aus dem Kahmen
- 申请人: Alfred Oftring , Gunter Oetter , Richard Baur , Oliver Borzyk , Bernd Burkhart , Christian Ott , Martin aus dem Kahmen
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX19650107 19961203; DEX19650151 19961203
- 主分类号: C07C231/00
- IPC分类号: C07C231/00 ; C07C231/02 ; C07C231/14 ; C07C231/24 ; C07C233/05 ; C07C233/09 ; C07C233/18 ; C07C233/20 ; C08G65/26 ; C11D1/52 ; C11D3/32 ; C11D19/00
摘要:
In a process for preparing an alkoxylated amide of the formula (I)R.sup.1 --CO--NR.sup.2 --CHR.sup.3 --CHR.sup.4 --O--(CHR.sup.5 --CHR.sup.6 --O).sub.n --H (I)(1) glycerides of the fatty acids, specified later on, of the formula (II):R.sup.1 --COOH (II)are reached with amines of the formula (III)HNR.sup.2 R.sup.7 (III)to give amides of the formula (IV)R.sup.1 --CO--NR.sup.2 --R.sup.7 (IV)and glycerol,(2) then the glycerol which has been formed is separated off by adding of aqueous acid solution to the reaction mixture until it has a pH in the range 1-7, in order to bring about phase separation into a glycerol-containing aqueous phase and an organic phase containing amides of the formula (IV), and separating off the aqueous phase, and(3) subsequently the amide of the formula (IV) is reacted with ethylene oxide and/or propylene oxide and/or butylene oxide to give alkoxylated amides of the formula (I).
公开/授权文献
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