发明授权
US6075162A Integrated method for producing methyl methacrylate and hydrogen cyanide
有权
生产甲基丙烯酸甲酯和氰化氢的综合方法
- 专利标题: Integrated method for producing methyl methacrylate and hydrogen cyanide
- 专利标题(中): 生产甲基丙烯酸甲酯和氰化氢的综合方法
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申请号: US260000申请日: 1999-03-02
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公开(公告)号: US6075162A公开(公告)日: 2000-06-13
- 发明人: Koichi Kida
- 申请人: Koichi Kida
- 申请人地址: JPX Tokyo
- 专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX10-059732 19980311
- 主分类号: C07C69/54
- IPC分类号: C07C69/54 ; C01C3/02 ; C07C67/20 ; C07C67/327 ; C07C69/675 ; C07C231/06 ; C07C235/06 ; C07C253/00 ; C07C255/12 ; C07C67/30
摘要:
A method of producing methyl methacrylate comprises Step 1 of producing acetone cyanhydrin from hydrogen cyanide and acetone; Step 2 of producing .alpha.-hydroxyisobutyramide by hydrating acetone cyanhydrin; Step 3 of producing methyl .alpha.-hydroxyisobutyrate and ammonia by a reaction of .alpha.-hydroxyisobutyramide and methanol; Step 4 of producing methyl methacrylate by dehydrating methyl .alpha.-hydroxyisobutyrate; and Step 5 of producing hydrogen cyanide in vapor phase by reacting methanol and the ammonia obtained in Step 3 over a solid catalyst in the presence of molecular oxygen. By using methanol in the step 3, the conversion ratio of .alpha.-hydroxyisobutyramide into methyl .alpha.-hydroxyisobutyrate can be increased because the equilibrium of the reaction is easily sifted toward the product side by removing ammonia being produced from the reaction system. The use of methanol in the step 3 produces additional advantages of efficiently linking the steps to eliminate the steps for separation and purification, thereby reducing the production cost.Step 1:HCN+CH.sub.3 COCH.sub.3 .fwdarw.(CH.sub.3).sub.2 (OH)CN;Step 2:(CH.sub.3).sub.2 C(OH)CN+H.sub.2 O.fwdarw.(CH.sub.3).sub.2 (OH)CONH.sub.2Step 3:(CH.sub.3).sub.2 C(OH)CONH.sub.2 +CH.sub.3 OH.fwdarw.(CH.sub.3).sub.2 (OH)CO.sub.2 CH.sub.3 +NH.sub.3Step 4:(CH.sub.3).sub.2 C(OH)CO.sub.2 CH.sub.3 .fwdarw.(CH.sub.2).sub.2 .dbd.C(CH.sub.3)CO.sub.2 CH.sub.3 +H.sub.2 OStep 5:CH.sub.3 OH+NH.sub.3 +O.sub.2 .fwdarw.HCN+3H.sub.2 O
公开/授权文献
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